Citation: XU Li-Hong, KAN Cai-Xia, WANG Chang-Shun, CONG Bo, NI Yuan, SHI Da-Ning. Synthesis of Ag Nanostructures with Controlled Shapes by a Polyvinylpyrrolidone-Assisted Hydrothermal Method[J]. Acta Physico-Chimica Sinica, ;2014, 30(3): 569-575. doi: 10.3866/PKU.WHXB201312253 shu

Synthesis of Ag Nanostructures with Controlled Shapes by a Polyvinylpyrrolidone-Assisted Hydrothermal Method

XU Li-Hong ¹ ,
KAN Cai-Xia ^1,2, ,
WANG Chang-Shun ¹ ,
CONG Bo ¹ ,
NI Yuan ¹ ,
SHI Da-Ning ^1,

1.
1 Department of Applied Physics, College of Science, Nanjing University of Aeronautics and Astronautics, Nanjing 211106, P. R. China;
2 Key Laboratory for Intelligent Nano Materials and Devices of the Ministry of Education, Nanjing University of Aeronautics and Astronautics, Nanjing 211106, P. R. China

Received Date: 28 October 2013
Available Online: 25 December 2013
Fund Project: 国家自然科学基金(11274173，51032002，61222403，11374159) (11274173，51032002，61222403，11374159)中央高校基本科研业务费专项资金(NZ2013304)资助项目 (NZ2013304)

Ag nanostructures with well-defined shapes and optical resonances have been masssynthesized by a hydrothermal method. Polyvinylpyrrolidone (PVP) polymers with average molecular weights (MW) of 8000, 40000, 160000, and 360000 denoted as K17, K30, K60, and K90, respectively, were chosen as surfactants (K is usually used to represent the characteristic value of relative viscosity of the PVP solution). It was found that the larger MW of PVP, the higher relative viscosity of the PVP solution. All of the reactants were transferred into a 60 mL stainless steel autoclave and heated at a certain temperature for hours. Five-fold twinned Ag nanodecahedrons with nearly uniform size were synthesized in the aqueous solution of K17. Ag nanowires were obtained with the presence of K30, K60, and K90 in ethylene glycol (EG) solution, and the aspect ratios of the Ag nanowires increased with increasing the MW of PVP. The morphology and microstructures of the obtained products were characterized by transmission electron microscopy (TEM) and field emission-scanning electron microscopy (FE-SEM). The surface plasmon resonance (SPR) spectra of the Ag nanostructures were measured using an UV-Vis spectrophotometer. The results showed that the surface plasma resonance of the Ag nanostructures was dependent on their shape and size.
- Ag nanowire,
- Five-fold twinned crystal,
- Decahedron,
- Polyvinylpyrrolidone,
- Growth mechanism
1. [1]
  
  (1) Lu,W.; Lieber, C. M. Nat. Mater. 2007, 6, 841. doi: 10.1038/nmat2028
2. [2]
  (2) Lal, S.; Link, S.; Halas, N. J. Nat. Photonics 2007, 1, 641. doi: 10.1038/nphoton.2007.223
3. [3]
  (3) Xiong, Y.;Wiley, B. J.; Xia, Y. Angew. Chem. Int. Edit. 2007, 46, 7157.
4. [4]
  (4) Feng, M.; Zhang, M.; Song, J.; Li, X.; Yu, S. ACS Nano 2011, 5, 6726. doi: 10.1021/nn202296h
5. [5]
  (5) Pedireddy, S.; Li, A.; Bosman, M.; Phang, I. Y.; Li, S.; Ling, X. Y. J. Phys. Chem. C 2013, 117, 16640. doi: 10.1021/jp4063077
6. [6]
  (6) Mackenzie, J. D.; Bescher, E. P. Accounts Chem. Res. 2007, 40, 810. doi: 10.1021/ar7000149
7. [7]
  (7) Reddy, M. V.; Jose, R.; Teng, T. H.; Chowdari, B. V. R.; Ramakrishna, S. Electrochim. Acta 2010, 55, 3109. doi: 10.1016/j.electacta.2009.12.095
8. [8]
  (8) Koch, C. C. Rev. Adv. Mater. Sci. 2003, 5, 91.
9. [9]
  (9) Zhang, D. L. Prog. Mater. Sci. 2004, 49, 537. doi: 10.1016/S0079-6425(03)00034-3
10. [10]
  (10) Fang, J. Y.; Qin, S. Q.; Zhang, X. A.;Wang, G.;Wang, F.; Chang, S. L. Micro & Nano Lett. 2011, 6, 971. doi: 10.1049/mnl.2011.0480
11. [11]
  (11) Duan, J. Y.; Zhang, Q. X.;Wang, Y. L.; Guan, J. G. Acta Phys. -Chim. Sin. 2009, 25, 1405. [段君元, 章桥新, 王一龙, 官建国. 物理化学学报, 2009, 25, 1405.] doi: 10.3866/PKU.WHXB20090731
12. [12]
  (12) Wu, H.; Kuo, C.; Huang, M. H. Langmuir 2010, 26, 12307. doi: 10.1021/la1015065
13. [13]
  (13) Li, Z. C.; Shang, T. M.; Zhou, Q. F.; Feng, K. Micro & Nano Lett. 2011, 6, 90. doi: 10.1049/mnl.2010.0183
14. [14]
  (14) Silva, J. N.; Saade, J.; Farias, P. M. A.; Falcão, E. H. L. Advances in Nanoparticles 2013, 2, 217. doi: 10.4236/anp.2013.23030
15. [15]
  (15) Wang, Y.; Zheng, Y.; Huang, C. Z.; Xia, Y. J. Am. Chem. Soc. 2013, 135, 1941. doi: 10.1021/ja311503q
16. [16]
  (16) Zhang, Q.; Ge, J.; Pham, T.; ebl, J.; Hu, Y.; Lu, Z.; Yin, Y. Angew. Chem. Int. Edit. 2009, 48, 3516. doi: 10.1002/anie.v48: 19
17. [17]
  (17) Huang, X.; Qi, X.; Huang, Y.; Li, S.; Xue, C.; Gan, C. L.; Boey, F.; Zhang, H. ACS Nano 2010, 4, 6196. doi: 10.1021/nn101803m
18. [18]
  (18) Bordenave, M. D.; Scarpettini, A. F.; Roldán, M. V.; Pellegri, N.; Bragas, A. V. Mater. Chem. Phys. 2013, 139, 100. doi: 10.1016/j.matchemphys.2012.12.061
19. [19]
  (19) Korte, K. E.; Skrabalak, S. E.; Xia, Y. J. Mater. Chem. 2008, 18, 437. doi: 10.1039/b714072j
20. [20]
  (20) Chen, D.; Qiao, X.; Qiu, X.; Chen, J. G.; Jiang, R. J. Colloid Interface Sci. 2010, 344, 286. doi: 10.1016/j.jcis.2009.12.055
21. [21]
  (21) Im, S. H.; Lee, Y. T.;Wiley, B.; Xia, Y. Angew. Chem. Int. Edit. 2005, 117, 2192.
22. [22]
  (22) Kan, C.;Wang, C.; Li, H.; Qi, J.; Zhu, J.; Li, Z.; Shi, D. Small 2010, 6, 1768. doi: 10.1002/smll.201000600
23. [23]
  (23) Sun, Y.; Xia, Y. Science 2002, 298, 2176. doi: 10.1126/science.1077229
24. [24]
  (24) Wiley, B.; Herricks, T.; Sun, Y.; Xia, Y. Nano Lett. 2004, 4, 1733. doi: 10.1021/nl048912c
25. [25]
  (25) Tang, X.; Tsuji, M.; Jiang, P.; Nishio, M.; Jang, S.; Yoon, S. Colloid Surface A 2009, 338, 33. doi: 10.1016/j.colsurfa.2008.12.029
26. [26]
  (26) Zhu, J.; Kan, C.; Zhu, X.;Wan, J.; Han, M.; Zhao, Y.;Wang, B.; Wang, G. J. Mater. Res. 2007, 22, 1479. doi: 10.1557/JMR.2007.0222
27. [27]
  (27) Zhao, T.; Sun, R.; Yu, S.; Zhang, Z.; Zhou, L.; Huang, H.; Du, R. Colloid Surface A 2010, 366, 197. doi: 10.1016/j.colsurfa.2010.06.005
28. [28]
  (28) Kottmann, J. P.; Martin, O. J. F.; Smith, D. R.; Schultz, S. Phys. Rev. B 2001, 64, 235402. doi: 10.1103/PhysRevB.64.235402
29. [29]
  (29) Kottmann, J. P.; Martin, O. J. F.; Smith, D. R.; Schultz, S. Opt. Express 2000, 6, 213. doi: 10.1364/OE.6.000213
30. [30]
  (30) Rycenga, M.; Cobley, C. M.; Zeng, J.; Li,W.; Moran, C. H.; Zhang, Q.; Qin, D.; Xia, Y. Chem. Rev. 2011, 111, 3669. doi: 10.1021/cr100275d
31. [31]
  (31) Kan, C.;Wang, C.; Zhu, J.; Li, H. J. Solid State Chem. 2010, 183, 858. doi: 10.1016/j.jssc.2010.01.021
32. [32]
  (32) u, L.; Chipara, M.; Zaleski, J. M. Chem. Mater. 2007, 19, 1755. doi: 10.1021/cm070160a
33. [33]
  (33) Hu, M.; Gao, J.; Dong, Y.; Yang, S.; Li, R. K. Y. RSC Adv. 2012, 2, 2055. doi: 10.1039/c2ra01162j
34. [34]
  (34) Chen, D.; Qiao, X.; Qiu, X.; Chen, J.; Jiang, R. J. Mater. Sci- Mater. El. 2011, 22, 6. doi: 10.1007/s10854-010-0074-2
35. [35]
  (35) Zhang,W. C.;Wu, X. L.; Chen, H. T.; Gao, Y. J.; Zhu, J.; Huang, G. S.; Chu, P. K. Acta Mater. 2008, 56, 2508. doi: 10.1016/j.actamat.2008.01.043
36. [36]
  (36) Mao, H.; Feng, J.; Ma, X.;Wu, C.; Zhao, X. J. Nanopart. Res. 2012, 14, 1.
37. [37]
  (37) Wang, Z. L. J. Phys. Chem. B 2000, 104, 1153. doi: 10.1021/jp993593c
38. [38]
  (38) Sun, Y.; Mayers, B.; Herricks, T.; Xia, Y. Nano Lett. 2003, 3, 955. doi: 10.1021/nl034312m
39. [39]
  (39) Jiang, P.; Li, S.; Xie, S.; Gao, Y.; Song, L. Chem. -Eur. J. 2004, 10, 4817.
40. [40]
  (40) Sosa, I. O.; Noguez, C.; Barrera, R. G. J. Phys. Chem. B 2003, 107, 6269. doi: 10.1021/jp0274076
41. [41]
  (41) Kan, C.; Zhu, J.; Zhu, X. J. Phys. D: Appl. Phys. 2008, 41, 155304. doi: 10.1088/0022-3727/41/15/155304
42. [42]
  (42) Li, C. R.; Lu, N. P.; Xu, Q.; Mei, J.; Dong,W. J.; Fu, J. L.; Cao, Z. X. J. Cryst. Growth 2011, 319, 88. doi: 10.1016/j.jcrysgro.2011.01.068
43. [43]
  (43) Xia, Y.; Xiong, Y.; Lim, B.; Skrabalak, S. E. Angew. Chem. Int. Edit. 2009, 48, 60. doi: 10.1002/anie.200802248
44. [44]
  (44) Gao, Y.; Jiang, P.; Song, L.;Wang, J. X.; Liu, L. F.; Xiang, Y. J.; Zhang, Z. X.; Zhao, X.W.; Dou, X. Y.; Luo, S. D.; Zhou,W. Y.; Xie, S. S. J. Cryst. Growth 2006, 289, 376. doi: 10.1016/j.jcrysgro.2005.11.123
45. [45]
  (45) Mo, B.; Kan, C. X.; Ke, S. L.; Cong, B.; Xu, L. H. Acta Phys. -Chim. Sin. 2012, 28, 2511. [莫博, 阚彩侠, 柯善林, 从博, 徐丽红. 物理化学学报, 2012, 28, 2511.] doi: 10.3866/PKU.WHXB201208132
1. [1]
  Yingtong FAN , Yujin YAO , Shouhao WAN , Yihang SHEN , Xiang GAO , Cuie ZHAO . Construction of copper tetrakis(4-carboxyphenyl)porphyrin/silver nanowire composite electrode for flexible and transparent supercapacitors. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1309-1317. doi: 10.11862/CJIC.20250043
2. [2]
  Huan LI , Shengyan WANG , Long Zhang , Yue CAO , Xiaohan YANG , Ziliang WANG , Wenjuan ZHU , Wenlei ZHU , Yang ZHOU . Growth mechanisms and application potentials of magic-size clusters of groups Ⅱ-Ⅵ semiconductors. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1425-1441. doi: 10.11862/CJIC.20240088
3. [3]
  Jiahong ZHENG , Jingyun YANG . Preparation and electrochemical properties of hollow dodecahedral CoNi₂S₄ supported by MnO₂ nanowires. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1881-1891. doi: 10.11862/CJIC.20240170
4. [4]
  Yinyin Qian , Rui Xu . Utilizing VESTA Software in the Context of Material Chemistry: Analyzing Twin Crystal Nanostructures in Indium Antimonide. University Chemistry, 2024, 39(3): 103-107. doi: 10.3866/PKU.DXHX202307051
5. [5]
  Tingting Yu , Si Chen , Lianglong Sun , Tongtong Shi , Kai Sun , Xin Wang . Comprehensive Experimental Design for the Photochemical Synthesis, Analysis, and Characterization of Difluoropyrroles. University Chemistry, 2024, 39(11): 196-203. doi: 10.3866/PKU.DXHX202401022
6. [6]
  Yuhao SUN , Qingzhe DONG , Lei ZHAO , Xiaodan JIANG , Hailing GUO , Xianglong MENG , Yongmei GUO . Synthesis and antibacterial properties of silver-loaded sod-based zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 761-770. doi: 10.11862/CJIC.20230169
7. [7]
  Yongming Guo , Jie Li , Chaoyong Liu . Green Improvement and Educational Design in the Synthesis and Characterization of Silver Nanoparticles. University Chemistry, 2024, 39(3): 258-265. doi: 10.3866/PKU.DXHX202309057
8. [8]
  Yongjie ZHANG , Bintong HUANG , Yueming ZHAI . Research progress of formation mechanism and characterization techniques of protein corona on the surface of nanoparticles. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2318-2334. doi: 10.11862/CJIC.20240247
9. [9]
  Huanhuan XIE , Yingnan SONG , Lei LI . Two-dimensional single-layer BiOI nanosheets: Lattice thermal conductivity and phonon transport mechanism. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 702-708. doi: 10.11862/CJIC.20240281
10. [10]
  Jingzhuo Tian , Chaohong Guan , Haobin Hu , Enzhou Liu , Dongyuan Yang . Waste plastics promoted photocatalytic H₂ evolution over S-scheme NiCr₂O₄/twinned-Cd_0.5Zn_0.5S homo-heterojunction. Acta Physico-Chimica Sinica, 2025, 41(6): 100068-0. doi: 10.1016/j.actphy.2025.100068
11. [11]
  Haiyuan Wang , Yiming Tang , Haoran Guo , Guohui Chen , Yajing Sun , Chao Zhao , Zhen Zhang . Comprehensive Chemistry Experimental Teaching Design Based on the Integration of Science and Education: Preparation and Catalytic Properties of Silver Nanomaterials. University Chemistry, 2024, 39(10): 219-228. doi: 10.12461/PKU.DXHX202404067
12. [12]
  Feng Lu , Tao Wang , Qi Wang . Preparation and Characterization of Water-Soluble Silver Nanoclusters: A New Design and Teaching Practice in Materials Chemistry Experiment. University Chemistry, 2025, 40(4): 375-381. doi: 10.12461/PKU.DXHX202406005
13. [13]
  Qin Li , Huihui Zhang , Huajun Gu , Yuanyuan Cui , Ruihua Gao , Wei-Lin Dai . In situ Growth of Cd_0.5Zn_0.5S Nanorods on Ti₃C₂ MXene Nanosheet for Efficient Visible-Light-Driven Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2025, 41(4): 100031-. doi: 10.3866/PKU.WHXB202402016
14. [14]
  Jiaxuan Zuo , Kun Zhang , Jing Wang , Xifei Li . 锂离子电池Ni-Co-Mn基正极材料前驱体的形核调控及机制. Acta Physico-Chimica Sinica, 2025, 41(1): 2404042-. doi: 10.3866/PKU.WHXB202404042
15. [15]
  Mengfei He , Chao Chen , Yue Tang , Si Meng , Zunfa Wang , Liyu Wang , Jiabao Xing , Xinyu Zhang , Jiahui Huang , Jiangbo Lu , Hongmei Jing , Xiangyu Liu , Hua Xu . Epitaxial Growth of Nonlayered 2D MnTe Nanosheets with Thickness-Tunable Conduction for p-Type Field Effect Transistor and Superior Contact Electrode. Acta Physico-Chimica Sinica, 2025, 41(2): 100016-. doi: 10.3866/PKU.WHXB202310029
16. [16]
  Yi DING , Peiyu LIAO , Jianhua JIA , Mingliang TONG . Structure and photoluminescence modulation of silver(Ⅰ)-tetra(pyridin-4-yl)ethene metal-organic frameworks by substituted benzoates. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 141-148. doi: 10.11862/CJIC.20240393
17. [17]
  Li Zhou , Dongyan Tang , Yunchen Du . Focusing on the Cultivation of Outstanding Talents: A “Five in One” Approach to Promoting the Construction of Chemical Experimental and Practical Teaching System. University Chemistry, 2024, 39(7): 121-128. doi: 10.12461/PKU.DXHX202405037
18. [18]
  Zhaoxuan ZHU , Lixin WANG , Xiaoning TANG , Long LI , Yan SHI , Jiaojing SHAO . Application of poly(vinyl alcohol) conductive hydrogel electrolytes in zinc ion batteries. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 893-902. doi: 10.11862/CJIC.20240368
19. [19]
  Laiying Zhang , Yaxian Zhu . Exploring the Silver Family. University Chemistry, 2024, 39(9): 1-4. doi: 10.12461/PKU.DXHX202409015
20. [20]
  Huafeng SHI . Construction of MnCoNi layered double hydroxide@Co-Ni-S amorphous hollow polyhedron composite with excellent electrocatalytic oxygen evolution performance. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1380-1386. doi: 10.11862/CJIC.20240378

Get Citation

PDF

XML

Metrics

PDF Downloads(1017)
Abstract views(1522)
HTML views(108)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142