Citation: ZHOU Jie, LI Bo-Lin, ZHU Pei-Zhi, LU Xiao-Lin. Vibrational Activity Change of Self-Assembled Monolayers upon Chemical Attachment and Nanoscale Block Revealed by Surface Enhanced Raman Spectroscopy[J]. Acta Physico-Chimica Sinica, ;2014, 30(4): 623-627. doi: 10.3866/PKU.WHXB201312273 shu

Vibrational Activity Change of Self-Assembled Monolayers upon Chemical Attachment and Nanoscale Block Revealed by Surface Enhanced Raman Spectroscopy

ZHOU Jie ¹ ,
LI Bo-Lin ² ,
ZHU Pei-Zhi ³ ,
LU Xiao-Lin ^1,2,

1.
1 Key Laboratory of Advanced Textile Materials and Manufacturing Technology of Education Ministry, Department of Chemistry, Zhejiang Sci-Tech University, Hangzhou 310018, P. R. China;
2 State Key Laboratory of Bioelectronics, School of Biological Science & Medical Engineering, Southeast University, Nanjing 210096, P. R. China;
3 College of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225009, Jiangsu Province, P. R. China

Received Date: 11 October 2013
Available Online: 27 December 2013
Fund Project: 国家自然科学基金(51173169，21004054)，浙江省钱江人才计划(2011R10025)，教育部留学归国人员科研启动基金和浙江省留学人员科技活动项目择优资助项目. 卢晓林还受到江苏高校优势学科建设工程项目(1107037001)资助 (51173169，21004054)，浙江省钱江人才计划(2011R10025)，教育部留学归国人员科研启动基金和浙江省留学人员科技活动项目择优资助项目. 卢晓林还受到江苏高校优势学科建设工程项目(1107037001)

The origin of weak ambiguous vibrational modes in surface enhanced Raman scattering (SERS), i.e., from the high-order effect or symmetry change using 1,4-benzenedithiol (BDT) as a probe, is investigated. Weak ambiguous vibrational modes are caused by symmetry change rather than high-order effect. The experimental method can be extended, e.g., to similar systems excited by lasers with different wavelengths, or microelectronic junctions bridged by organic molecules.
- Surface-enhanced raman scattering,
- High-order effect,
- Symmetry change,
- 1,4-Benzenedithiol,
- Silver nanoparticle
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