Citation: JIN Hao, SUN Xiao-Dan, DONG Shu, WU Yi-Zhi, SUN Su-Hua, LIU Jie, ZHU Hui-Hong, YANG Guang, YI Xiao-Dong, FANG Wei-Ping. Influence of Cs Substitution on the Structural Properties and Catalytic Performance of Ni-H₃PW₁₂O₄₀/SiO₂ Catalysts[J]. Acta Physico-Chimica Sinica, ;2014, 30(3): 527-534. doi: 10.3866/PKU.WHXB201401072 shu

Influence of Cs Substitution on the Structural Properties and Catalytic Performance of Ni-H₃PW₁₂O₄₀/SiO₂ Catalysts

JIN Hao ^1,2, ,
SUN Xiao-Dan ¹ ,
DONG Shu ³ ,
WU Yi-Zhi ³ ,
SUN Su-Hua ¹ ,
LIU Jie ¹ ,
ZHU Hui-Hong ¹ ,
YANG Guang ¹ ,
YI Xiao-Dong ^2, ,
FANG Wei-Ping ²

1.
1 Fushun Research Institute of Petroleum and Petrochemicals, SINOPEC, Fushun 113001, Liaoning Province, P. R. China;
2 State Key Laboratory for Physical Chemistry of the Solid Surfaces, National Engineering Laboratory for Green Chemical Productions of Alcohols, Ethers and Esters, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian Province, P. R. China;
3 PetroChina Fushun Petrochemical Company No.2 Refinery, Fushun 113004, Liaoning Province, P. R. China

Received Date: 8 October 2013
Available Online: 7 January 2014
Fund Project: 国家重点基础研究发展规划项目(973) (2010CB226903)，国家自然科学基金(21073147，21303140) (973) (2010CB226903)，国家自然科学基金(21073147，21303140)教育部长江学者和创新团队发展计划项目(IRT₁036)资助 (IRT₁036)

Cs-substituted Ni-Cs_xH_3-xPW₁₂O₄₀/SiO₂ catalysts were prepared by two-step impregnation and in situ reaction on the support. The catalysts were characterized by N₂ adsorption measurements, inductively coupled plasma atomic emission spectrometry, Raman spectroscopy, in situ X-ray diffraction, NH₃-temperature programmed desorption (TPD), H₂-temperature programmed reduction, H₂-TPD, and Fourier transform infrared spectroscopy. The hydrocracking of n-decane was used to study the catalytic performance of the Ni-Cs_xH_3-xPW₁₂O₄₀/SiO₂ catalysts. The highest C₅₊ yield obtained for 8%Ni-50%Cs_1.5H_1.5PW/SiO₂ was superior to those of 8%Ni-50% H₃PW/SiO₂ and an industrial catalyst. The conversion of n-decane slightly decreased and the C₅₊ selectivity increased with increasing Cs content in the Cs_xH_3-xPW catalysts. Ni-Cs_xH_3-xPW₁₂O₄₀/SiO₂ catalysts possessed relatively large pore sizes, so the improved selectivity might have been due to a weaker acidity of the catalysts. The reduced conversion might have been due to a weaker hydrogenation ability.
- Hydrocracking,
- n-Decane,
- Bifunctional catalyst,
- Ni,
- Cs,
- H₃PW₁₂O₄₀
1. [1]
  
  (1) Morawski, I.; Mosio-Mosiewski, J. Fuel Process. Technol. 2006, 87, 659. doi: 10.1016/j.fuproc.2006.01.006
2. [2]
  (2) Ancheyta, J.; Sánchez, S.; Rodríguez, M. A. Catal. Today 2005, 109, 76. doi: 10.1016/j.cattod.2005.08.015
3. [3]
  (3) Roussel, M.; Lemberton, J. L.; Guisnet, M.; Cseri, T.; Benazzi, E. J. Catal. 2003, 218, 427. doi: 10.1016/S0021-9517(03)00164-7
4. [4]
  (4) Calemma, V.; Peratello, S.; Pere , C. Appl. Catal. A: Gen. 2000, 190, 207. doi: 10.1016/S0926-860X(99)00292-6
5. [5]
  (5) Ren, X. T.; Li, N.; Cao, J. Q.;Wang, Z. Y.; Liu, S. Y.; Xiang, S. H. Appl. Catal. A: Gen. 2006, 298, 144. doi: 10.1016/j.apcata.2005.09.031
6. [6]
  (6) Zeng, S. Q.; Blanchard, J.; Breysse, M.; Shi, Y. H.; Su, X. T.; Nie, H. Appl. Catal. A: Gen. 2005, 294, 59. doi: 10.1016/j.apcata.2005.07.015
7. [7]
  (7) Roussel, M.; Norsic, S.; Lemberton, J. L.; Guisnet, M.; Cseri, T.; Benazzi, E. Appl. Catal. A: Gen. 2005, 279, 53. doi: 10.1016/j.apcata.2004.10.011
8. [8]
  (8) Timofeeva, M. N. Appl. Catal. A: Gen. 2003, 256, 19. doi: 10.1016/S0926-860X(03)00386-7
9. [9]
  (9) Zhang, Q. D.; Tan, Y. S.; Yang, C. H.; Han, Y. Z. J. Mol. Catal. A: Chem. 2007, 263, 149. doi: 10.1016/j.molcata.2006.08.044
10. [10]
  (10) Zhang, P.; Huang, M.; Chu,W.; Luo, S. Z.; Li, T. Acta Phys. -Chim. Sin. 2013, 29, 770. [张坡, 黄明, 储伟, 罗仕忠, 李通. 物理化学学报, 2013, 29, 770.] doi: 10.3866/PKU.WHXB201301152
11. [11]
  (11) Gu, L. Y.; Gao, B. J.; Fang, X. L. Acta Phys. -Chim. Sin. 2013, 29, 191. [顾来沅, 高保娇, 房晓琳. 物理化学学报, 2013, 29, 191.] doi: 10.3866/PKU.WHXB201210266
12. [12]
  (12) Yuan, C. Y.; Chen, J. Chin. J. Catal. 2011, 32, 1191. doi: 10.1016/S1872-2067(10)60236-7
13. [13]
  (13) Kumar, G. S.; Vishnuvarthan, M.; Palanichamy, M.; Murugesan, V. J. Mol. Catal. A: Chem. 2006, 260, 49. doi: 10.1016/j.molcata.2006.07.050
14. [14]
  (14) Yang, X. K.; Chen, L. F.;Wang, J. A.; Noreña, L. E.; Novaro, O. Catal. Today 2009, 148, 160. doi: 10.1016/j.cattod.2009.03.022
15. [15]
  (15) Wang, J. A.; Chen, L. F.; Noreña, L. E.; Navarrete, J. Appl. Catal. A: Gen. 2009, 357, 223. doi: 10.1016/j.apcata.2009.01.023
16. [16]
  (16) Qiu, B.; Yi, X. D.; Lin, L.; Fang,W. P.;Wan, H. L. Catal. Today 2008, 131, 464. doi: 10.1016/j.cattod.2007.10.095
17. [17]
  (17) Qiu, B.; Yi, X. D.; Lin, L.; Fang,W. P.;Wan, H. L. Catal. Commun. 2009, 10, 1296. doi: 10.1016/j.catcom.2009.02.007
18. [18]
  (18) Vazquez, P.; Pizzio, L.; Romanelli, G.; Autino, J.; Caceres, C.; Blanco, M. Appl. Catal. A: Gen. 2002, 235, 233, doi: 10.1016/S0926-860X(02)00266-1
19. [19]
  (19) Haber, J.; Pamin, K.; Matachowski, L.; Mucha, D. Appl. Catal. A: Gen. 2003, 256, 141. doi: 10.1016/S0926-860X(03)00395-8
20. [20]
  (20) Narasimharao, K.; Brown, D. R.; Lee, A. F.; Newman, A. D.; Siril, P. F.; Tavener, S. J.;Wilson, K. J. Catal. 2007, 248, 226. doi: 10.1016/j.jcat.2007.02.016
21. [21]
  (21) Luzgin, M. V.; Kazantsev, M. S.; Volkova, G. G.;Wang,W.; Stepanov, A. G. J. Catal. 2011, 277, 72. doi: 10.1016/j.jcat.2010.10.015
22. [22]
  (22) Okuhara, T.; Kimura, M.; Kawai, T.; Xu, Z.; Nakato, T. Catal. Today 1998, 45, 73. doi: 10.1016/S0920-5861(98)00251-X
23. [23]
  (23) Choi, S.;Wang, Y.; Nie, Z.; Liu, J.; Peden, C. H. F. Catal. Today 2000, 55, 117. doi: 10.1016/S0920-5861(99)00231-X
24. [24]
  (24) Soled, S.; Miseo, S.; McVicker, G.; Gates,W. E.; Gutierrez, A.; Paes, J. Catal. Today 1997, 36, 441. doi: 10.1016/S0920-5861(96)00235-0
25. [25]
  (25) Yang,W.; Billy, J.; Taârit, Y. B.; Védrine, J. C.; Essayem, N. Catal. Today 2002, 73, 153. doi: 10.1016/S0920-5861(01)00508-9
26. [26]
  (26) Gao, R. H.; Chen, H.; Le, Y. Y.; Dai,W. L.; Fan, K. N. Appl. Catal. A: Gen. 2009, 352, 61. doi: 10.1016/j.apcata.2008.09.031
27. [27]
  (27) Jin, H.; Yi, X. D.; Sun, S. H.; Liu, J.; Yang, G.; Zhu, H. H.; Fang,W. P. Fuel Process. Technol. 2012, 97, 52. doi: 10.1016/j.fuproc.2012.01.011
28. [28]
  (28) Popa, A.; Sasca, V.; Holclajtner-Antunovi , I. Microporous Mesoporous Mat. 2012, 156, 127. doi: 10.1016/j.micromeso.2012.02.030
29. [29]
  (29) Yuan, S. H.; Ji, N. H.; Xia,W. S.; Yi, X. D.; Fang,W. P. React. Kinet. Mech. Catal. 2012, 106, 475. doi: 10.1007/s11144-012-0448-y
30. [30]
  (30) Jin, H.; Guo, D. Y.; Sun, X. D.; Sun, S. H.; Liu, J.; Zhu, H. H.; Yang, G.; Yi, X. D.; Fang,W. P. Fuel 2013, 112, 134. doi: 10.1016/j.fuel.2013.05.007
31. [31]
  (31) Rocchiccioli-Deltcheff, C.; Fournier, M.; Franck, R.; Thouvenot, R. Inorg. Chem. 1983, 22, 207. doi: 10.1021/ic00144a006
32. [32]
  (32) Qu, X. S.; Guo, Y. H.; Hu, C.W. J. Mol. Catal. A: Chem. 2007, 262, 128. doi: 10.1016/j.molcata.2006.08.026
33. [33]
  (33) Chen, L. F.; Noreña, L. E.;Wang, J. A.; Zhou, X. L.; Navarrete, J.; Hernández, I.; Montoya, A.; Pérez Romo, P.; Salas, P.; Castella Pergher, S. Catal. Today 2008, 133-135, 331.
34. [34]
  (34) Varisli, D.; Dogu, T.; Dogu, G. Ind. Eng. Chem. Res. 2008, 47, 4071. doi: 10.1021/ie800192t
35. [35]
  (35) Jin, H.; Yi, X. D.; Sun, X. D.; Qiu, B.; Fang,W. P.;Weng,W. Z.; Wan, H. L. Fuel 2010, 89, 1953. doi: 10.1016/j.fuel.2009.11.031
36. [36]
  (36) Kuba, S.; Lukinskas, P.; Grasselli, R. K.; Gates, B. C.; Knözinger, H. J. Catal. 2003, 216, 353. doi: 10.1016/S0021-9517(02)00125-2
37. [37]
  (37) Corma, A.; Martinez, A.; Pergher, S.; Peratello, S.; Pere , C.; Bellusi, G. Appl. Catal. A: Gen. 1997, 152, 107. doi: 10.1016/S0926-860X(96)00338-9
1. [1]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421
2. [2]
  Juan WANG , Zhongqiu WANG , Qin SHANG , Guohong WANG , Jinmao LI . NiS and Pt as dual co-catalysts for the enhanced photocatalytic H₂ production activity of BaTiO₃ nanofibers. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1719-1730. doi: 10.11862/CJIC.20240102
3. [3]
  Dan Li , Hui Xin , Xiaofeng Yi . Comprehensive Experimental Design on Ni-based Catalyst for Biofuel Production. University Chemistry, 2024, 39(8): 204-211. doi: 10.3866/PKU.DXHX202312046
4. [4]
  Juan Guo , Mingyuan Fang , Qingsong Liu , Xiao Ren , Yongqiang Qiao , Mingju Chao , Erjun Liang , Qilong Gao . Zero thermal expansion in Cs₂W₃O₁₀. Chinese Chemical Letters, 2024, 35(7): 108957-. doi: 10.1016/j.cclet.2023.108957
5. [5]
  Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
6. [6]
  Wei Zhong , Dan Zheng , Yuanxin Ou , Aiyun Meng , Yaorong Su . K原子掺杂高度面间结晶的g-C₃N₄光催化剂及其高效H₂O₂光合成. Acta Physico-Chimica Sinica, 2024, 40(11): 2406005-. doi: 10.3866/PKU.WHXB202406005
7. [7]
  Hongyi LI , Aimin WU , Liuyang ZHAO , Xinpeng LIU , Fengqin CHEN , Aikui LI , Hao HUANG . Effect of Y(PO₃)₃ double-coating modification on the electrochemical properties of Li[Ni_0.8Co_0.15Al_0.05]O₂. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1320-1328. doi: 10.11862/CJIC.20230480
8. [8]
  Maomao Liu , Guizeng Liang , Ningce Zhang , Tao Li , Lipeng Diao , Ping Lu , Xiaoliang Zhao , Daohao Li , Dongjiang Yang . Electron-rich Ni2+ in Ni3S2 boosting electrocatalytic CO2 reduction to formate and syngas. Chinese Journal of Structural Chemistry, 2024, 43(8): 100359-100359. doi: 10.1016/j.cjsc.2024.100359
9. [9]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
10. [10]
  Ruolin CHENG , Haoran WANG , Jing REN , Yingying MA , Huagen LIANG . Efficient photocatalytic CO₂ cycloaddition over W₁₈O₄₉/NH₂-UiO-66 composite catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 523-532. doi: 10.11862/CJIC.20230349
11. [11]
  Yi YANG , Shuang WANG , Wendan WANG , Limiao CHEN . Photocatalytic CO₂ reduction performance of Z-scheme Ag-Cu₂O/BiVO₄ photocatalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 895-906. doi: 10.11862/CJIC.20230434
12. [12]
  Asif Hassan Raza , Shumail Farhan , Zhixian Yu , Yan Wu . 用于高效制氢的双S型ZnS/ZnO/CdS异质结构光催化剂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406020-. doi: 10.3866/PKU.WHXB202406020
13. [13]
  Jinli Chen , Shouquan Feng , Tianqi Yu , Yongjin Zou , Huan Wen , Shibin Yin . Modulating Metal-Support Interaction Between Pt3Ni and Unsaturated WOx to Selectively Regulate the ORR Performance. Chinese Journal of Structural Chemistry, 2023, 42(10): 100168-100168. doi: 10.1016/j.cjsc.2023.100168
14. [14]
  Yuchen Guo , Xiangyu Zou , Xueling Wei , Weiwei Bao , Junjun Zhang , Jie Han , Feihong Jia . Fe regulating Ni3S2/ZrCoFe-LDH@NF heterojunction catalysts for overall water splitting. Chinese Journal of Structural Chemistry, 2024, 43(2): 100206-100206. doi: 10.1016/j.cjsc.2023.100206
15. [15]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
16. [16]
  Cheng PENG , Jianwei WEI , Yating CHEN , Nan HU , Hui ZENG . First principles investigation about interference effects of electronic and optical properties of inorganic and lead-free perovskite Cs₃Bi₂X₉ (X=Cl, Br, I). Chinese Journal of Inorganic Chemistry, 2024, 40(3): 555-560. doi: 10.11862/CJIC.20230282
17. [17]
  Jingzhao Cheng , Shiyu Gao , Bei Cheng , Kai Yang , Wang Wang , Shaowen Cao . 4-氨基-1H-咪唑-5-甲腈修饰供体-受体型氮化碳光催化剂的构建及其高效光催化产氢研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2406026-. doi: 10.3866/PKU.WHXB202406026
18. [18]
  Qin Hu , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . Ni掺杂构建电子桥及激活MoS₂惰性基面增强光催化分解水产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2406024-. doi: 10.3866/PKU.WHXB202406024
19. [19]
  Pan Liu , Yanming Sun , Alberto J. Fernández-Carrión , Bowen Zhang , Hui Fu , Lunhua He , Xing Ming , Congling Yin , Xiaojun Kuang . Bismuth-based halide double perovskite Cs₂KBiCl₆: Disorder and luminescence. Chinese Chemical Letters, 2024, 35(5): 108641-. doi: 10.1016/j.cclet.2023.108641
20. [20]
  Kai Han , Guohui Dong , Ishaaq Saeed , Tingting Dong , Chenyang Xiao . Boosting bulk charge transport of CuWO4 photoanodes via Cs doping for solar water oxidation. Chinese Journal of Structural Chemistry, 2024, 43(2): 100207-100207. doi: 10.1016/j.cjsc.2023.100207

Get Citation

PDF

XML

Metrics

PDF Downloads(466)
Abstract views(710)
HTML views(8)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Influence of Cs Substitution on the Structural Properties and Catalytic Performance of Ni-H3PW12O40/SiO2 Catalysts

Metrics

通讯作者: 陈斌, bchen63@163.com

Influence of Cs Substitution on the Structural Properties and Catalytic Performance of Ni-H₃PW₁₂O₄₀/SiO₂ Catalysts