Citation: GAO Peng, LI Feng, ZHAO Ning, WANG Hui, WEI Wei, SUN Yu-Han. Preparation of Cu/Zn/Al/(Zr)/(Y) Catalysts from Hydrotalcite-Like Precursors and Their Catalytic Performance for the Hydrogenation of CO₂ to Methanol[J]. Acta Physico-Chimica Sinica, ;2014, 30(6): 1155-1162. doi: 10.3866/PKU.WHXB201401252 shu

Preparation of Cu/Zn/Al/(Zr)/(Y) Catalysts from Hydrotalcite-Like Precursors and Their Catalytic Performance for the Hydrogenation of CO₂ to Methanol

GAO Peng ^1,2 ,
LI Feng ² ,
ZHAO Ning ^2, ,
WANG Hui ¹ ,
WEI Wei ^1, ,
SUN Yu-Han ^2,3

1.
1 Center for Greenhouse Gas and Environmental Engineering, Shanghai Advanced Research Institute, Chinese Academy of Sciences, Shanghai 201203, P. R. China;
2 State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, P. R. China;
3 Chinese Academy of Sciences Key Laboratory of Low-Carbon Conversion Science and Engineering, Shanghai Advanced Research Institute, Chinese Academy of Sciences, Shanghai 201203, P. R. China

Received Date: 10 February 2014
Available Online: 2 April 2014
Fund Project:

Cu/Zn/Al/(Zr)/(Y) hydrotalcite-like compounds with Cu:Zn:Al:Zr:Y atomic ratios of 2:1:1:0:0, 2:1: 0.8:0.2:0, 2:1:0.8:0:0.2, and 2:1:0.8:0.1:0.1 were prepared using the coprecipitation method. The mixed oxides were then obtained by the calcination of the precursors at 500 ℃ in air, and subsequently evaluated in terms of their catalytic performance for the synthesis of methanol from the hydrogenation of CO₂. The asprepared samples were characterized by X-ray diffraction (XRD), thermogravimetric (TG) analysis, N₂ adsorption, reactive N₂O adsorption, H₂ temperature-programmed reduction (H₂-TPR), and H₂/CO₂ temperature-programmed desorption (H₂/CO₂ TPD) techniques. The results of these analyses showed that the BET specific surface area increased significantly with the introduction of Zr and Y, which was related to the amount of H₂O and CO₂ evolved from the precursors during calcination. The Cu specific surface area and Cu dispersion properties increased in the order of Cu/Zn/Al2 revealed that the CO₂ conversion was dependent on the Cu specific surface area, and the CH₃OH selectivity increased linearly as the proportion of strongly basic sites increased. The introduction of Zr and Y therefore favored the production of methanol and the maximum CH₃OH yield was obtained over the Cu/Zn/Al/Zr/Y catalyst.
- Hydrotalcite-like precursor,
- Modifier,
- Cu/Zn/Al catalyst,
- CO₂ hydrogenation,
- Methanol
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Preparation of Cu/Zn/Al/(Zr)/(Y) Catalysts from Hydrotalcite-Like Precursors and Their Catalytic Performance for the Hydrogenation of CO2 to Methanol

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通讯作者: 陈斌, bchen63@163.com

Preparation of Cu/Zn/Al/(Zr)/(Y) Catalysts from Hydrotalcite-Like Precursors and Their Catalytic Performance for the Hydrogenation of CO₂ to Methanol