Citation: ZHANG Qing-Qing, LI Rong, ZHANG Meng-Meng, U Xing-Long. Synthesis and Electrochemical Lithium Storage Performance of WO₃ Nanorods/Graphene Nanocomposites[J]. Acta Physico-Chimica Sinica, ;2014, 30(3): 476-484. doi: 10.3866/PKU.WHXB201401071 shu

Synthesis and Electrochemical Lithium Storage Performance of WO₃ Nanorods/Graphene Nanocomposites

1.
Chemical Synthesis and Pollution Control Key Laboratory of Sichuan Province, College of Chemistry and Chemical Engineering, China West Normal University, Nanchong 637000, Sichuan Province, P. R. China

Received Date: 6 August 2013
Available Online: 7 January 2014
Fund Project: 国家自然科学基金(51071131) (51071131)教育部新世纪优秀人才计划(NCET-10-0890)项目资助 (NCET-10-0890)

WO₃ nanorods/graphene nanocomposites (WO₃/R ) were prepared by the solvothermal treatment of tungsten hexachloride and graphene oxide in alcohol. The electrochemical performance of WO₃/R as anode materials for lithium-ion batteries was investigated by galvanostatic charge-discharge tests, cyclic voltammetry (CV), and electrochemical impedance spectroscopy (EIS). The discharge capacity of the composite at the first cycle was 761.4 mAh·g^-1, and about 635 mAh·g^-1 of reversible capacity remained after 100 cycles at a rate of 0.1C (1C=638 mA·g^-1). The corresponding retention rate was 83.4%. The reversible capacity remained lager than 460 mAh·g^-1 at a rate of 5C. WO₃/R exhibited excellent cycling stability and rate performance, and has potential in advanced lithium-ion batteries.
- Tungsten trioxide,
- Graphene,
- Nanocomposite,
- Lithium-ion battery,
- Anode material
1. [1]
  
  (1) Poizot, P.; Laruelle, S.; Dupont, L.; Tarascon, J. J. M. Nature 2000, 407, 496. doi: 10.1038/35035045
2. [2]
  (2) Park, J. C.; Kim, J.; Kwon, H.; Song, H. Adv. Mater. 2008, 20, 1. doi: 10.1002/adma.v20:16
3. [3]
  (3) Chen, J.; Xu, L. N.; Li,W. Y.; u, X. L. Adv. Mater. 2005, 17, 5.
4. [4]
  (4) Wang, B.;Wu, H. B.; Zhang, L.; Lou, X.W. Angew. Chem. Int. Edit. 2013, 52, 4165. doi: 10.1002/anie.201300190
5. [5]
  (5) Zhen, F. M.; Geng, B. Y.; u, Y. J. Chem. Eur. J. 2009, 15, 6169. doi: 10.1002/chem.v15:25
6. [6]
  (6) Manickam, S.; Nanda, G.; Masaki, Y.; Kenichi, N. Nano Energy 2012, 1, 503. doi: 10.1016/j.nanoen.2012.03.003
7. [7]
  (7) Gu, Z. J.; Li, H. Q.; Zhai, T. Y.; Yang,W. S.; Xia, Y. Y.; Ma, Y.; Yao, J. N. J. Solid State Electrochem. 2007, 180, 98.
8. [8]
  (8) Qiu, Y. C.; Xu, G. L.; Kuang, Q.; Sun, S. G.; Yang, S. H. Nano Res. 2012, 5, 8260.
9. [9]
  (9) Guo, X.W.; Fang, X. P.; Sun, Y.; Shen, L. Y.;Wang, Z. X.; Chen, L. Q. J. Power Sources 2013, 226, 75. doi: 10.1016/j.jpowsour.2012.10.068
10. [10]
  (10) Sun, X. L.;Wang, X. H.; Qiao, L.; Hu, D. K.; Feng, N.; Li, X. W.; Liu, Y. Q.; He, D. Y. Electrochim. Acta 2012, 66, 204. doi: 10.1016/j.electacta.2012.01.083
11. [11]
  (11) Shen, Y. X.; Yan, L.; Song, H. H.; Yang, J.; Yang, G.; Chen, X. H.; Zhou, J. S.; Yu, Z. Z.; Yang, S. B. Angew. Chem. Int. Edit. 2012, 51, 1. doi: 10.1002/anie.201106864
12. [12]
  (12) Zhao, Y.; Li, J. X.; Ding, Y. H.; Guan, L. H. Chem. Commun. 2011, 47, 7416. doi: 10.1039/c1cc12171e
13. [13]
  (13) Ji, L.W.; Zhang, X.W. Energy Environ. Sci. 2010, 3, 124. doi: 10.1039/b912188a
14. [14]
  (14) Cheng, F.; Huang, K. L.; Liu, S. Q.; Fang, X. S.; Zhang, X. Acta Phys. -Chim. Sin. 2011, 27, 1439. [程凤, 黄可龙, 刘素琴, 房雪松, 张新. 物理化学学报, 2011, 27, 1439.] doi: 10.3866/PKU.WHXB20110607
15. [15]
  (15) Ren, Y. M.; Zhang, J.; Liu, Y. Y.; Li, H. B.;Wei, H. J.; Li, B. J.; Wang, X. Y. ACS Appl. Mater. Interfaces 2012, 4, 4776. doi: 10.1021/am301131h
16. [16]
  (16) Fang,W.; Zuo, P. J.; Ma, Y. L.; Chen, X. Q.; Liao, L. X.; Yin, G. P. Electrochim. Acta 2013, 94, 294. doi: 10.1016/j.electacta.2013.01.132
17. [17]
  (17) Chen, Z.; Berciaud, S. P.; Nuckolls, C.; Heinz, T. F.; Brus, L. E. ACS Nano 2010, 4, 2964. doi: 10.1021/nn1005107
18. [18]
  (18) Guo, P.; Song, H. H.; Chen, X. H. Electrochem. Commun. 2009, 11, 1320. doi: 10.1016/j.elecom.2009.04.036
19. [19]
  (19) Pumera, M. Energy Environ. Sci. 2011, 4, 668. doi: 10.1039/c0ee00295j
20. [20]
  (20) Wang, G. X.; Shen, X. P.; Yao, J.; Park, J. Carbon 2009, 47, 2049. doi: 10.1016/j.carbon.2009.03.053
21. [21]
  (21) Li, D.; Muller, M.; Gilje, S.; Kaner, R.;Wallace, G. Nat. Nanotechnol. 2008, 3, 101. doi: 10.1038/nnano.2007.451
22. [22]
  (22) Yoo, E. J.; Hosono, E.; Zhou, H. S.; Kudo, T.; Honma, I. Nano Lett. 2008, 8, 2277. doi: 10.1021/nl800957b
23. [23]
  (23) Hummers,W. S.; Offeman, R. E. J. Am. Chem. Soc. 1958, 80, 1339. doi: 10.1021/ja01539a017
24. [24]
  (24) Li, R.;Wei, Z. D.; u, X. L.; Xu,W. RSC Adv. 2013, 3, 9978. doi: 10.1039/c3ra41079j
25. [25]
  (25) Luo, B.; Fang, Y.;Wang, B.; Zhou, J.; Song, H.; Zhi, L. J. Energy Environ. Sci. 2012, 5, 5226. doi: 10.1039/c1ee02800f
26. [26]
  (26) Xu, Y. X.; Sheng, K. X.; Li, C.; Shi, G. Q. ACS Nano 2010, 4, 4324. doi: 10.1021/nn101187z
27. [27]
  (27) Yang, J. Q.; Jiao, L. F.; Zhao, Q. Q.;Wang, Q. H.; Gao, H. Y.; Huan, Q. N.; Zheng,W. J.;Wang, Y. J.; Yuan, H. T. J. Mater. Chem. 2012, 22, 3699. doi: 10.1039/c2jm15837j
28. [28]
  (28) Qin, J.W.; Cao, M. H.; Li, N.; Hu, C.W. J. Mater. Chem. 2011, 21, 17167. doi: 10.1039/c1jm12692j
29. [29]
  (29) Thangavel, S.; Elayaperumal, M.; Venu pal, G. Mater. Express 2012, 2, 327. doi: 10.1166/mex.2012.1087
30. [30]
  (30) Akhavan, O.; Choobtashani, M.; Ghaderi, E. J. Phys. Chem. C 2012, 116, 9653. doi: 10.1021/jp301707m
31. [31]
  (31) u, J. J.; Li, Y.; Zhu, S. M.; Chen, Z. X.; Liu, Q. L.; Zhang, D.; Moon,W. J, Song, D. M. RSC Adv. 2012, 2, 1356. doi: 10.1039/c1ra00621e
32. [32]
  (32) Li,W. J.; Fu, Z.W. Appl. Surf. Sci. 2010, 256, 2447. doi: 10.1016/j.apsusc.2009.10.085
33. [33]
  (33) Delmer, O.; Balaya, P.; Kienle, L.; Maier, J. Adv. Mater. 2008,20, 501.
34. [34]
  (34) Ding, P.; Xu, Y. L.; Sun, X. F. Acta Phys. -Chim. Sin. 2013, 29, 293. [丁朋, 许友龙, 孙孝飞. 物理化学学报, 2013, 29, 293.] doi: 10.3866/PKU.WHXB201211142
35. [35]
  (35) Laruelle, S.; Grugeon, S.; Poizot, P.; Dolle, M.; Dupont, L.; Tarasconet, J. M. J. Electrochem. Soc. 2002, 149, A627.
36. [36]
  (36) Jamnik, J.; Maier, J. Phys. Chem. Chem. Phys. 2003, 5, 5215. doi: 10.1039/b309130a
37. [37]
  (37) Liu, H.;Wang, X. L.; Hu, J. S.;Wexler, D. Electrochem. Commun. 2008, 10, 1879. doi: 10.1016/j.elecom.2008.09.036
38. [38]
  (38) Xu, C. H.; Xu, B. H.; Gu, Y.; Xiong, Z. G.; Sun, J.; Zhao, X. S. Energy Environ. Sci. 2013, 6, 1388. doi: 10.1039/c3ee23870a
39. [39]
  (39) Marappan, S.; Satoshi, M.; Takaaki, T.; Itaru, H. J. Phys. Chem. C 2012, 116, 12475. doi: 10.1021/jp303121n
40. [40]
  (40) Xu, K.; Shen, L. F.; Mi, C. H.; Zhang, X. G. Acta Phys. -Chim. Sin. 2012, 28, 105. [许科, 申来法, 米常焕, 张校刚. 物理化学学报, 2012, 28, 105.] doi: 10.3866/PKU.WHXB201228105
41. [41]
  (41) Reddy, M. V.; Yu, T.; Sow, C. H.; Shen, Z. X.; Lim, C. T.; Rao, G. V.; Chowdari, B. V. R. Adv. Funct. Mater. 2007, 17, 2792.
42. [42]
  (42) Gan, L.; Guo, H. J.;Wang, Z. X.; Li, X. H.; Peng,W. J.;Wang, J. X.; Huang, S. L.; Su, M. R. Electrochim. Acta 2013, 104, 117. doi: 10.1016/j.electacta.2013.04.083
43. [43]
  (43) Zhuo, L. H.;Wu, Y. Q.;Wang, L. Y.; Yu, Y. C.; Zhang, X. B.; Zhao, F. Y. RSC Adv. 2012, 2, 5084. doi: 10.1039/c2ra00002d
44. [44]
  (44) Zou, Y. Q.; Kan, J.;Wang, Y. J. Phys. Chem. C 2011, 115, 20747. doi: 10.1021/jp206876t
45. [45]
  (45) Xue, X. Y.; Ma, C. H.; Cui, C. X.; Xing, L. L. Solid State Sci. 2011, 11, 1526.
46. [46]
  (46) Chen, J.; Xu, L. N.; Li,W. Y. Adv. Mater. 2005, 17, 582.
1. [1]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
2. [2]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
3. [3]
  Min LI , Xianfeng MENG . Preparation and microwave absorption properties of ZIF-67 derived Co@C/MoS₂ nanocomposites. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1932-1942. doi: 10.11862/CJIC.20240065
4. [4]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
5. [5]
  Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn_0.8Fe_0.2PO₄/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252
6. [6]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
7. [7]
  Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO₂/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1461-1473. doi: 10.11862/CJIC.20240189
8. [8]
  Yifeng Xu , Jiquan Liu , Bin Cui , Yan Li , Gang Xie , Ying Yang . “Xiao Li’s School Adventures: The Working Principles and Safety Risks of Lithium-ion Batteries”. University Chemistry, 2024, 39(9): 259-265. doi: 10.12461/PKU.DXHX202404009
9. [9]
  Siyu Zhang , Kunhong Gu , Bing'an Lu , Junwei Han , Jiang Zhou . Hydrometallurgical Processes on Recycling of Spent Lithium-lon Battery Cathode: Advances and Applications in Sustainable Technologies. Acta Physico-Chimica Sinica, 2024, 40(10): 2309028-. doi: 10.3866/PKU.WHXB202309028
10. [10]
  Zhenming Xu , Mingbo Zheng , Zhenhui Liu , Duo Chen , Qingsheng Liu . Experimental Design of Project-Driven Teaching in Computational Materials Science: First-Principles Calculations of the LiFePO₄ Cathode Material for Lithium-Ion Batteries. University Chemistry, 2024, 39(4): 140-148. doi: 10.3866/PKU.DXHX202307022
11. [11]
  Jie XIE , Hongnan XU , Jianfeng LIAO , Ruoyu CHEN , Lin SUN , Zhong JIN . Nitrogen-doped 3D graphene-carbon nanotube network for efficient lithium storage. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1840-1849. doi: 10.11862/CJIC.20240216
12. [12]
  Yunting Shang , Yue Dai , Jianxin Zhang , Nan Zhu , Yan Su . Something about RGO (Reduced Graphene Oxide). University Chemistry, 2024, 39(9): 273-278. doi: 10.3866/PKU.DXHX202306050
13. [13]
  Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe₃O₄@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239
14. [14]
  Meng Lin , Hanrui Chen , Congcong Xu . Preparation and Study of Photo-Enhanced Electrocatalytic Oxygen Evolution Performance of ZIF-67/Copper(I) Oxide Composite: A Recommended Comprehensive Physical Chemistry Experiment. University Chemistry, 2024, 39(4): 163-168. doi: 10.3866/PKU.DXHX202308117
15. [15]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
16. [16]
  Jianbao Mei , Bei Li , Shu Zhang , Dongdong Xiao , Pu Hu , Geng Zhang . Enhanced Performance of Ternary NASICON-Type Na_3.5-xMn_0.5V_1.5-xZr_x(PO₄)₃/C Cathodes for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(12): 2407023-. doi: 10.3866/PKU.WHXB202407023
17. [17]
  Limei CHEN , Mengfei ZHAO , Lin CHEN , Ding LI , Wei LI , Weiye HAN , Hongbin WANG . Preparation and performance of paraffin/alkali modified diatomite/expanded graphite composite phase change thermal storage material. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 533-543. doi: 10.11862/CJIC.20230312
18. [18]
  Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO₄/NiMoS₄ composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253
19. [19]
  Zeyu XU , Anlei DANG , Bihua DENG , Xiaoxin ZUO , Yu LU , Ping YANG , Wenzhu YIN . Evaluation of the efficacy of graphene oxide quantum dots as an ovalbumin delivery platform and adjuvant for immune enhancement. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1065-1078. doi: 10.11862/CJIC.20240099
20. [20]
  Doudou Qin , Junyang Ding , Chu Liang , Qian Liu , Ligang Feng , Yang Luo , Guangzhi Hu , Jun Luo , Xijun Liu . Addressing Challenges and Enhancing Performance of Manganese-based Cathode Materials in Aqueous Zinc-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(10): 2310034-. doi: 10.3866/PKU.WHXB202310034

Get Citation

PDF

XML

Metrics

PDF Downloads(1146)
Abstract views(892)
HTML views(4)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis and Electrochemical Lithium Storage Performance of WO3 Nanorods/Graphene Nanocomposites

Metrics

通讯作者: 陈斌, bchen63@163.com

Synthesis and Electrochemical Lithium Storage Performance of WO₃ Nanorods/Graphene Nanocomposites