Citation: GAO Su-Wen, LAN Zhang, WU Wan-Xia, QUE Lan-Fang, WU Ji-Huai, LIN Jian-Ming, HUANG Miao-Liang. Fabrication and Photovoltaic Performance of High Efficiency Front-Illuminated Dye-Sensitized Solar Cell Based on Ordered TiO₂ Nanotube Arrays[J]. Acta Physico-Chimica Sinica, ;2014, 30(3): 446-452. doi: 10.3866/PKU.WHXB201401022 shu

Fabrication and Photovoltaic Performance of High Efficiency Front-Illuminated Dye-Sensitized Solar Cell Based on Ordered TiO₂ Nanotube Arrays

GAO Su-Wen ¹ ,
LAN Zhang ^1,2,3, ,
WU Wan-Xia ¹ ,
QUE Lan-Fang ¹ ,
WU Ji-Huai ^1,2,3 ,
LIN Jian-Ming ^1,2,3 ,
HUANG Miao-Liang ^1,2,3

1.
1 Institute of Materials Physical Chemistry, Huaqiao University, Xiamen 361021, Fujian Province, P. R. China;
2 Engineering Research Center of Environment-Friendly Functional Materials, Ministry of Education, Xiamen 361021, Fujian Province, P. R. China;
3 Key Laboratory of Functional Materials for Fujian Higher Education, Xiamen 361021, Fujian Province, P. R. China

Received Date: 15 November 2013
Available Online: 2 January 2014
Fund Project: 国家自然科学基金(U1205112，51002053)，教育部科技重点项目(212206)，福建省高校杰出青年研究人才计划项目，福建省高校新世纪优秀人才支持计划项目和华侨大学中青年教师科研提升资助计划(ZQN-YX102)资助 (U1205112，51002053)，教育部科技重点项目(212206)，福建省高校杰出青年研究人才计划项目，福建省高校新世纪优秀人才支持计划项目和华侨大学中青年教师科研提升资助计划(ZQN-YX102)

An efficient front-illuminated dye-sensitized solar cell (DSSC) based on ordered TiO₂ nanotube (TNT) arrays was prepared. Sintering at 450 ℃ avoided damage of the ordered TNTs during HF treatment. Fast electron transport channels were maintained in the membrane, for efficient charge transportat in the DSSC. The sintered TNT membranes were subsequently treated with HF, TiCl₄, and HF combined with TiCl₄. This formed a rougher surface, and allowed increased dye loadings. The increased dye loading improved the light harvesting efficiency of the photoanode at 300-570 nm wavelength range, which is the main absorption region of the adsorbed dye. The adsorbed dye had a low absorption at 570-800 nm wavelength range. The enhanced light harvesting efficiency of the photoanode originated from its increased diffuse reflectance. The incident-photon-to-current and absorbed-photon-to-current conversion efficiencies were increased over the entire 300-800 nm wavelength range. This resulted in an increased short-circuit current density of the DSSC. Electrochemical impedance spectroscopy indicated that electron transport and related parameters including charge transport resistance, interfacial charge recombination resistance, distributed chemical capacitance, electron lifetime, effective electron diffusion length, and collection efficiency were significantly improved in the DSSC containing the treated TNT photoanode. This also resulted in an enhanced photovoltaic performance. The maximum power conversion efficiency from combining HF and TiCl₄ treatments was 7.30%, which was a 35.69% enhancement compared with the nontreated DSSC (5.38%).
- TiO₂ nanotube array,
- Dye-sensitized solar cell,
- Photoanode,
- HF,
- TiCl₄
1. [1]
  
  (1) O'Regan, B.; Grätzel, M. Nature 1991, 353, 737. doi: 10.1038/353737a0
2. [2]
  (2) Bella, F.; Bongiovanni, R.; Kumar, R. S.; Kulandainathan, M. A.; Stephanc, A. M. J. Mater. Chem. A 2013, 1, 9033. doi: 10.1039/c3ta12135f
3. [3]
  (3) Xin, X.; He, M.; Han,W.; Jung, J.; Lin, Z. Angew. Chem. Int. Edit. 2011, 50, 11739. doi: 10.1002/anie.201104786
4. [4]
  (4) Grätzel, M. Nature 2001, 414, 338. doi: 10.1038/35104607
5. [5]
  (5) Shu,W.; Liu, Y.; Peng, Z.; Chen, K.; Zhang, C.; Chen,W. J. Alloy. Compd. 2013, 563, 229. doi: 10.1016/j.jallcom.2013.02.086
6. [6]
  (6) Frank, J.; Kopidakis, N.; Lagemaat, J. Coord. Chem. Rev. 2004, 248, 1165. doi: 10.1016/j.ccr.2004.03.015
7. [7]
  (7) (a) Liu, R. H.; Zhang, S.; Xia, X. Y.; Yun, D. Q.; Bian, Z. Q.; Zhao, Y. L. Acta Phys. -Chim. Sin. 2011, 27, 1701. [刘润花, 张森, 夏新元, 云大钦, 卞祖强, 赵永亮. 物理化学学报, 2011, 27, 1701.] doi: 10.3866/PKU.WHXB20110734
8. [8]
  (b) Lan, Z.;Wu, J. H.; Lin, J. M.; Huang, M. L. J. Inorg. Mater. 2011, 26, 119. [兰章, 吴季怀, 林建明, 黄妙良. 无机材料学报, 2011, 26, 119.]
9. [9]
  (8) (a) Xiao, Y. M.;Wu, J. H.; Yue, G. T.; Lin, J. M.; Huang, M. L.; Fan, L. Q.; Lan, Z. Acta Phys. -Chim. Sin. 2012, 28, 578. [肖尧明, 吴季怀, 岳根田, 林建明, 黄妙良, 范乐庆, 兰章. 物理化学学报, 2012, 28, 578.] doi: 10.3866/PKU.WHXB201201032
10. [10]
  (b) Feng, X.; Shankar, K.; Varghese, O. K.; Paulose, M. T.; Latempa, J.; Grimes, C. A. Nano Lett. 2008, 8, 3781.
11. [11]
  (9) (a) Zhang, Z. Y.; Sang, L. X.; Sun, B.; Zhang, X. M.; Ma, C. F. Acta Phys. -Chim. Sin. 2010, 26, 2935. [张知宇, 桑丽霞, 孙彪, 张晓敏, 马重芳. 物理化学学报, 2010, 26, 2935.] doi: 10.3866/PKU.WHXB20101131
12. [12]
  (b) Hyeokapark, J.; Guakang, M. Chem. Commun. 2008, 2867. (10) (a) Li, H. H.; Chen, R. F.; Ma, Z.; Zhang, S. L.; An, Z. F.; Huang,W. Acta Phys. -Chim. Sin. 2011, 27, 1017. [李欢欢,陈润锋, 马琮, 张胜兰, 安众福, 黄维. 物理化学学报, 2011, 27, 1017.] doi: 10.3866/PKU.WHXB20110514
13. [13]
  (b) Mor, G. K.; Shankar, K.; Paulose, M.; Varghese, O. K.; Grimes, G. A. Nano Lett. 2006, 6, 215.
14. [14]
  (11) Jun, Y.; Park, J. H.; Kang, M. G. Chem. Commun. 2012, 48, 6456. doi: 10.1039/c2cc30733b
15. [15]
  (12) (a) Su, Y. L.; Li, Y.; Du, Y. X.; Lei, L. C. Acta Phys. -Chim. Sin. 2011, 27, 939. [苏雅玲, 李轶, 杜瑛珣, 雷乐成. 物理化学学报, 2011, 27, 939.] doi: 10.3866/PKU.WHXB20110401
16. [16]
  (b) Chang,W. T.; Hsueh, Y. C.; Huang, S. H.; Liu, K. I.; Kei, C. C.; Perng, T. P. J. Mater. Chem. A 2013, 1, 1987.
17. [17]
  (13) Zhang, Z.;Wang, P. Energy Environ. Sci. 2012, 5, 6506. doi: 10.1039/c2ee03461a
18. [18]
  (14) Kuang, D.; Brillet, J.; Chen, P.; Takata, M.; Uchida, S.; Miura, H.; Sumioka, K.; Zakeeruddin, S. M.; Grätzel, M. ACS Nano 2008, 2, 1113. doi: 10.1021/nn800174y
19. [19]
  (15) Zhang, T.; Hu, X.; Fang, M.; Zhang, L.;Wang, Z. CrystEngComm 2012, 14, 7656. doi: 10.1039/c2ce25323b
20. [20]
  (16) Tao, L.; Xiong, Y.; Liu, H.; Shen,W. J. Mater. Chem. 2012, 22, 7863. doi: 10.1039/c2jm00005a
21. [21]
  (17) Lan, Z.;Wu, J. H.; Lin, J. M.; Huang, M. L. J. Mater. Chem. 2011, 21, 15552. doi: 10.1039/c1jm12812d
22. [22]
  (18) Lan, Z.;Wu, J. H.; Lin, J. M.; Huang, M. L. J. Mater. Chem. 2012, 22, 3948. doi: 10.1039/c2jm15019k
23. [23]
  (19) Wang, Q.; Moser, J. E.; Grätzel, M. J. Phys. Chem. B 2005, 109, 14945. doi: 10.1021/jp052768h
24. [24]
  (20) Lan, Z.;Wu, J. H.; Lin, J. M.; Huang, M. L. J. Mater. Sci.: Mater. Electron. 2010, 21, 833. doi: 10.1007/s10854-009-0003-4
25. [25]
  (21) Choi, J.; Park, S. H.; Kwon, Y. S.; Lim, J.; Song, I. Y.; Park, T. Chem. Commun. 2012, 48, 8748. doi: 10.1039/c2cc33629d
26. [26]
  (22) Yip, C. T.; Guo, M.; Huang, H.; Zhou, L.;Wang, Y.; Huang, C. Nanoscale 2012, 4, 448. doi: 10.1039/c2nr11317a
27. [27]
  (23) Huang, F.; Chen, D.; Zhang, X. L.; Caruso, R. A.; Cheng, Y. B. Adv. Funct. Mater. 2010, 20, 1301. doi: 10.1002/adfm.v20:8
28. [28]
  (24) Yanagida, M.; Yamaguchi, T.; Kurashige, M.; Hara, K.; Katoh, R.; Sugihara, H.; Arakawa, H. Inorg. Chem. 2003, 42, 7921. doi: 10.1021/ic034674x
29. [29]
  (25) Wang, Z. S.; Li, F. Y.; Huang, C. H. J. Phys. Chem. B 2001, 105, 9210. doi: 10.1021/jp010667n
30. [30]
  (26) Bisquert, J.; Belmonte, G. G.; Santia , F. F.; Ferriols, N. S.; Bogdanoff, P.; Pereira, E. C. J. Phys. Chem. B 2000, 104, 2287. doi: 10.1021/jp993148h
1. [1]
  Jiaxin Su , Jiaqi Zhang , Shuming Chai , Yankun Wang , Sibo Wang , Yuanxing Fang . Optimizing Poly(heptazine imide) Photoanodes Using Binary Molten Salt Synthesis for Water Oxidation Reaction. Acta Physico-Chimica Sinica, 2024, 40(12): 2408012-. doi: 10.3866/PKU.WHXB202408012
2. [2]
  Xiufang Wang , Donglin Zhao , Kehua Zhang , Xiaojie Song . “Preparation of Carbon Nanotube/SnS₂ Photoanode Materials”: A Comprehensive University Chemistry Experiment. University Chemistry, 2024, 39(4): 157-162. doi: 10.3866/PKU.DXHX202308025
3. [3]
  Pengyu Dong , Yue Jiang , Zhengchi Yang , Licheng Liu , Gu Li , Xinyang Wen , Zhen Wang , Xinbo Shi , Guofu Zhou , Jun-Ming Liu , Jinwei Gao . NbSe₂纳米片优化钙钛矿太阳能电池的埋底界面. Acta Physico-Chimica Sinica, 2025, 41(3): 2407025-. doi: 10.3866/PKU.WHXB202407025
4. [4]
  Zeyuan WANG , Songzhi ZHENG , Hao LI , Jingbo WENG , Wei WANG , Yang WANG , Weihai SUN . Effect of I₂ interface modification engineering on the performance of all-inorganic CsPbBr₃ perovskite solar cells. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1290-1300. doi: 10.11862/CJIC.20240021
5. [5]
  Xiaoyao YIN , Wenhao ZHU , Puyao SHI , Zongsheng LI , Yichao WANG , Nengmin ZHU , Yang WANG , Weihai SUN . Fabrication of all-inorganic CsPbBr₃ perovskite solar cells with SnCl₂ interface modification. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 469-479. doi: 10.11862/CJIC.20240309
6. [6]
  Zizheng LU , Wanyi SU , Qin SHI , Honghui PAN , Chuanqi ZHAO , Chengfeng HUANG , Jinguo PENG . Surface state behavior of W doped BiVO₄ photoanode for ciprofloxacin degradation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 591-600. doi: 10.11862/CJIC.20230225
7. [7]
  Yipeng Zhou , Chenxin Ran , Zhongbin Wu . Metacognitive Enhancement in Diversifying Ideological and Political Education within Graduate Course: A Case Study on “Solar Cell Performance Enhancement Technology”. University Chemistry, 2024, 39(6): 151-159. doi: 10.3866/PKU.DXHX202312096
8. [8]
  Yixuan Gao , Lingxing Zan , Wenlin Zhang , Qingbo Wei . Comprehensive Innovation Experiment: Preparation and Characterization of Carbon-based Perovskite Solar Cells. University Chemistry, 2024, 39(4): 178-183. doi: 10.3866/PKU.DXHX202311091
9. [9]
  Zhuoyan Lv , Yangming Ding , Leilei Kang , Lin Li , Xiao Yan Liu , Aiqin Wang , Tao Zhang . Light-Enhanced Direct Epoxidation of Propylene by Molecular Oxygen over CuO_x/TiO₂ Catalyst. Acta Physico-Chimica Sinica, 2025, 41(4): 100038-. doi: 10.3866/PKU.WHXB202408015
10. [10]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
11. [11]
  Jizhou Liu , Chenbin Ai , Chenrui Hu , Bei Cheng , Jianjun Zhang . 六氯锡酸铵促进钙钛矿太阳能电池界面电子转移及其飞秒瞬态吸收光谱研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2402006-. doi: 10.3866/PKU.WHXB202402006
12. [12]
  Yikai Wang , Xiaolin Jiang , Haoming Song , Nan Wei , Yifan Wang , Xinjun Xu , Cuihong Li , Hao Lu , Yahui Liu , Zhishan Bo . 氰基修饰的苝二酰亚胺衍生物作为膜厚不敏感型阴极界面材料用于高效有机太阳能电池. Acta Physico-Chimica Sinica, 2025, 41(3): 2406007-. doi: 10.3866/PKU.WHXB202406007
13. [13]
  Fei ZHOU , Xiaolin JIA . Co₃O₄/TiO₂ composite photocatalyst: Preparation and synergistic degradation performance of toluene. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2232-2240. doi: 10.11862/CJIC.20240236
14. [14]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
15. [15]
  Xing Xiao , Yunling Jia , Wanyu Hong , Yuqing He , Yanjun Wang , Lizhi Zhao , Huiqin An , Zhen Yin . Sulfur-defective ZnIn2S4 nanosheets decorated by TiO2 nanosheets with exposed {001} facets to accelerate charge transfer for efficient photocatalytic hydrogen evolution. Chinese Journal of Structural Chemistry, 2024, 43(12): 100474-100474. doi: 10.1016/j.cjsc.2024.100474
16. [16]
  Shuangxi Li , Huijun Yu , Tianwei Lan , Liyi Shi , Danhong Cheng , Lupeng Han , Dengsong Zhang . NO_x reduction against alkali poisoning over Ce(SO₄)₂-V₂O₅/TiO₂ catalysts by constructing the Ce⁴⁺–SO₄²⁻ pair sites. Chinese Chemical Letters, 2024, 35(5): 108240-. doi: 10.1016/j.cclet.2023.108240
17. [17]
  Jianjun LI , Mingjie REN , Lili ZHANG , Lingling ZENG , Huiling WANG , Xiangwu MENG . UV-assisted degradation of tetracycline hydrochloride by MnFe₂O₄@activated carbon activated persulfate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1869-1880. doi: 10.11862/CJIC.20240187
18. [18]
  Wei HE , Jing XI , Tianpei HE , Na CHEN , Quan YUAN . Application of solar-driven inorganic semiconductor-microbe hybrids in carbon dioxide fixation and biomanufacturing. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 35-44. doi: 10.11862/CJIC.20240364
19. [19]
  Xinxin JING , Weiduo WANG , Hesu MO , Peng TAN , Zhigang CHEN , Zhengying WU , Linbing SUN . Research progress on photothermal materials and their application in solar desalination. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1033-1064. doi: 10.11862/CJIC.20230371
20. [20]
  Yuanyin Cui , Jinfeng Zhang , Hailiang Chu , Lixian Sun , Kai Dai . Rational Design of Bismuth Based Photocatalysts for Solar Energy Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2405016-. doi: 10.3866/PKU.WHXB202405016

Get Citation

PDF

XML

Metrics

PDF Downloads(719)
Abstract views(842)
HTML views(6)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Fabrication and Photovoltaic Performance of High Efficiency Front-Illuminated Dye-Sensitized Solar Cell Based on Ordered TiO2 Nanotube Arrays

Metrics

通讯作者: 陈斌, bchen63@163.com

Fabrication and Photovoltaic Performance of High Efficiency Front-Illuminated Dye-Sensitized Solar Cell Based on Ordered TiO₂ Nanotube Arrays