Citation: NI Ting, ZOU Fan, JIANG Yu-Rong, YANG Sheng-Yi. To Improve the Efficiency of Bulk Heterojunction Organic Solar Cells by Incorporating CdSe/ZnS Quantum Dots[J]. Acta Physico-Chimica Sinica, ;2014, 30(3): 453-459. doi: 10.3866/PKU.WHXB201312274 shu

To Improve the Efficiency of Bulk Heterojunction Organic Solar Cells by Incorporating CdSe/ZnS Quantum Dots

1.
Beijing Key Laboratory of Nanophotonics and Ultrafine Optoelectronic Systems, School of Optoelectronics and School of Physics, Beijing Institute of Technology, Beijing 100081, P. R. China

Received Date: 23 October 2013
Available Online: 27 December 2013
Fund Project: 国家自然科学基金(60777025)，北京市科技新星合作项目(XXHZ201204)，北京理工大学杰出中青年教师支持计划项目(BIT-JC-201005)以及光电成像与系统教育部重点实验室开放项目(2012OEIOF02)资助 (60777025)，北京市科技新星合作项目(XXHZ201204)，北京理工大学杰出中青年教师支持计划项目(BIT-JC-201005)以及光电成像与系统教育部重点实验室开放项目(2012OEIOF02)

The efficiency of bulk heterojunction solar cells was enhanced by incorporating CdSe/ZnS core-shell colloidal quantum dots (CQDs) into copolymers of poly(3-hexylthiophene (P3HT) and [6,6]-phenyl-C₆₁-butyric acid methyl ester (PCBM) as the active layer, as result of the increased absorption in the visible region. The doping of CdSe/ZnS CQDs in the active layer and the influence of CQD surface ligands on device performance were investigated. A maximum power conversion efficiency (PCE) of 3.99% was obtained from the optimized solar cell ITO/PEDOT:PSS/P3HT:PCBM:(CdSe/ZnS)/Al (ITO: indium-tin oxide; PEDOT: poly(3,4-ethylendioxythiophene; PSS: poly(styrenesulfonate)) under AM1.5 illumination. This was 45.1% improvement on the PCE of the control device ITO/PEDOT:PSS/P3HT:PCBM/Al.
- Bulk heterojunction solar cell,
- CdSe/ZnS core-shell colloidal quantum dot,
- Polymer,
- Ligand exchange,
- Power conversion efficiency
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