Citation: PEI Juan, HAO Yan-Zhong, SUN Bao, LI Ying-Pin, FAN Long-Xue, SUN Shuo, WANG Shang-Xin. Heterojunction Interface Modification and Its Effect on the Photovoltaic Performance of Hybrid Solar Cells[J]. Acta Physico-Chimica Sinica, ;2014, 30(3): 397-407. doi: 10.3866/PKU.WHXB201401202 shu

Heterojunction Interface Modification and Its Effect on the Photovoltaic Performance of Hybrid Solar Cells

1.
College of Science, Hebei University of Science and Technology, Shijiazhuang 050018, P. R. China

Received Date: 18 October 2013
Available Online: 20 January 2014
Fund Project: 国家自然科学基金(21173065，20573031)，河北省自然科学基金(B2010000856)，河北省科技计划项目(13214413) (21173065，20573031)，河北省自然科学基金(B2010000856)，河北省科技计划项目(13214413)河北科技大学博士启动基金(QD201050) (QD201050)校立科研基金(XL201255)资助 (XL201255)

Much attention has been focused on hybrid solar cells because of their low cost and high theoretical efficiencies. The photoactive layer of hybrid solar cells is composed of inorganic semiconductor and organic conjugated polymer. Excitons (electron-hole pairs) are formed upon the absorption of photons by the polymer. The excitons diffuse to the heterojunction interface between the organic donor and inorganic acceptor, and then dissociate to free electrons and holes. These electrons and holes then transfer to the inorganic and organic materials to realize charge separation and transportation. The exciton dissociation efficiency at the organic-inorganic heterojunction interface influences the photovoltaic performance of the cell. A small contact area and poor chemical compatibility between the organic and inorganic materials decrease the exciton dissociation efficiency, and thus the overall cell efficiency. This can be overcome by modifying the heterojunction interface. This paper reviews available interfacial modification methods, their function and significance, and explores prospects for the future development and application of hybrid solar cells.
- Hybrid solar cell,
- Heterojunction interface,
- Interfacial modification,
- Charge separation and transportation,
- Photovoltaic performance
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沈阳化工大学材料科学与工程学院沈阳 110142