Citation: HE Yuan-Yuan, ZHANG Jin-Jiang, ZHAO Jian-Wei. Influence of Graphene with Different Oxidation Degrees on Nickel Hydroxide Pseudocapacitor Characterization[J]. Acta Physico-Chimica Sinica, ;2014, 30(2): 297-304. doi: 10.3866/PKU.WHXB201312233 shu

Influence of Graphene with Different Oxidation Degrees on Nickel Hydroxide Pseudocapacitor Characterization

1.
State Key Laboratory of Analytical Chemistry for Life Science, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210008, P. R. China

Received Date: 21 October 2013
Available Online: 23 December 2013
Fund Project: 国家自然科学基金(51071084，21273113，21121091，11204120)与国家科技攻关计划(2012BAF03B05)资助项目 (51071084，21273113，21121091，11204120)与国家科技攻关计划(2012BAF03B05)

We designed a series of models of reduced graphene oxide sheets (rGNOs) with different oxidation degrees and then studied the interactions between oxidation defects on rGNOs and nickel hydroxide (Ni(OH)₂) using density functional theory (DFT). The adsorption energy between the oxygen-containing groups on rGNOs and Ni(OH)₂ is dependent on the oxidation degree of rGNOs. The variations of atomic distances and charge distribution of the oxide-defected graphene after absorbing Ni(OH)₂ suggested that the oxygen-containing groups on rGNOs improve the characteristics of Ni(OH)₂ as a pseudocapacitor. These theoretical results agree well with available experimental observations and give an explanation for some experimental results. We also introduce a simple potentiostatic electrodeposition method, with which Ni(OH)₂ nanoparticles about 5 nm in diameter were effectively dispersed on the substrate via induction of oxidation defects on rGNOs. In the fabrication of Ni(OH)₂/rGNOs, electrochemical reduction of graphene oxide is the key process. The stronger adsorption results in Ni(OH)₂/rGNOs have higher rate pseudocapacitance (1591 F·g^-1 at 5 mV·s^-1) compared with that of Ni(OH)₂ on bare nickel (656 F·g^-1 at 5 mV·s^-1). The variations of the geometries and charge distributions of the rGNOs after absorbing Ni(OH)₂ lead to the lower equivalent series resistance and better frequency response of Ni(OH)₂/rGNOs than Ni(OH)₂/Ni. The high capacitance of Ni(OH)₂/rGNOs indicates that Ni(OH)₂/rGNOs have the potential of being used as the electrode material of pseudocapacitors.
- Nickel hydroxide,
- Oxidation defect,
- Atomic distance,
- Charge distribution,
- Adsorption energy,
- Pseudocapacitance
1. [1]
  
  (1) Levi, E.; fer, Y.; Aurbach, D. Chem. Mater. 2010, 22, 860.doi: 10.1021/cm9016497
2. [2]
  (2) Yuan, Y. F.; Xia, X. H.;Wu, J. B.; Yang, J. L.; Chen, Y. B.; Guo,S. Y. Electrochim. Acta 2011, 56, 2627. doi: 10.1016/j.electacta.2010.12.001
3. [3]
  (3) Pang, S. C.; Anderson, M. A.; Chapman, T.W. J. Electrochem. Soc. 2000, 147, 444. doi: 10.1149/1.1393216
4. [4]
  (4) Aricò, A. S.; Bruce, P.; Scrosati, B.; Tarascon, J. M.; VanSchalkwijk,W. Nature Materials 2005, 4, 366. doi: 10.1038/nmat1368
5. [5]
  (5) Choi, B. G.; Yang, M.; Jung, S. C.; Lee, K. G.; Kim, J. G.; Park,H.; Park, T. J.; Lee, S. B.; Han, Y. K.; Huh, Y. S. ACS Nano2013, 7, 2453. doi: 10.1021/nn305750s
6. [6]
  (6) Yang, X. F.;Wang, G. C.;Wang, R. Y.; Li, X.W. Electrochim. Acta 2010, 55, 5414. doi: 10.1016/j.electacta.2010.04.067
7. [7]
  (7) Pico, F.; Morales, E.; Fernandez, J. A.; Centeno, T. A.; Ibañez,J.; Rojas, R. M.; Amarilla, J. M.; Rojo, J. M. Electrochim. Acta2009, 54, 2239. doi: 10.1016/j.electacta.2008.10.028
8. [8]
  (8) Zhao, D. D.; Bao, S. J.; Zhou,W. J.; Li, H. L. Electrochem. Commun. 2007, 9, 869. doi: 10.1016/j.elecom.2006.11.030
9. [9]
  (9) Zhang, L. L.; Xiong, Z. G.; Zhao, X. S. J. Power Sources 2013,222, 326. doi: 10.1016/j.jpowsour.2012.09.016
10. [10]
  (10) Yang, G.W.; Xu, C. L.; Li, H. L. Chem. Commun. 2008, 6537.
11. [11]
  (11) Yang, D. N.;Wang, R. M.; He, M. S.; Zhang, J.; Liu, Z. F.J. Phys. Chem. B 2005, 109, 7654. doi: 10.1021/jp050083b
12. [12]
  (12) Xu, L. P.; Ding, Y. S.; Chen, C. H.; Zhao, L. L.; Rimkus, C.Chem. Mater. 2008, 20, 308. doi: 10.1021/cm702207w
13. [13]
  (13) Wang, D. B.; Song, C. X.; Hu, Z. S.; Fu, X. J. Phys. Chem. B2005, 109, 1125. doi: 10.1021/jp046797o
14. [14]
  (14) Chen, X.; Chen, X. H.; Zhang, F. Q.; Yang, Z.; Huang, S. M.J. Power Sources 2013, 243, 555. doi: 10.1016/j.jpowsour.2013.04.076
15. [15]
  (15) Zhao, D. D.; Xu, M.W.; Zhou,W. J.; Zhang, J.; Li, H. L.Electrochim. Acta 2008, 53, 2699. doi: 10.1016/j.electacta.2007.07.053
16. [16]
  (16) Kotte da, I. R. M.; Idris, N. H.; Lu, L.;Wang, J. Z.; Liu, H. K.Electrochim. Acta 2011, 56, 5815. doi: 10.1016/j.electacta.2011.03.143
17. [17]
  (17) Li, S. M.;Wang, B.; Liu, J. H.; Yu, M.; An, J.W. Acta Phys. -Chim. Sin. 2012, 28, 2754. [李松梅, 王博, 刘建华,于美, 安军伟. 物理化学学报, 2012, 28, 2754.] doi: 10.3866/PKU.WHXB201208292
18. [18]
  (18) Wang, H. L.; Casalongue, H. S.; Liang, Y. Y.; Dai, H. J. J. Am. Chem. Soc. 2010, 132, 7472. doi: 10.1021/ja102267j
19. [19]
  (19) Frackowiak, E.; Beguin, F. Carbon 2001, 39, 937. doi: 10.1016/S0008-6223(00)00183-4
20. [20]
  (20) Xu, H. B.; Fan, X. Z.; Lu, Y. H.; Zhong, L. A.; Kong, X. F.;Wang, J. Carbon 2010, 48, 3300. doi: 10.1016/j.carbon.2010.04.051
21. [21]
  (21) Fan, X. Z.; Lu, Y. H.; Xu, H. B.; Kong, X. F.;Wang, J. J. Mater. Chem. 2011, 21, 18753. doi: 10.1039/c1jm13214h
22. [22]
  (22) Sun, Z. P.; Lu, X. M. Ind. Eng. Chem. Res. 2012, 51, 9973. doi: 10.1021/ie202706h
23. [23]
  (23) Frisch, M. J.; Trucks, G.W.; Schlegel, H. B.; et al. Gaussian 03,Revision A.01; Gaussian Inc.: Pittsburgh, PA, 2003.
24. [24]
  (24) Zhao, J.W.; Liu, H. M.; Ni,W. B.; Guo, Y.; Yin, X. Acta Phys. -Chim. Sin. 2009, 25, 1472. [赵健伟, 刘洪梅, 倪文彬,郭彦, 尹星. 物理化学学报, 2009, 25, 1472.] doi: 10.3866/PKU.WHXB20090744
25. [25]
  (25) Hummers,W. S.; Offeman, R. E. J. Am. Chem. Soc. 1958, 80,1339. doi: 10.1021/ja01539a017
26. [26]
  (26) Ramesha, G. K.; Sampath, S. J. Phys. Chem. C 2009, 113,7985. doi: 10.1021/jp811377n
27. [27]
  (27) Guo, H. L.;Wang, X. F.; Qian, Q. Y.;Wang, F. B.; Xia, X. H.ACS Nano 2009, 3, 2653. doi: 10.1021/nn900227d
28. [28]
  (28) Gao, F.; Qi, X.W.; Cai, X. L.;Wang, Q. X.; Gao, F.; Sun,W.Thin Solid Films 2012, 520, 5064. doi: 10.1016/j.tsf.2012.03.002
29. [29]
  (29) Zhao, C. M.;Wang, X.;Wang, S. M.;Wang, Y. Y.; Zhao, Y. X.;Zheng,W. T. Int. J. Hydrog. Energy 2012, 37, 11846. doi: 10.1016/j.ijhydene.2012.05.138
30. [30]
  (30) Wang, D. H.; Choi, D.W.; Li, J.; Yang, Z. G.; Nie, Z. M.; Kou,R.; Hu, D. H.;Wang, C. M.; Saraf, L. V.; Zhang, J. G.; Aksay, I.A.; Liu, J. ACS Nano 2009, 3, 907. doi: 10.1021/nn900150y
31. [31]
  (31) Corrigan, D. A.; Bendert, R. M. J. Electrochem. Soc. 1989, 136,723. doi: 10.1149/1.2096717
32. [32]
  (32) Kim, S. J.; Park, G. J.; Kim, B. C.; Chung, J. K.;Wallace, G. G.;Park, S. Y. Synthetic Metals 2012, 161, 2641.
33. [33]
  (33) mez, J.; Kalu, E. E. J. Power Sources 2013, 230, 218. doi: 10.1016/j.jpowsour.2012.12.069
34. [34]
  (34) Zhang,W. K.;Wang, L.; Huang, H.; Gan, Y. P.;Wang, C. T.;Tao, X. Y. Electrochim. Acta 2009, 54, 4760. doi: 10.1016/j.electacta.2009.04.008
35. [35]
  (35) Buglione, L.; Chng, E. L. K.; Ambrosi, A.; Sofer, Z.; Pumera,M. Electrochem. Commun. 2012, 14, 5. doi: 10.1016/j.elecom.2011.09.013
36. [36]
  (36) Li, L.; He, Y. Q.; Chu, X. F.; Li, Y. M.; Sun, F. F.; Huang, H. Z.Acta Phys. -Chim. Sin. 2013, 29, 1681. [李乐, 贺蕴秋, 储晓菲, 李一鸣, 孙芳芳, 黄河洲. 物理化学学报, 2013, 29,1681.] doi: 10.3866/PKU.WHXB201305223
37. [37]
  (37) Zhang, J. T.; Jiang, J.W.; Zhao, X. S. J. Phys. Chem. C 2011,115, 6448. doi: 10.1021/jp200724h
38. [38]
  (38) Jagadale, A. D.; Kumbhar, V. S.; Dhawale, D. S.; Lokhande, C.D. Electrochim. Acta 2013, 98, 32. doi: 10.1016/j.electacta.2013.02.094
39. [39]
  (39) Grden, M.; Alsabet, M.; Jerkiewicz, G. ACS Appl. Mater. Interfaces 2012, 4, 3012. doi: 10.1021/am300380m
40. [40]
  (40) Taberna, P. L.; Simon, P.; Fauvarque, J. F. J. Electrochem. Soc.2003, 150, A292.
41. [41]
  (41) Chmiola, J.; Yushin, G.; Dash, R.; tsi, Y. J. Power Sources2006, 158, 765. doi: 10.1016/j.jpowsour.2005.09.008
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