Citation: ZHONG Xiao-Cong, GUI Jun-Feng, YU Xiao-Ying, LIU Fang-Yang, JIANG Liang-Xing, LAI Yan-Qing, LI Jie, LIU Ye-Xiang. Influence of Alloying Element Nd on the Electrochemical Behavior of Pb-Ag Anode in H₂SO₄ Solution[J]. Acta Physico-Chimica Sinica, ;2014, 30(3): 492-499. doi: 10.3866/PKU.WHXB201312301 shu

Influence of Alloying Element Nd on the Electrochemical Behavior of Pb-Ag Anode in H₂SO₄ Solution

1.
1 School of Metallurgy and Environment, Central South University, Changsha 410083, P. R. China;
2 Powder Metallurgy Research Institute, Central South University, Changsha 410083, P. R. China

Received Date: 1 November 2013
Available Online: 30 December 2013
Fund Project: 国家自然科学基金(51204208，51374240)，国家科技支撑计划课题(2012BAA03B04) (51204208，51374240)，国家科技支撑计划课题(2012BAA03B04)湖南省自然科学基金(13JJ1003)资助项目 (13JJ1003)

Anodic layers and oxygen evolution reaction (OER) of Pb-Ag and Pb-Ag-Nd anodes were investigated by cyclic voltammetry, linear sweep voltammetry (LSV), electrochemical impedance spectroscopy (EIS), and environmental scanning electron microscopy (ESEM). Alloying with Nd promoted the formation of Pb/PbO_n/PbSO₄ (1≤n<2). Nd facilitated the transformation of PbO_n and PbSO₄ to α-PbO₂ and β-PbO₂, at potential above 1.2 V vs Hg/Hg₂SO₄ (saturated K₂SO₄ solution). ESEM and LSV indicated that the anodic layer formed on the Pb-Ag-Nd anode was thicker and more compact than that formed on the Pb-Ag anode. Consequently, the anodic layer on the Pb-Ag-Nd anode could provide better protection for metallic substrates. EIS indicated that the OER was determined by the formation and adsorption of intermediates. Nd enhanced the OER reactivity, because of a smaller adsorption resistance and larger coverage of intermediates at the anodic layer/electrolyte interface. In summary, alloying with Nd can enhance the corrosion resistance and reduce the energy consumption of Pb-Ag anode due to lower anodic potential.
- Electrowinning,
- Anodic layer,
- Passivation,
- Oxygen evolution,
- Corrosion resistance
1. [1]
  
  (1) (a) Lai, Y. Q.; Jiang, L. X.; Li, J.; Zhong, S. P.; Lv, X. J.; Peng, H. Z.; Liu, Y. X. Hydrometallurgy 2010, 102 (1-4), 73. doi: 10.1016/j.hydromet.2010.02.012
2. [2]
  (b) Newnham, R. H. J. Appl. Electrochem. 1992, 22 (2), 116.
3. [3]
  (c) Petrova, M.; Noncheva, Z.; Dobrev, T.; Rashkov, Kunchev, N.; Petrov, D.; Vlaev, S.; Mihnev, V.; Zarev, S. Hydrometallurgy 1996, 40 (3), 319. doi: 10.1016/0304-386X(95)00010-E
4. [4]
  (4) Clancy, M.; Bettles, C. J.; Stuart, A.; Birbilis, N. Hydrometallurgy 2013, 131-132, 144.
5. [5]
  (5) Hong, B.; Jiang, L. X.; Lv, X. J.; Ni, H. F.; Lai, Y. Q.; Li, J.; Liu, Y. X. T. Nonferr. Metal Soc. 2012, 22 (4), 1126. [洪波, 蒋良兴, 吕晓军, 倪恒发, 赖延清, 李劼, 刘业翔. 中国有色金属学报, 2012, 22 (4), 1126.]
6. [6]
  (6) (a) Pavlov, D.; Poulieff, C.; Klaja, E.; Iordanov, N. J. Electrochem. Soc. 1969, 116, 316. doi: 10.1149/1.2411836
7. [7]
  (b) Monahov, B.; Pavlov, D. J. Appl. Electrochem. 1993, 23 (12), 1244.
8. [8]
  (c) Ho, J.; Simpraga, R.; Conway, B. J. Electroanal. Chem. 1994, 366 (1), 147.
9. [9]
  (d) Li, H.; Guo,W. X.; Chen, H. Y.; Finlow, D. E.; Zhou, H.W.; Dou, C. L.; Xiao, G. M.; Peng, S. G.;Wei,W.W.;Wang, H. J. Power Sources 2009, 191 (1), 111.
10. [10]
  (7) Burbank, J. J. Electrochem. Soc. 1959, 106, 369. doi: 10.1149/1.2427362
11. [11]
  (8) (a) Babi , R.; Metiko -Hukovi , M.; Lajqy, N.; Brini , S. J. Power Sources 1994, 52 (1), 17. doi: 10.1016/0378-7753(94)01925-8
12. [12]
  (b) Dobrev, T.; Valchanova, I.; Stefanov, Y.; Magaeva, S. Trans. Inst. Met. Finish. 2009, 87 (3), 136.
13. [13]
  (c) Ijomah, M. J. Electrochem. Soc. 1987, 134 (12), 2960.
14. [14]
  (d) Buchanan, J.; Peter, L. Electrochim. Acta 1988, 33 (1), 127.
15. [15]
  (e) Ijomah, M. J. Appl. Electrochem. 1988, 18 (1), 142.
16. [16]
  (f) Varela, F.; Gassa, L.; Vilche, J. Electrochim. Acta 1992, 37 (6), 1119.
17. [17]
  (9) Sharpe, T. F. J. Electrochem. Soc. 1977, 124 (2), 168. doi: 10.1149/1.2133259
18. [18]
  (10) Czerwinski, A.; Zelazowska, M.; Grden, M.; Kuc, K.; Milewski, J.; Nowacki, A.;Wojcik, G.; Kopczyk, M. J. Power Sources 2000, 85 (1), 49. doi: 10.1016/S0378-7753(99)00381-X
19. [19]
  (11) Guo, Y. L. J. Electrochem. Soc. 1991, 138 (5), 1222. doi: 10.1149/1.2085763
20. [20]
  (12) Sun, Q. J.; Guo, Y. L. J. Electroanal. Chem. 2000, 493 (1), 123.
21. [21]
  (13) Hu, J. M.; Zhang, J. Q.; Cao, C. N. Int. J. Hydrog. Energy 2004, 29 (8), 791. doi: 10.1016/j.ijhydene.2003.09.007
22. [22]
  (14) Rerolle, C.;Wiart, R. Electrochim. Acta 1995, 40 (8), 939. doi: 10.1016/0013-4686(95)00026-B
23. [23]
  (15) (a) Yang, C. J.; Ko, Y.; Park, S. M. Electrochim. Acta 2012, 78, 615. doi: 10.1016/j.electacta.2012.06.055
24. [24]
  (b) Conway, B. E.; Liu, T., Langmuir 1990, 6 (1), 268.
25. [25]
  (c) Li,W.; Chen, H.; Long, X.;Wu, F.;Wu, Y.; Yan, J.; Zhang, C. J. Power Sources 2006, 158 (2), 902.
26. [26]
  (d) Zhang,W.; Houlachi, G. Hydrometallurgy 2010, 104 (2), 129.
27. [27]
  (e) Ye, Z. G.; Meng, H. M.; Sun, D. B. Electrochim. Acta 2008, 53 (18), 5639.
28. [28]
  (16) (a) Palmas, S.; Polcaro, A.; Ferrara, F.; Ruiz, J. R.; Delogu, F.; Bonatto-Minella, C.; Mulas, G. J. Appl. Electrochem. 2008, 38 (7), 907. doi: 10.1007/s10800-008-9494-6
29. [29]
  (b) Cao, C. N. Electrochim. Acta 1990, 35 (5), 831.
30. [30]
  (17) (a) Alves, V.; Da Silva, L.; Boodts, J. Electrochim. Acta 1998, 44 (8-9), 1525. doi: 10.1016/S0013-4686(98)00276-X
31. [31]
  (b) Franco, D. V.; Silva, L. M. D.; Jardim,W. F.; Boodts, J. F. J. Brazil. Chem. Soc. 2006, 17 (4), 446.
32. [32]
  (18) Brug, G. J.; van den Eeden, A. L. G.; Sluyters-Rehbach, M.; Sluyters, J. H. J. Electroanal. Chem. Interfacial Electrochem. 1984, 176 (1-2), 275.
33. [33]
  (19) Martelli, G. N.; Ornelas, R.; Faita, G. Electrochim. Acta 1994, 39 (11-12), 1551.
34. [34]
  (20) Lai, Y. Q.; Li, Y.; Jiang, L. X.; Xu,W.; Lv, X. J.; Li, J.; Liu, Y. X. J. Electroanal. Chem. 2012, 671, 16. doi: 10.1016/j.jelechem.2012.02.011
1. [1]
  Jiao CHEN , Yi LI , Yi XIE , Dandan DIAO , Qiang XIAO . Vapor-phase transport of MFI nanosheets for the fabrication of ultrathin b-axis oriented zeolite membranes. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 507-514. doi: 10.11862/CJIC.20230403
2. [2]
  Yang WANG , Xiaoqin ZHENG , Yang LIU , Kai ZHANG , Jiahui KOU , Linbing SUN . Mn single-atom catalysts based on confined space: Fabrication and the electrocatalytic oxygen evolution reaction performance. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2175-2185. doi: 10.11862/CJIC.20240165
3. [3]
  Lei Shi . Nucleophilicity and Electrophilicity of Radicals. University Chemistry, 2024, 39(11): 131-135. doi: 10.3866/PKU.DXHX202402018
4. [4]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
5. [5]
  Xiufang Wang , Donglin Zhao , Kehua Zhang , Xiaojie Song . “Preparation of Carbon Nanotube/SnS₂ Photoanode Materials”: A Comprehensive University Chemistry Experiment. University Chemistry, 2024, 39(4): 157-162. doi: 10.3866/PKU.DXHX202308025
6. [6]
  Xiao Liu , Guangzhong Cao , Mingli Gao , Hong Wu , Hongyan Feng , Chenxiao Jiang , Tongwen Xu . Seawater Salinity Gradient Energy’s Job Application in the Field of Membranes. University Chemistry, 2024, 39(9): 279-282. doi: 10.3866/PKU.DXHX202306043
7. [7]
  Shuyu Liu , Xiaomin Sun , Bohan Song , Gaofeng Zeng , Bingbing Du , Chongshen Guo , Cong Wang , Lei Wang . Design and Fabrication of Phospholipid-Vesicle-based Artificial Cells towards Biomedical Applications. University Chemistry, 2024, 39(11): 182-188. doi: 10.12461/PKU.DXHX202404113
8. [8]
  Zizheng LU , Wanyi SU , Qin SHI , Honghui PAN , Chuanqi ZHAO , Chengfeng HUANG , Jinguo PENG . Surface state behavior of W doped BiVO₄ photoanode for ciprofloxacin degradation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 591-600. doi: 10.11862/CJIC.20230225
9. [9]
  Kun Li , Na Gao , Shuangyan Huan , Yuzhi Wang . Design of Ideological and Political Education for the Experiment of Detecting Cadmium with Anodic Stripping Voltammetry. University Chemistry, 2024, 39(2): 155-161. doi: 10.3866/PKU.DXHX202307068
10. [10]
  Zongfei YANG , Xiaosen ZHAO , Jing LI , Wenchang ZHUANG . Research advances in heteropolyoxoniobates. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 465-480. doi: 10.11862/CJIC.20230306
11. [11]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
12. [12]
  Wenxiu Yang , Jinfeng Zhang , Quanlong Xu , Yun Yang , Lijie Zhang . Bimetallic AuCu Alloy Decorated Covalent Organic Frameworks for Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312014-. doi: 10.3866/PKU.WHXB202312014
13. [13]
  Shengjuan Huo , Xiaoyan Zhang , Xiangheng Li , Xiangning Li , Tianfang Chen , Yuting Shen . Unveiling the Marvels of Titanium: Popularizing Multifunctional Colored Titanium Product Films. University Chemistry, 2024, 39(5): 184-192. doi: 10.3866/PKU.DXHX202310127
14. [14]
  Lan Ma , Cailu He , Ziqi Liu , Yaohan Yang , Qingxia Ming , Xue Luo , Tianfeng He , Liyun Zhang . Magical Surface Chemistry: Fabrication and Application of Oil-Water Separation Membranes. University Chemistry, 2024, 39(5): 218-227. doi: 10.3866/PKU.DXHX202311046
15. [15]
  Shicheng Yan . Experimental Teaching Design for the Integration of Scientific Research and Teaching: A Case Study on Organic Electrooxidation. University Chemistry, 2024, 39(11): 350-358. doi: 10.12461/PKU.DXHX202408036
16. [16]
  Tianqi Bai , Kun Huang , Fachen Liu , Ruochen Shi , Wencai Ren , Songfeng Pei , Peng Gao , Zhongfan Liu . 石墨烯厚膜热扩散系数与微观结构的关系. Acta Physico-Chimica Sinica, 2025, 41(3): 2404024-. doi: 10.3866/PKU.WHXB202404024
17. [17]
  Yiping HUANG , Liqin TANG , Yufan JI , Cheng CHEN , Shuangtao LI , Jingjing HUANG , Xuechao GAO , Xuehong GU . Hollow fiber NaA zeolite membrane for deep dehydration of ethanol solvent by vapor permeation. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 225-234. doi: 10.11862/CJIC.20240224
18. [18]
  Yongwei ZHANG , Chuang ZHU , Wenbin WU , Yongyong MA , Heng YANG . Efficient hydrogen evolution reaction activity induced by ZnSe@nitrogen doped porous carbon heterojunction. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 650-660. doi: 10.11862/CJIC.20240386
19. [19]
  Jiaxin Su , Jiaqi Zhang , Shuming Chai , Yankun Wang , Sibo Wang , Yuanxing Fang . Optimizing Poly(heptazine imide) Photoanodes Using Binary Molten Salt Synthesis for Water Oxidation Reaction. Acta Physico-Chimica Sinica, 2024, 40(12): 2408012-. doi: 10.3866/PKU.WHXB202408012
20. [20]
  .
  南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积
  . CCS Chemistry, 2025, 7(0): -.

Get Citation

PDF

XML

Metrics

PDF Downloads(602)
Abstract views(686)
HTML views(14)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Influence of Alloying Element Nd on the Electrochemical Behavior of Pb-Ag Anode in H2SO4 Solution

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

Metrics

通讯作者: 陈斌, bchen63@163.com

Influence of Alloying Element Nd on the Electrochemical Behavior of Pb-Ag Anode in H₂SO₄ Solution