Citation: CHEN Lai, CHEN Shi, HU Dao-Zhong, SU Yue-Feng, LI Wei-Kang, WANG Zhao, BAO Li-Ying, WU Feng. Crystal Structure and Electrochemical Performance of Lithium-Rich Cathode Materials xLi₂MnO₃·(1-x)LiNi_0.5Mn_0.5O₂ (x=0.1-0.8)[J]. Acta Physico-Chimica Sinica, ;2014, 30(3): 467-475. doi: 10.3866/PKU.WHXB201312252 shu

Crystal Structure and Electrochemical Performance of Lithium-Rich Cathode Materials xLi₂MnO₃·(1-x)LiNi_0.5Mn_0.5O₂ (x=0.1-0.8)

CHEN Lai ¹ ,
CHEN Shi ^1,2 ,
HU Dao-Zhong ³ ,
SU Yue-Feng ^1,2, ,
LI Wei-Kang ¹ ,
WANG Zhao ¹ ,
BAO Li-Ying ^1,2 ,
WU Feng ^1,2

1.
1 Beijing Key Laboratory of Environmental Science and Engineering, School of Chemical Engineering and the Environment, Beijing Institute of Technology, Beijing 100081, P. R. China;
2 National Development Center of Hi-Tech Green Materials, Beijing 100081, P. R. China;
3 China North Vehicle Research Institute, Beijing 100072, P. R. China

Received Date: 24 October 2013
Available Online: 25 December 2013
Fund Project: 国家重点基础研究发展规划项目(973) (2009CB220100)，国家自然科学基金(51102018，21103011)，国家高技术研究发展计划项目(863)(2011AA11A235，SQ2010AA1123116001) (973) (2009CB220100)，国家自然科学基金(51102018，21103011)，国家高技术研究发展计划项目(863)(2011AA11A235，SQ2010AA1123116001)北京理工大学重大项目培育专项计划项目(2013CX01003)资助 (2013CX01003)

A series of lithium-rich cathode materials, xLi₂MnO₃·(1-x)LiNi_0.5Mn_0.5O₂ (x=0.1-0.8), were successfully synthesized by a sol-gel method. X-ray diffraction, scanning electron microscopy, and electrochemical tests were used to investigate the crystal structure, morphology, and electrochemical performance of the as-synthesized materials, respectively. The results showed that the materials with higher Li₂MnO₃ content had higher initial discharge capacity but poorer cycle stability, while the materials with lower Li₂MnO₃ content showed lower discharge capacity but better cycle stability, and the spinel impurity phase was also found. Based on the data, the optimal electrochemical properties were obtained when x=0.5 in xLi₂MnO₃·(1-x)LiNi_0.5Mn_0.5O₂. Moreover, the electrochemical properties were also worthy of attention when x=0.4, 0.6.
- Lithium-ion battery,
- Cathode,
- Li₂MnO₃,
- Crystal structure,
- Electrochemical performance
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Crystal Structure and Electrochemical Performance of Lithium-Rich Cathode Materials xLi2MnO3·(1-x)LiNi0.5Mn0.5O2 (x=0.1-0.8)

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Crystal Structure and Electrochemical Performance of Lithium-Rich Cathode Materials xLi₂MnO₃·(1-x)LiNi_0.5Mn_0.5O₂ (x=0.1-0.8)