Citation: LI Na, CHEN Xi, XUE Qi-Kun. Contribution of Chemical Bonding to the Force in Atomic Force Microscopy[J]. Acta Physico-Chimica Sinica, ;2014, 30(2): 205-209. doi: 10.3866/PKU.WHXB201312131 shu

Contribution of Chemical Bonding to the Force in Atomic Force Microscopy

1.
State Key Laboratory of Low-Dimensional Quantum Physics and Department of Physics, Tsinghua University, Beijing 100084, P. R. China

Received Date: 20 November 2013
Available Online: 13 December 2013
Fund Project: 国家自然科学基金(10974111)资助项目 (10974111)

Non-contact atomic force microscope (NC-AFM) has become a powerful tool. It can provide the atomic structure and chemical bonding information at the atomic scale. Three kinds of tip- sample interactions are often concerned: including van der Waals interaction, electrostatic interaction, and chemical bonding interaction. In this work, the chemical bonding interaction between the tip and a Pb film is clearly demonstrated by NC-AFM based on a Q-plus force sensor. The tip-sample interaction energy versus the bias voltage was obtained and fitted by a parabolic function to find the effective local contact potential difference, which decreased with increasing tip- sample distance. Such a trend is caused by the wave function overlap. Thus, the decay length of the electron wave function was estimated. Oscillation of the decay length with film thickness was also observed, which can be attributed to the thickness-dependent quantum well states in the Pb islands.
- Atomic force microscopy,
- Q-plus sensor,
- Local contact potential difference,
- Chemical bond,
- Quantum size effect
1. [1]
  
  (1) Binnig, G.; Quate, C. F. Phys. Rev. Lett. 1986, 56, 930. doi: 10.1103/PhysRevLett.56.930
2. [2]
  (2) Orisaka, S.; Minobe, T.; Uchihashi, T.; Sugawara, Y.; Morita, S.Appl. Surf. Sci. 1999, 140, 243. doi: 10.1016/S0169-4332(98)00534-0
3. [3]
  (3) Bammerlin, M.; Lüthi, R.; Meyer, E.; Baraoff, A.; Lü, J.;Guggisberg, M.; Loppacher, C.; Gerber, C.; Güntherodt, H. J.Appl. Phys. A 1998, 66, S293.
4. [4]
  (4) Giessibl, F. J. Science 1995, 267, 68. doi: 10.1126/science.267.5194.68
5. [5]
  (5) Fukui, K.; Onishi, H.; Iwasawa, Y. Phys. Rev. Lett. 1997, 79,4202. doi: 10.1103/PhysRevLett.79.4202
6. [6]
  (6) Oyabu, N.; Custance, ó.; Yi, I.; Sugawara, Y.; Morita, S. Phys. Rev. Lett. 2003, 90, 176102. doi: 10.1103/PhysRevLett.90.176102
7. [7]
  (7) Oyabu, N.; Sugimoto, Y.; Abe, M.; Custance, ó.; Morita, S.Nanotechnology 2005, 16, S112.
8. [8]
  (8) Sugimoto, Y.; Abe, M.; Hirayama, S.; Oyabu, N.; Custance, ó.;Morita, S. Nat. Mater. 2005, 4, 156. doi: 10.1038/nmat1297
9. [9]
  (9) Sugimoto, Y.; Pou, P.; Custance, O.; Jelinek, P.; Abe, M.; Perez,R.; Morita, S. Science 2008, 322, 413. doi: 10.1126/science.1160601
10. [10]
  (10) Ternes, M.; Luts, C. P.; Hirjibehedin, C. F.; Giessibl, F. J.;Heinrich, A. J. Science 2008, 319, 1066. doi: 10.1126/science.1150288
11. [11]
  (11) Sugimoto, Y.; Pou, P.; Abe, M.; Jelinek, P.; Perez, R.; Morita, S.;Custance, ó. Nature 2007, 446, 64. doi: 10.1038/nature05530
12. [12]
  (12) Gross, L.; Mohn, F.; Liljeroth, P.; Repp, J.; Giessibl, F. J.;Meyer, G. Science 2009, 324, 1428. doi: 10.1126/science.1172273
13. [13]
  (13) Gross, L.; Mohn, F.; Moll, N.; Liljeroth, P.; Meyer, G. Science2009, 325, 1110. doi: 10.1126/science.1176210
14. [14]
  (14) Mohn, F.; Gross, L.; Moll, N.; Meyer, G. Nature Nanotech.2012, 7, 227. doi: 10.1038/nnano.2012.20
15. [15]
  (15) de Oteyza, D. G.; rman, P.; Chen, Y. C.; Wickenburg, S.;Riss, A.; Mowbray, D. J.; Etkin, G.; Pedramrazi, Z.; Tsai, H. Z.;Rubio, A.; Crommie, M. F.; Fischer, F. R. Science 2013, 340,1434. doi: 10.1126/science.1238187
16. [16]
  (16) Martin, Y.; Wickramasinghe, H. K. Appl. Phys. Lett. 1987, 50,1455. doi: 10.1063/1.97800
17. [17]
  (17) Nonnenmacher, M. O.; Boyle, M. P.; Wickramasinghe, H. K.Appl. Phys. Lett. 1991, 58, 2921. doi: 10.1063/1.105227
18. [18]
  (18) Li, J. L.; Jia, J. F.; Liang, X. J.; Liu, X.; Wang, J. Z.; Xue, Q. K.;Li, Z. Q.; Tse, J. S.; Zhang, Z. Y.; Zhang, S. B. Phys. Rev. Lett.2002, 88, 066101. doi: 10.1103/PhysRevLett.88.066101
19. [19]
  (19) Paggel, J. J.; Chiang, T. C. Science 1999, 283, 1709. doi: 10.1126/science.283.5408.1709
20. [20]
  (20) Chiang, T. C. Surf. Sci. Rep. 2000, 39, 181. doi: 10.1016/S0167-5729(00)00006-6
21. [21]
  (21) Guo, Y.; Zhang, Y. F.; Bao, X. Y.; Han, T. Z.; Tang, Z.; Zhang,L. X.; Zhu, W. G.; Wang, E. G.; Niu, Q.; Qiu, Z. Q.; Jia, J. F.;Zhao, Z. X.; Xue, Q. K. Science 2004, 306, 1915. doi: 10.1126/science.1105130
22. [22]
  (22) Qi, Y.; Ma, X. C.; Jiang, P.; Ji, S. H.; Fu, Y. S.; Jia, J. F.; Xue, Q.K.; Zhang, S. B. Appl. Phys. Lett. 2007, 90, 013109. doi: 10.1063/1.2403926
23. [23]
  (23) Chan, T. L.; Wang, C. Z.; Hupalo, M.; Tringides, M. C.; Hou, K.M. Phys. Rev. Lett. 2006, 96, 226102. doi: 10.1103/PhysRevLett.96.226102
24. [24]
  (24) Ma, L. Y.; Tang, L.; Guan, Z. L.; He, K.; An, K.; Ma, X. C.; Jia,J. F.; Xue, Q. K. Phys. Rev. Lett. 2006, 97, 266102. doi: 10.1103/PhysRevLett.97.266102
25. [25]
  (25) Fu, Y. S.; Ji, S. H.; Chen, X.; Ma, X. C.;Wu, R.; Wang, C. C.;Duan, W. H.; Qiu, X. H.; Sun, B.; Zhang, P.; Jia, J. F.; Xue, Q.K. Phys. Rev. Lett. 2007, 99, 256601. doi: 10.1103/PhysRevLett.99.256601
26. [26]
  (26) Ma, X. C.; Jiang, P.; Qi, Y.; Jia, J. F.; Yang, Y.; Duan, W. H.; Li,W. X.; Bao, X. H.; Zhang, S. B.; Xue, Q. K. Proc. Natl. Acad. Sci. U. S. A. 2007, 104, 9204. doi: 10.1073/pnas.0611024104
27. [27]
  (27) Song, C. L.; Wang, Y. L.; Ning, Y. X.; Jia, J. F.; Chen, X.; Sun,B.; Zhang, P.; Xue, Q. K.; Ma, X. C. J. Am. Chem. Soc. 2010,132, 1456. doi: 10.1021/ja908040g
28. [28]
  (28) Altfeder, I. B.; Matveev, K. A.; Chen, D. M. Phys. Rev. Lett.1997, 78, 2815. doi: 10.1103/PhysRevLett.78.2815
29. [29]
  (29) Sader, J. E.; Jarvis, S. P. Appl. Phys. Lett. 2004, 84, 1801. doi: 10.1063/1.1667267
30. [30]
  (30) Chen, C. J. Nanotechnology 2005, 16, S27.
31. [31]
  (31) Weiymouth, A. J.; Wutscher, T.; Welker, J.; Hofmann, T.;Giessibl, F. J. Phys. Rev. Lett. 2011, 106, 226801. doi: 10.1103/PhysRevLett.106.226801
32. [32]
  (32) Guggisberg, M.; Bammerlin, M.; Loppacher, C.; Pfeiffer, O.;Abdurixit, A.; Barwich, V.; Bennewitz, R.; Baratoff, A.; Meyer,E.; Güntherodt, H. J. Phys. Rev. B 2000, 61, 11151. doi: 10.1103/PhysRevB.61.11151
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