Citation:
SUN Xian-Zhong, ZHANG Xiong, HUANG Bo, MA Yan-Wei. Effects of Separator on the Electrochemical Performance of Electrical Double-Layer Capacitor and Hybrid Battery-Supercapacitor[J]. Acta Physico-Chimica Sinica,
;2014, 30(3): 485-491.
doi:
10.3866/PKU.WHXB201401131
-
Separators are important components in electrochemical energy storage devices such as electrical double layer capacitors (EDLCs) and hybrid battery-supercapacitors. We prepared activated carbon-based EDLCs using an electrolyte of 1 mol ·L-1 tetraethyl ammonium tetrafluoroborate (Et4NBF4) in propylene carbonate (PC), and (LiNi0.5Co0.2Mn0.3O2+activated carbon)/graphite hybrid battery-supercapacitors using a 1 mol·L-1 lithium hexafluorophate (LiPF6) Li-ion electrolyte. The physicochemical properties and effect of various separators on the electrochemical properties of the EDLC and hybrid battery-supercapacitor were studied. The four separators were nonwoven polypropylene (PP) mat, porous PP membrane, Al2O3-coated PP membrane, and cellulose paper. The surface morphology, differential scanning calorimetry, electrolyte uptake, and apparent contact angle were investigated. The electrochemical characterizations of coin cells indicated that the EDLC with cellulose separator had the highest specific capacitance and rate capability. Differences in the selfdischarge of the four cells were not obvious. The specific capacities of the hybrid battery-supercapacitors with PP membrane and nonwoven PP mat separators were approximately 20% higher than the others. The capacitor with the cellulose paper separator had the highest self-discharge rate.
-
-
-
[1]
(1) Miller, J. R.; Simon, P. Science 2008, 321, 651. doi: 10.1126/science.1158736
-
[2]
(2) Yang, X.; Cheng, C.;Wang, Y.; Qiu, L.; Li, D. Science 2013, 341, 534. doi: 10.1126/science.1239089
-
[3]
(3) Hu, X. B.; Deng, Z. H.; Suo, J. S.; Pan, Z. L. J. Power Sources 2009, 187, 635. doi: 10.1016/j.jpowsour.2008.11.033
-
[4]
(4) Hu, X. B.; Huai, Y. J.; Lin, Z. J.; Suo, J. S.; Deng, Z. H. J. Electrochem. Soc. 2007, 154, A1026.
-
[5]
(5) Lei, Y.; Huang, Z. H.; Shen,W. C.; Kang, F. Y.; Zheng, Y. P. Electrochim. Acta 2013, 107, 413. doi: 10.1016/j.electacta.2013.06.002
-
[6]
(6) Lei, Y.; Huang, Z. H.; Yang, Y.; Shen,W. C.; Zheng, Y. P.; Sun, H. Y.; Kang, F. Y. Sci. Rep. 2013, 3, 2477.
-
[7]
(7) Davies, A.; Yu, A. P. Can. J. Chem. Eng. 2011, 89, 1342. doi: 10.1002/cjce.v89.6
-
[8]
(8) Liu, S. Q.; Liu, S. Q.; Huang, K. L.; Liu, J. S.; Li, Y. K.; Fang, D.;Wang, H. M.; Xia, Y. F. J. Solid State Electrochem. 2012, 16, 1631. doi: 10.1007/s10008-011-1573-7
-
[9]
(9) Böckenfeld, N.; Kuhnel, R. S.; Passerini, S.;Winter, M.; Balducci, A. J. Power Sources 2011, 196, 4136. doi: 10.1016/j.jpowsour.2010.11.042
-
[10]
(10) Ping, L. N.; Zheng, J. M.; Shi, Z. Q.; Qi, J.;Wang, C. Y. Chin. Sci. Bull. 2013, 58, 689.
-
[11]
(11) Li, J. M.; Chang, K. H.;Wu, T. H.; Hu, C. C. J. Power Sources 2013, 224, 59. doi: 10.1016/j.jpowsour.2012.09.007
-
[12]
(12) Ping, L. N.; Zheng, J. M.; Shi, Z. Q.;Wang, C. Y. Acta Phys. -Chim. Sin. 2012, 28, 1733. [平丽娜, 郑嘉明, 时志强, 王成扬. 物理化学学报, 2012, 28, 1733.] doi: 10.3866/PKU.WHXB201205092
-
[13]
(13) Amatucci, G. G.; Badway, F.; Du Pasquier, A.; Zheng, T. J. Electrochem. Soc. 2001, 148, A930.
-
[14]
(14) Cericola, D.; Kötz, R. Electrochim. Acta 2012, 72, 1. doi: 10.1016/j.electacta.2012.03.151
-
[15]
(15) Cericola, D.; Ruch, P.W.; Kötz, R.; Novak, P.;Wokaun, A. J. Power Sources 2010, 195, 2731. doi: 10.1016/j.jpowsour.2009.10.104
-
[16]
(16) Hantel, M. M.; Kaspar, T.; Nesper, R.;Wokaun, A.; Kötz, R. ECS Electrochem. Lett. 2012, 1, A1.
-
[17]
(17) Sun, X. Z.; Zhang, X.; Huang, B.; Zhang, H. T.; Zhang, D. C.; Ma, Y.W. J. Power Sources 2013, 243, 361. doi: 10.1016/j.jpowsour.2013.06.038
-
[18]
(18) Liang, Y. Z.; Cheng, S. C.; Zhao, J. M.; Zhang, C. H.; Sun, S. Y.; Zhou, N. T.; Qiu, Y. P.; Zhang, X.W. J. Power Sources 2013, 240, 204. doi: 10.1016/j.jpowsour.2013.04.019
-
[19]
(19) Huang, X. S. J. Solid State Electrochem. 2011, 15, 649. doi: 10.1007/s10008-010-1264-9
-
[20]
(20) Huang, B.; Sun, X. Z.; Zhang, X.; Zhang, D. C.; Ma, Y.W. Acta Phys. -Chim. Sin. 2013, 29, 1998. [黄博, 孙现众, 张熊, 张大成, 马衍伟. 物理化学学报, 2013, 29, 1998.] doi: 10.3866/PKU.WHXB201307031
-
[21]
(21) Sun, X. Z.; Zhang, X.; Zhang, D. C.; Ma, Y.W. Acta Phys. -Chim. Sin. 2012, 28, 367. [孙现众, 张熊, 张大成, 马衍伟. 物理化学学报, 2012, 28, 367.] doi: 10.3866/PKU.WHXB201112131
-
[22]
(22) Yi, T. F.; Xie, Y.; Zhu, Y. R.; Zhu, R. S.; Shen, H. Y. J. Power Sources 2013, 222, 448. doi: 10.1016/j.jpowsour.2012.09.020
-
[23]
(23) Idris, N. H.; Rahman, M. M.;Wang, J. Z.; Liu, H. K. J. Power Sources 2012, 201, 294. doi: 10.1016/j.jpowsour.2011.10.141
-
[24]
(24) Tonurist, K.; Thomberg, T.; Janes, A.; Romann, T.; Sammelselg, V.; Lust, E. J. Electroanal. Chem. 2013, 689, 8.
-
[25]
(25) Sun, X. Z.; Zhang, X.; Zhang, H. T.; Zhang, D. C.; Ma, Y.W. J. Solid State Electrochem. 2012, 16, 2597. doi: 10.1007/s10008-012-1678-7
-
[26]
(26) Dsoke, S.; Tian, X.; Taubert, C.; Schluter, S.;Wohlfahrt-Mehrens, M. J. Power Sources 2013, 238, 422. doi: 10.1016/j.jpowsour.2013.04.031
-
[27]
(27) Lewandowski, A.; Olejniczak, A.; Galinski, M.; Stepniak, I. J. Power Sources 2010, 195, 5814. doi: 10.1016/j.jpowsour.2010.03.082
-
[28]
(28) de Levie, R. Electrochim. Acta 1963, 8, 751. doi: 10.1016/0013-4686(63)80042-0
-
[29]
(29) Kötz, R.; Carlen, M. Electrochim. Acta 2000, 45, 2483. doi: 10.1016/S0013-4686(00)00354-6
-
[30]
(30) Yang, X.; He, Y. S.; Jiang, G.; Liao, X. Z.; Ma, Z. F. Electrochem. Commun. 2011, 13, 1166. doi: 10.1016/j.elecom.2011.09.006
-
[31]
(31) Xu, J.; Chou, S. L.; Gu, Q. F.; Liu, H. K.; Dou, S. X. J. Power Sources 2013, 225, 172. doi: 10.1016/j.jpowsour.2012.10.033
-
[1]
-
-
-
[1]
Chunai Dai , Yongsheng Han , Luting Yan , Zhen Li , Yingze Cao . Ideological and Political Design of Solid-liquid Contact Angle Measurement Experiment. University Chemistry, 2024, 39(2): 28-33. doi: 10.3866/PKU.DXHX202306065
-
[2]
Jin CHANG . Supercapacitor performance and first-principles calculation study of Co-doping Ni(OH)2. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1697-1707. doi: 10.11862/CJIC.20240108
-
[3]
Yanhui XUE , Shaofei CHAO , Man XU , Qiong WU , Fufa WU , Sufyan Javed Muhammad . Construction of high energy density hexagonal hole MXene aqueous supercapacitor by vacancy defect control strategy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1640-1652. doi: 10.11862/CJIC.20240183
-
[4]
Guanghui SUI , Yanyan CHENG . Application of rice husk-based activated carbon-loaded MgO composite for symmetric supercapacitors. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 521-530. doi: 10.11862/CJIC.20240221
-
[5]
Zhaomei LIU , Wenshi ZHONG , Jiaxin LI , Gengshen HU . Preparation of nitrogen-doped porous carbons with ultra-high surface areas for high-performance supercapacitors. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 677-685. doi: 10.11862/CJIC.20230404
-
[6]
Xingchao Zhao , Xiaoming Li , Ming Liu , Zijin Zhao , Kaixuan Yang , Pengtian Liu , Haolan Zhang , Jintai Li , Xiaoling Ma , Qi Yao , Yanming Sun , Fujun Zhang . 倍增型全聚合物光电探测器及其在光电容积描记传感器上的应用. Acta Physico-Chimica Sinica, 2025, 41(1): 2311021-. doi: 10.3866/PKU.WHXB202311021
-
[7]
Guoze Yan , Bin Zuo , Shaoqing Liu , Tao Wang , Ruoyu Wang , Jinyang Bao , Zhongzhou Zhao , Feifei Chu , Zhengtong Li , Yusuke Yamauchi , Saad Melhi , Xingtao Xu . Opportunities and Challenges of Capacitive Deionization for Uranium Extraction from Seawater. Acta Physico-Chimica Sinica, 2025, 41(4): 100032-. doi: 10.3866/PKU.WHXB202404006
-
[8]
Jiahe LIU , Gan TANG , Kai CHEN , Mingda ZHANG . Effect of low-temperature electrolyte additives on low-temperature performance of lithium cobaltate batteries. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 719-728. doi: 10.11862/CJIC.20250023
-
[9]
Mingyang Men , Jinghua Wu , Gaozhan Liu , Jing Zhang , Nini Zhang , Xiayin Yao . 液相法制备硫化物固体电解质及其在全固态锂电池中的应用. Acta Physico-Chimica Sinica, 2025, 41(1): 2309019-. doi: 10.3866/PKU.WHXB202309019
-
[10]
Aoyu Huang , Jun Xu , Yu Huang , Gui Chu , Mao Wang , Lili Wang , Yongqi Sun , Zhen Jiang , Xiaobo Zhu . Tailoring Electrode-Electrolyte Interfaces via a Simple Slurry Additive for Stable High-Voltage Lithium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 100037-. doi: 10.3866/PKU.WHXB202408007
-
[11]
Xiaochen Zhang , Fei Yu , Jie Ma . 多角度数理模拟在电容去离子中的前沿应用. Acta Physico-Chimica Sinica, 2024, 40(11): 2311026-. doi: 10.3866/PKU.WHXB202311026
-
[12]
Mengfei He , Chao Chen , Yue Tang , Si Meng , Zunfa Wang , Liyu Wang , Jiabao Xing , Xinyu Zhang , Jiahui Huang , Jiangbo Lu , Hongmei Jing , Xiangyu Liu , Hua Xu . Epitaxial Growth of Nonlayered 2D MnTe Nanosheets with Thickness-Tunable Conduction for p-Type Field Effect Transistor and Superior Contact Electrode. Acta Physico-Chimica Sinica, 2025, 41(2): 100016-. doi: 10.3866/PKU.WHXB202310029
-
[13]
Qiqi Li , Su Zhang , Yuting Jiang , Linna Zhu , Nannan Guo , Jing Zhang , Yutong Li , Tong Wei , Zhuangjun Fan . 前驱体机械压实制备高密度活性炭及其致密电容储能性能. Acta Physico-Chimica Sinica, 2025, 41(3): 2406009-. doi: 10.3866/PKU.WHXB202406009
-
[14]
Zhening Lou , Quanxing Mao , Xiaogeng Feng , Lei Zhang , Xu Xu , Yuyang Zhang , Xueyan Liu , Hongling Kang , Dongyang Feng , Yongku Li . Practice of Implementing Blended Teaching in Shared Analytical Chemistry Course. University Chemistry, 2024, 39(2): 263-269. doi: 10.3866/PKU.DXHX202308089
-
[15]
Yutong Dong , Huiling Xu , Yucheng Zhao , Zexin Zhang , Ying Wang . The Hidden World of Surface Tension and Droplets. University Chemistry, 2024, 39(6): 357-365. doi: 10.3866/PKU.DXHX202312022
-
[16]
Yingran Liang , Fei Wang , Jiabao Sun , Hongtao Zheng , Zhenli Zhu . Construction and Application of a New Experimental Device for Determination of Alkaline Metal Elements by Plasma Atomic Emission Spectrometry Based on Solution Cathode Glow Discharge: An Alternative Approach for Fundamental Teaching Experiments in Emission Spectroscopy. University Chemistry, 2024, 39(5): 380-387. doi: 10.3866/PKU.DXHX202312024
-
[17]
Asif Hassan Raza , Shumail Farhan , Zhixian Yu , Yan Wu . 用于高效制氢的双S型ZnS/ZnO/CdS异质结构光催化剂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406020-. doi: 10.3866/PKU.WHXB202406020
-
[18]
Ziheng Zhuang , Xiao Xu , Kin Shing Chan . Superdrugs for Superbugs. University Chemistry, 2024, 39(9): 128-133. doi: 10.3866/PKU.DXHX202309040
-
[19]
Wenkai Chen , Yunjia Shen , Xiangmeng Kong , Yanli Zeng . Quantum Chemistry Calculation of Key Physical Quantity in Circularly Polarized Luminescence: Introducing an Exploratory Computational Chemistry Experiment. University Chemistry, 2025, 40(3): 83-91. doi: 10.12461/PKU.DXHX202405018
-
[20]
Feiya Cao , Qixin Wang , Pu Li , Zhirong Xing , Ziyu Song , Heng Zhang , Zhibin Zhou , Wenfang Feng . Magnesium-Ion Conducting Electrolyte Based on Grignard Reaction: Synthesis and Properties. University Chemistry, 2024, 39(3): 359-368. doi: 10.3866/PKU.DXHX202308094
-
[1]
Metrics
- PDF Downloads(1056)
- Abstract views(1197)
- HTML views(4)