Citation: SU Tong-Yu, XIAO Xiao-Jian, YE Meng-Wei, TIAN Xiao-Chun, LIN Jian-Hang, TANG Jing. Preparation of AuPd and Au Microarrays on ITO and Characterization of Electrocatalytic Activity with SECM[J]. Acta Physico-Chimica Sinica, ;2014, 30(2): 325-330. doi: 10.3866/PKU.WHXB201312242 shu

Preparation of AuPd and Au Microarrays on ITO and Characterization of Electrocatalytic Activity with SECM

1.
1 Key Laboratory of Analysis and Detection Technology for Food Safety, Ministry of Education, College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350116, P. R. China;
2 Instrumental Measurement and Analysis Center, Fuzhou University, Fuzhou 350002, P. R. China

Received Date: 29 October 2013
Available Online: 24 December 2013
Fund Project: 国家自然科学基金(21173048，21073038)资助项目 (21173048，21073038)

Au and AuPd arrays were deposited onto an indium tin oxide (ITO) surface by the electrochemical wet stamping method. Agarose stamp with microstructures and solution was used to electrodeposit and generate patterns of a certain thickness. Field emission scanning electron microscopy (FE-SEM), energy-dispersive X-ray analysis (EDX), and atomic force microscopy (AFM) were employed to characterize the morphology and components on the surface. Tip generation-substrate collection (TG-SC) mode and redox-competition (RC) mode of scanning electrochemical microscopy (SECM) combined with cyclic voltammetry were used to explore the electrocatalytic activity of the alloy arrays. In the study of the electrocatalysis, AuPd exhibited higher activity for the reduction of H₂O₂ than pure Au, but lower activity for that of ferrocenemethanol oxide (FcMeOH⁺).
- Agarose,
- AuPd alloy array,
- Electrochemical wet stamping method,
- Scanning electrochemical microscopy
1. [1]
  
  (1) Lee, K. R.; Jung, Y.;Woo, S. I. ACS Combinatorial Science2012, 14, 10. doi: 10.1021/co200056d
2. [2]
  (2) Walsh, D. A.; Fernández, J. L.; Bard, A. J. Journal of The Electrochemical Society 2006, 153, E99.
3. [3]
  (3) Tang,W.; Jayaraman, S.; Jaramillo, T. F.; Stucky, G. D.;McFarland, E.W. Journal of Physical Chemistry C 2009, 113,5014. doi: 10.1021/jp8089209
4. [4]
  (4) Qiu, H.; Zou, F. ACS Applied Materials & Interfaces 2013, 5,6775. doi: 10.1021/am4022472
5. [5]
  (5) Lee, Y.W.; Kim, M.; Kim, Y.; Kang, S.W.; Lee, J. H.; Han, S.W. Journal of Physical Chemistry C 2010, 114, 7689. doi: 10.1021/jp9119588
6. [6]
  (6) Hernández-Fernández, P.; Rojas, S.; Ocón, P.; Gómez de laFuente, J. L.; San Fabián, J.; Sanza, J.; Peña, M. A.; García-García, F. J.; Terreros, P.; Fierro, J. L. G. Journal of Physical Chemistry C 2007, 111, 2913. doi: 10.1021/jp066812k
7. [7]
  (7) Lee, K. R.; Jung, Y.;Woo, S. I. ACS Combinatorial Science2011, 14, 10.
8. [8]
  (8) Choi, S. I.; Lee, S. U.; Kim,W. Y.; Choi, R.; Hong, K.; Nam, K.M.; Han, S.W.; Park, J. T. ACS Applied Materials & Interfaces2012, 4, 6228. doi: 10.1021/am301824w
9. [9]
  (9) Fernández, J. L.; Bard, A. J. Analytical Chemistry 2003, 75,2967. doi: 10.1021/ac0340354
10. [10]
  (10) Calabretta, A.;Wasserberg, D.; Posthuma-Trumpie, G. A.;Subramaniam, V.; van Amerongen, A.; Corradini, R.; Tedeschi,T.; Sforza, S.; Reinhoudt, D. N.; Marchelli, R.; Huskens, J.;Jonkheijm, P. Langmuir 2010, 27, 1536.
11. [11]
  (11) Nagaiah, T. C.; Schäfer, D.; Schuhmann,W.; Dimcheva, N.Analytical Chemistry 2013, 85, 7897.
12. [12]
  (12) Wendeln, C.; Ravoo, B. J. Langmuir 2012, 28, 5527. doi: 10.1021/la204721x
13. [13]
  (13) Lin, C. L.; Rodríguez-López, J. N.; Bard, A. J. Analytical Chemistry 2009, 81, 8868. doi: 10.1021/ac901434a
14. [14]
  (14) Zhang, L.; Zhuang, J. L.; Ma, X. Z.; Tang, J.; Tian, Z.W.Electrochemistry Communications 2007, 9, 2529. doi: 10.1016/j.elecom.2007.07.035
15. [15]
  (15) Tang, J.; Zhuang, J. L.; Zhang, L.;Wang,W. H.; Tian, Z.W.Electrochimica Acta 2008, 53, 5628. doi: 10.1016/j.electacta.2008.03.006
16. [16]
  (16) Tang, J.; Zhang, L.; Tian, X. Journal of Micromechanics and Microengineering 2010, 20, 115030. doi: 10.1088/0960-1317/20/11/115030
17. [17]
  (17) Bowyer,W. J.; Xie, J.; Engstrom, R. C. Analytical Chemistry1996, 68, 2005. doi: 10.1021/ac9512259
18. [18]
  (18) Shan, X.; Diez-Perez, I.;Wang, L.;Wiktor, P.; Gu, Y.; Zhang,L.;Wang,W.; Lu, J.;Wang, S.; ng, Q.; Li, J.; Tao, N. Nat. Nano 2012, 7, 668. doi: 10.1038/nnano.2012.134
19. [19]
  (19) Lin, X.; Zheng, L.; Gao, G.; Chi, Y.; Chen, G. Analytical Chemistry 2012, 84, 7700. doi: 10.1021/ac300875x
20. [20]
  (20) Mezour, M. A.; Cornut, R.; Hussien, E. M.; Morin, M.;Mauzeroll, J. Langmuir 2010, 26, 13000. doi: 10.1021/la100444n
21. [21]
  (21) Dumitrescu, I.; Dudin, P. V.; Edgeworth, J. P.; Macpherson, J.V.; Unwin, P. R. Journal of Physical Chemistry C 2010, 114,2633.
22. [22]
  (22) Sanchez-Sanchez, C. M.; Rodriguez-Lopez, J.; Bard, A. J.Analytical Chemistry 2008, 80, 3254. doi: 10.1021/ac702453n
23. [23]
  (23) Minguzzi, A.; Alpuche-Aviles, M. A.; López, J. R.; Rondinini,S.; Bard, A. J. Analytical Chemistry 2008, 80, 4055. doi: 10.1021/ac8001287
24. [24]
  (24) Weng, Y. C.; Fan, F. R. F.; Bard, A. J. Journal of the American Chemical Society 2005, 127, 17576. doi: 10.1021/ja054812c
25. [25]
  (25) Jayaraman, S.; Hillier, A. C. Journal of Physical Chemistry B2003, 107, 5221. doi: 10.1021/jp0274886
26. [26]
  (26) Zeradjanin, A. R.; Schilling, T.; Seisel, S.; Bron, M.;Schuhmann,W. Analytical Chemistry 2011, 83, 7645. doi: 10.1021/ac200677g
27. [27]
  (27) Nagaiah, T. C.; Maljusch, A.; Chen, X.; Bron, M.; Schuhmann,W. ChemPhysChem 2009, 10, 2711. doi: 10.1002/cphc.v10:15
28. [28]
  (28) Eckhard, K.; Chen, X.; Turcu, F.; Schuhmann,W. Physical Chemistry Chemical Physics 2006, 8, 5359. doi: 10.1039/b609511a
29. [29]
  (29) Mayer, M.; Yang, J.; Gitlin, I.; Gracias, D. H.; Whitesides, G.M. Proteomics 2004, 4, 2366.
30. [30]
  (30) Tang, J.; Tian, X. C.; Pang,W. H.; Liu, Y. Q.; Lin, J. H.Electrochimica Acta 2012, 81, 8. doi: 10.1016/j.electacta.2012.07.048
1. [1]
  Linbao Zhang , Weisi Guo , Shuwen Wang , Ran Song , Ming Li . Electrochemical Oxidation of Sulfides to Sulfoxides. University Chemistry, 2024, 39(11): 204-209. doi: 10.3866/PKU.DXHX202401009
2. [2]
  Shuhui Li , Xucen Wang , Yingming Pan . Exploring the Role of Electrochemical Technologies in Everyday Life. University Chemistry, 2025, 40(3): 302-307. doi: 10.12461/PKU.DXHX202406059
3. [3]
  Zihan Lin , Wanzhen Lin , Fa-Jie Chen . Electrochemical Modifications of Native Peptides. University Chemistry, 2025, 40(3): 318-327. doi: 10.12461/PKU.DXHX202406089
4. [4]
  Liangzhen Hu , Li Ni , Ziyi Liu , Xiaohui Zhang , Bo Qin , Yan Xiong . A Green Chemistry Experiment on Electrochemical Synthesis of Benzophenone. University Chemistry, 2024, 39(6): 350-356. doi: 10.3866/PKU.DXHX202312001
5. [5]
  Cen Zhou , Biqiong Hong , Yiting Chen . Application of Electrochemical Techniques in Supramolecular Chemistry. University Chemistry, 2025, 40(3): 308-317. doi: 10.12461/PKU.DXHX202406086
6. [6]
  Renxiu Zhang , Xin Zhao , Yunfei Zhang . Application of Electrochemical Synthesis in the Teaching of Organic Chemistry. University Chemistry, 2025, 40(4): 174-180. doi: 10.12461/PKU.DXHX202406116
7. [7]
  Yongming Zhu , Huili Hu , Yuanchun Yu , Xudong Li , Peng Gao . Construction and Practice on New Form Stereoscopic Textbook of Electrochemistry for Energy Storage Science and Engineering: Taking Basic Course of Electrochemistry as an Example. University Chemistry, 2024, 39(8): 44-47. doi: 10.3866/PKU.DXHX202312086
8. [8]
  Jinyao Du , Xingchao Zang , Ningning Xu , Yongjun Liu , Weisi Guo . Electrochemical Thiocyanation of 4-Bromoethylbenzene. University Chemistry, 2024, 39(6): 312-317. doi: 10.3866/PKU.DXHX202310039
9. [9]
  Yong Zhou , Jia Guo , Yun Xiong , Luying He , Hui Li . Comprehensive Teaching Experiment on Electrochemical Corrosion in Galvanic Cell for Chemical Safety and Environmental Protection Course. University Chemistry, 2024, 39(7): 330-336. doi: 10.3866/PKU.DXHX202310109
10. [10]
  Zhengli Hu , Jia Wang , Yi-Lun Ying , Shaochuang Liu , Hui Ma , Wenwei Zhang , Jianrong Zhang , Yi-Tao Long . Exploration of Ideological and Political Elements in the Development History of Nanopore Electrochemistry. University Chemistry, 2024, 39(8): 344-350. doi: 10.3866/PKU.DXHX202401072
11. [11]
  Xiangyu CAO , Jiaying ZHANG , Yun FENG , Linkun SHEN , Xiuling ZHANG , Juanzhi YAN . Synthesis and electrochemical properties of bimetallic-doped porous carbon cathode material. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 509-520. doi: 10.11862/CJIC.20240270
12. [12]
  Meifeng Zhu , Jin Cheng , Kai Huang , Cheng Lian , Shouhong Xu , Honglai Liu . Classical Density Functional Theory for Understanding Electrochemical Interface. University Chemistry, 2025, 40(3): 148-152. doi: 10.12461/PKU.DXHX202405166
13. [13]
  Jingwen Wang , Minghao Wu , Xing Zuo , Yaofeng Yuan , Yahao Wang , Xiaoshun Zhou , Jianfeng Yan . Advances in the Application of Electrochemical Regulation in Investigating the Electron Transport Properties of Single-Molecule Junctions. University Chemistry, 2025, 40(3): 291-301. doi: 10.12461/PKU.DXHX202406023
14. [14]
  Zhongyan Cao , Youzhi Xu , Menghua Li , Xiao Xiao , Xianqiang Kong , Deyun Qian . Electrochemically Driven Denitrative Borylation and Fluorosulfonylation of Nitroarenes. University Chemistry, 2025, 40(4): 277-281. doi: 10.12461/PKU.DXHX202407017
15. [15]
  Caixia Lin , Ting Liu , Zhaojiang Shi , Hong Yan , Keyin Ye , Yaofeng Yuan . Innovative Experiment of Electrochemical Dearomative Spirocyclization of N-Acyl Sulfonamides. University Chemistry, 2025, 40(4): 359-366. doi: 10.12461/PKU.DXHX202406107
16. [16]
  Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO₄/NiMoS₄ composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253
17. [17]
  Tiantian MA , Sumei LI , Chengyu ZHANG , Lu XU , Yiyan BAI , Yunlong FU , Wenjuan JI , Haiying YANG . Methyl-functionalized Cd-based metal-organic framework for highly sensitive electrochemical sensing of dopamine. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 725-735. doi: 10.11862/CJIC.20230351
18. [18]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
19. [19]
  Qin ZHU , Jiao MA , Zhihui QIAN , Yuxu LUO , Yujiao GUO , Mingwu XIANG , Xiaofang LIU , Ping NING , Junming GUO . Morphological evolution and electrochemical properties of cathode material LiAl_0.08Mn_1.92O₄ single crystal particles. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1549-1562. doi: 10.11862/CJIC.20240022
20. [20]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115

Get Citation

PDF

XML

Metrics

PDF Downloads(510)
Abstract views(899)
HTML views(12)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142