Citation: NAN Guang-Hua, WANG Jian-Ping, WANG Yan, WANG He, LI Wei, ZHANG Xing-Xiang. Preparation and Properties of Nanoencapsulated Phase Change Materials Containing Polyaniline[J]. Acta Physico-Chimica Sinica, ;2014, 30(2): 338-344. doi: 10.3866/PKU.WHXB201312231 shu

Preparation and Properties of Nanoencapsulated Phase Change Materials Containing Polyaniline

1.
Tianjin Municipal Key Laboratory of Fiber Modification and Functional Fibers, Institute of Functional Fibers, Tianjin Polytechnic University, Tianjin 300387, P. R. China

Received Date: 2 September 2013
Available Online: 23 December 2013
Fund Project: 航空科学基金(201229Q2002) (201229Q2002)天津市科技计划项目(09ZCKFGX02200)资助项目 (09ZCKFGX02200)

Nanocapsules containing polyaniline homodispersed in n-octadecane (n-Oct) were synthesized by free radical emulsion polymerization and in situ polymerization using poly(methyl methacrylate-co- allyl methacrylate) (P(MMA-co-AMA)) as a shell, in which polyaniline was used as the nucleating agent. Furthermore, the surface morphologies, crystallization properties, thermal stabilities, and crystallization process of nanoencapsulated phase change materials (NanoPCMs) were investigated using scanning electron microscopy (SEM), differential scanning calorimetry (DSC), thermogravimetric analysis (TG), and wide-angle X-ray diffraction (WAXD), respectively. The results showed that the addition of aniline as a monomer and polyaniline generated by in situ polymerization had little effect on the morphologies, particle sizes, encapsulation efficiencies, and crystallization process, but the heat resistance properties slightly decreased. Addition of 1.5 g of aniline effectively improved the supercooling crystallization behavior of the nanocapsule.
- Nanoencapsulated phase change material,
- n-Octadecane,
- P(MMA-co-AMA),
- Polyaniline,
- Supercooling
1. [1]
  
  (1) Zhang, X. X.;Wang, X.;Wu,W. J. The Preparation and Application of Encapsulated Phase Change Materials, 1st ed.;Chemical Industry Press: Beijing, 2009; pp 13-73. [张兴祥, 王馨, 吴文健. 相变材料胶囊制备与应用. 北京: 化学工业出版社, 2009: 13-73.]
2. [2]
  (2) Oppenheim, R. C.; Stewart, N. F.; rdon, L.; Patel, H. M.Drug Dev. Ind. Pharm. 1982, 8 (4), 531. doi: 10.3109/03639048209022119
3. [3]
  (3) Florence, A. T. Pharm. Res. 1997, 14 (3), 259. doi: 10.1023/A:1012029517394
4. [4]
  (4) Wang, J. P.; Zhang, X. X. Mater. Rev. 2007, 21 (4), 107. [王建平, 张兴祥. 材料导报, 2007, 21 (4), 107.]
5. [5]
  (5) Cai, L. H.; Zhang, X. X. Mater. Rev. 2002, 16 (12), 61. [蔡利海, 张兴祥. 材料导报, 2002, 16 (12), 61.]
6. [6]
  (6) Mao, H. J.; Yan, H.; Xie, J. Q. J. Funct. Mater. 2006, 37 (7),1022. [毛华军, 晏华, 谢家庆. 功能材料, 2006, 37 (7),1022.]
7. [7]
  (7) Ravikumar, M.; Srinivasan, P. S. S. Journal of Theoretical and Applied Information Technology 2008, 4 (6), 503.
8. [8]
  (8) Yau, Y. H.; Behzad, R. Renewable Sustainable Energy Review2012, 16 (1), 787. doi: 10.1016/j.rser.2011.09.004
9. [9]
  (9) Yamagishi, Y.; Sugeno, T.; Ishige, T.; Takeuchi, H.; Pyatenko, A.T. An Evaluation of Microencapsulated PCM for Use in ColdEnergy Transportation Medium. IECEC 96. Proceedings of the31st Intersociety Energy Conversion Engineering Conference,Washington, DC, USA, Aug. 11-16, 1996; IEEE: New York,NY, USA, 1996; pp 2077-2083.
10. [10]
  (10) Kishimoto, A.; Setoguchi, T.; Yoshikawa, M.; Nakahira, T.Study on Thermal Properties of O/W Emulsions Type LatentHeat Tranportation Media. In Proceedings of 16th Japan Symposium on Thermophysical Properties, 1995; pp 233-240.
11. [11]
  (11) Zhang, X. X.; Fan, Y. F.; Tao, X. M.; Yick, K. L. J. Colloid Interface Sci. 2005, 281 (2), 299. doi: 10.1016/j.jcis.2004.08.046
12. [12]
  (12) Fan, Y. F.; Zhang, X. X.;Wang, X. C.; Li, J.; Zhu, Q. B.Thermochim. Acta 2004, 413 (1), 1.
13. [13]
  (13) Alvarado, J. L.; Marsh, C.; Sohn, C.; Vilceus, M.; Hock, V.;Phetteplace, G.; Newell, T. J. Therm. Anal. Calorim. 2006, 86 (2), 505. doi: 10.1007/s10973-005-7430-0
14. [14]
  (14) Song, Q.W.; Li, Y.; Yuen, M.; Xing, J.W. Journal of Fiber Bioengineering and Informatics 2008, 1 (3), 239. doi: 10.3993/jfbi122008
15. [15]
  (15) Shan, X. L.;Wang, J. P.; Liu, Y.; Zhang, X. X. Acta Phys. -Chim. Sin. 2009, 25 (12), 2590. [单新丽, 王建平,刘妍, 张兴祥. 物理化学学报, 2009, 25 (12), 2590.] doi: 10.3866/PKU.WHXB20091208
16. [16]
  (16) Zhang, X. J.;Wang, J. P.; Zhang, X. X. New Chem. Mater. 2011,39 (1), 45. [张学静, 王建平, 张兴祥. 化工新型材料, 2011, 39 (1), 45.]
17. [17]
  (17) Sirota, E. B.; King, H. E.; Singer, D. M.; Shao, H. H. J. Chem. Phys. 1993, 98 (7), 5809. doi: 10.1063/1.464874
18. [18]
  (18) Wang, H.;Wang, J. P.;Wang, X. C.; Li,W.; Zhang, X. X. Ind. Eng. Chem. Res. 2013, 52 (41), 14706. doi: 10.1021/ie401055r
19. [19]
  (19) Sari, A.; Alkan, C.; Karaipekli, A. Appl. Energy 2010, 87 (5),1529. doi: 10.1016/j.apenergy.2009.10.011
20. [20]
  (20) Zhang, X. X.; Tao, X. M.; Yick, K. L.;Wang, X. C. Colloid Polym. Sci. 2004, 282 (4), 330. doi: 10.1007/s00396-003-0925-y
21. [21]
  (21) Jin, Y.; Lee,W. P.; Musina, Z.; Ding, Y. L. Particuology 2010, 8 (6), 588. doi: 10.1016/j.partic.2010.07.009
1. [1]
  Li Jiang , Changzheng Chen , Yang Su , Hao Song , Yanmao Dong , Yan Yuan , Li Li . Electrochemical Synthesis of Polyaniline and Its Anticorrosive Application: Improvement and Innovative Design of the “Chemical Synthesis of Polyaniline” Experiment. University Chemistry, 2024, 39(3): 336-344. doi: 10.3866/PKU.DXHX202309002
2. [2]
  Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe₃O₄@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239
3. [3]
  Zijian Zhao , Yanxin Shi , Shicheng Li , Wenhong Ruan , Fang Zhu , Jijun Jiang . A New Exploration of the Preparation of Polyacrylic Acid by Free Radical Polymerization Based on the Concept of Green Chemistry. University Chemistry, 2024, 39(5): 315-324. doi: 10.3866/PKU.DXHX202311094
4. [4]
  Yonghui ZHOU , Rujun HUANG , Dongchao YAO , Aiwei ZHANG , Yuhang SUN , Zhujun CHEN , Baisong ZHU , Youxuan ZHENG . Synthesis and photoelectric properties of fluorescence materials with electron donor-acceptor structures based on quinoxaline and pyridinopyrazine, carbazole, and diphenylamine derivatives. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 701-712. doi: 10.11862/CJIC.20230373
5. [5]
  Limei CHEN , Mengfei ZHAO , Lin CHEN , Ding LI , Wei LI , Weiye HAN , Hongbin WANG . Preparation and performance of paraffin/alkali modified diatomite/expanded graphite composite phase change thermal storage material. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 533-543. doi: 10.11862/CJIC.20230312
6. [6]
  Ping Song , Nan Zhang , Jie Wang , Rui Yan , Zhiqiang Wang , Yingxue Jin . Experimental Teaching Design on Synthesis and Antitumor Activity Study of Cu-Pyropheophorbide-a Methyl Ester. University Chemistry, 2024, 39(6): 278-286. doi: 10.3866/PKU.DXHX202310087
7. [7]
  Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO₂/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1461-1473. doi: 10.11862/CJIC.20240189
8. [8]
  Geyang Song , Dong Xue , Gang Li . Recent Advances in Transition Metal-Catalyzed Synthesis of Anilines from Aryl Halides. University Chemistry, 2024, 39(2): 321-329. doi: 10.3866/PKU.DXHX202308030
9. [9]
  Tingting Yu , Si Chen , Lianglong Sun , Tongtong Shi , Kai Sun , Xin Wang . Comprehensive Experimental Design for the Photochemical Synthesis, Analysis, and Characterization of Difluoropyrroles. University Chemistry, 2024, 39(11): 196-203. doi: 10.3866/PKU.DXHX202401022
10. [10]
  Guang Huang , Lei Li , Dingyi Zhang , Xingze Wang , Yugai Huang , Wenhui Liang , Zhifen Guo , Wenmei Jiao . Cobalt’s Valor, Nickel’s Foe: A Comprehensive Chemical Experiment Utilizing a Cobalt-based Imidazolate Framework for Nickel Ion Removal. University Chemistry, 2024, 39(8): 174-183. doi: 10.3866/PKU.DXHX202311051
11. [11]
  Ruming Yuan , Pingping Wu , Laiying Zhang , Xiaoming Xu , Gang Fu . Patriotic Devotion, Upholding Integrity and Innovation, Wholeheartedly Nurturing the New: The Ideological and Political Design of the Experiment on Determining the Thermodynamic Functions of Chemical Reactions by Electromotive Force Method. University Chemistry, 2024, 39(4): 125-132. doi: 10.3866/PKU.DXHX202311057
12. [12]
  Yuting ZHANG , Zunyi LIU , Ning LI , Dongqiang ZHANG , Shiling ZHAO , Yu ZHAO . Nickel vanadate anode material with high specific surface area through improved co-precipitation method: Preparation and electrochemical properties. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2163-2174. doi: 10.11862/CJIC.20240204
13. [13]
  Lirui Shen , Kun Liu , Ying Yang , Dongwan Li , Wengui Chang . Synthesis and Application of Decanedioic Acid-N-Hydroxysuccinimide Ester: Exploration of Teaching Reform in Comprehensive Applied Chemistry Experiment. University Chemistry, 2024, 39(8): 212-220. doi: 10.3866/PKU.DXHX202312035
14. [14]
  Jinghua Wang , Yanxin Yu , Yanbiao Ren , Yesheng Wang . Integration of Science and Education: Investigation of Tributyl Citrate Synthesis under the Promotion of Hydrate Molten Salts for Research and Innovation Training. University Chemistry, 2024, 39(11): 232-240. doi: 10.3866/PKU.DXHX202402057
15. [15]
  Yunxin Xu , Wenbo Zhang , Jing Yan , Wangchang Geng , Yi Yan . A Fascinating Saga of “Energetic Materials”. University Chemistry, 2024, 39(9): 266-272. doi: 10.3866/PKU.DXHX202307008
16. [16]
  . . Chinese Journal of Inorganic Chemistry, 2024, 40(11): 0-0.
17. [17]
  . . Chinese Journal of Inorganic Chemistry, 2024, 40(12): 0-0.
18. [18]
  Xianfei Chen , Wentao Zhang , Haiying Du . Experimental Design of Computational Materials Science Based on Scientific Research Cases. University Chemistry, 2025, 40(3): 52-61. doi: 10.3866/PKU.DXHX202403112
19. [19]
  Xianggui Kong , Wenying Shi . Comprehensive Chemical Experimental Design of Optically Encrypted Materials. University Chemistry, 2025, 40(3): 355-362. doi: 10.12461/PKU.DXHX202406067
20. [20]
  Tiantian MA , Sumei LI , Chengyu ZHANG , Lu XU , Yiyan BAI , Yunlong FU , Wenjuan JI , Haiying YANG . Methyl-functionalized Cd-based metal-organic framework for highly sensitive electrochemical sensing of dopamine. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 725-735. doi: 10.11862/CJIC.20230351

Get Citation

PDF

XML

Metrics

PDF Downloads(776)
Abstract views(748)
HTML views(5)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142