Citation: LI Na, CHEN Xi, XUE Qi-Kun. Contribution of Chemical Bonding to the Force in Atomic Force Microscopy[J]. Acta Physico-Chimica Sinica, ;2014, 30(2): 205-209. doi: 10.3866/PKU.WHXB201312131 shu

Contribution of Chemical Bonding to the Force in Atomic Force Microscopy

1.
State Key Laboratory of Low-Dimensional Quantum Physics and Department of Physics, Tsinghua University, Beijing 100084, P. R. China

Received Date: 20 November 2013
Available Online: 13 December 2013
Fund Project: 国家自然科学基金(10974111)资助项目 (10974111)

Non-contact atomic force microscope (NC-AFM) has become a powerful tool. It can provide the atomic structure and chemical bonding information at the atomic scale. Three kinds of tip- sample interactions are often concerned: including van der Waals interaction, electrostatic interaction, and chemical bonding interaction. In this work, the chemical bonding interaction between the tip and a Pb film is clearly demonstrated by NC-AFM based on a Q-plus force sensor. The tip-sample interaction energy versus the bias voltage was obtained and fitted by a parabolic function to find the effective local contact potential difference, which decreased with increasing tip- sample distance. Such a trend is caused by the wave function overlap. Thus, the decay length of the electron wave function was estimated. Oscillation of the decay length with film thickness was also observed, which can be attributed to the thickness-dependent quantum well states in the Pb islands.
- Atomic force microscopy,
- Q-plus sensor,
- Local contact potential difference,
- Chemical bond,
- Quantum size effect
1. [1]
  
  (1) Binnig, G.; Quate, C. F. Phys. Rev. Lett. 1986, 56, 930. doi: 10.1103/PhysRevLett.56.930
2. [2]
  (2) Orisaka, S.; Minobe, T.; Uchihashi, T.; Sugawara, Y.; Morita, S.Appl. Surf. Sci. 1999, 140, 243. doi: 10.1016/S0169-4332(98)00534-0
3. [3]
  (3) Bammerlin, M.; Lüthi, R.; Meyer, E.; Baraoff, A.; Lü, J.;Guggisberg, M.; Loppacher, C.; Gerber, C.; Güntherodt, H. J.Appl. Phys. A 1998, 66, S293.
4. [4]
  (4) Giessibl, F. J. Science 1995, 267, 68. doi: 10.1126/science.267.5194.68
5. [5]
  (5) Fukui, K.; Onishi, H.; Iwasawa, Y. Phys. Rev. Lett. 1997, 79,4202. doi: 10.1103/PhysRevLett.79.4202
6. [6]
  (6) Oyabu, N.; Custance, ó.; Yi, I.; Sugawara, Y.; Morita, S. Phys. Rev. Lett. 2003, 90, 176102. doi: 10.1103/PhysRevLett.90.176102
7. [7]
  (7) Oyabu, N.; Sugimoto, Y.; Abe, M.; Custance, ó.; Morita, S.Nanotechnology 2005, 16, S112.
8. [8]
  (8) Sugimoto, Y.; Abe, M.; Hirayama, S.; Oyabu, N.; Custance, ó.;Morita, S. Nat. Mater. 2005, 4, 156. doi: 10.1038/nmat1297
9. [9]
  (9) Sugimoto, Y.; Pou, P.; Custance, O.; Jelinek, P.; Abe, M.; Perez,R.; Morita, S. Science 2008, 322, 413. doi: 10.1126/science.1160601
10. [10]
  (10) Ternes, M.; Luts, C. P.; Hirjibehedin, C. F.; Giessibl, F. J.;Heinrich, A. J. Science 2008, 319, 1066. doi: 10.1126/science.1150288
11. [11]
  (11) Sugimoto, Y.; Pou, P.; Abe, M.; Jelinek, P.; Perez, R.; Morita, S.;Custance, ó. Nature 2007, 446, 64. doi: 10.1038/nature05530
12. [12]
  (12) Gross, L.; Mohn, F.; Liljeroth, P.; Repp, J.; Giessibl, F. J.;Meyer, G. Science 2009, 324, 1428. doi: 10.1126/science.1172273
13. [13]
  (13) Gross, L.; Mohn, F.; Moll, N.; Liljeroth, P.; Meyer, G. Science2009, 325, 1110. doi: 10.1126/science.1176210
14. [14]
  (14) Mohn, F.; Gross, L.; Moll, N.; Meyer, G. Nature Nanotech.2012, 7, 227. doi: 10.1038/nnano.2012.20
15. [15]
  (15) de Oteyza, D. G.; rman, P.; Chen, Y. C.; Wickenburg, S.;Riss, A.; Mowbray, D. J.; Etkin, G.; Pedramrazi, Z.; Tsai, H. Z.;Rubio, A.; Crommie, M. F.; Fischer, F. R. Science 2013, 340,1434. doi: 10.1126/science.1238187
16. [16]
  (16) Martin, Y.; Wickramasinghe, H. K. Appl. Phys. Lett. 1987, 50,1455. doi: 10.1063/1.97800
17. [17]
  (17) Nonnenmacher, M. O.; Boyle, M. P.; Wickramasinghe, H. K.Appl. Phys. Lett. 1991, 58, 2921. doi: 10.1063/1.105227
18. [18]
  (18) Li, J. L.; Jia, J. F.; Liang, X. J.; Liu, X.; Wang, J. Z.; Xue, Q. K.;Li, Z. Q.; Tse, J. S.; Zhang, Z. Y.; Zhang, S. B. Phys. Rev. Lett.2002, 88, 066101. doi: 10.1103/PhysRevLett.88.066101
19. [19]
  (19) Paggel, J. J.; Chiang, T. C. Science 1999, 283, 1709. doi: 10.1126/science.283.5408.1709
20. [20]
  (20) Chiang, T. C. Surf. Sci. Rep. 2000, 39, 181. doi: 10.1016/S0167-5729(00)00006-6
21. [21]
  (21) Guo, Y.; Zhang, Y. F.; Bao, X. Y.; Han, T. Z.; Tang, Z.; Zhang,L. X.; Zhu, W. G.; Wang, E. G.; Niu, Q.; Qiu, Z. Q.; Jia, J. F.;Zhao, Z. X.; Xue, Q. K. Science 2004, 306, 1915. doi: 10.1126/science.1105130
22. [22]
  (22) Qi, Y.; Ma, X. C.; Jiang, P.; Ji, S. H.; Fu, Y. S.; Jia, J. F.; Xue, Q.K.; Zhang, S. B. Appl. Phys. Lett. 2007, 90, 013109. doi: 10.1063/1.2403926
23. [23]
  (23) Chan, T. L.; Wang, C. Z.; Hupalo, M.; Tringides, M. C.; Hou, K.M. Phys. Rev. Lett. 2006, 96, 226102. doi: 10.1103/PhysRevLett.96.226102
24. [24]
  (24) Ma, L. Y.; Tang, L.; Guan, Z. L.; He, K.; An, K.; Ma, X. C.; Jia,J. F.; Xue, Q. K. Phys. Rev. Lett. 2006, 97, 266102. doi: 10.1103/PhysRevLett.97.266102
25. [25]
  (25) Fu, Y. S.; Ji, S. H.; Chen, X.; Ma, X. C.;Wu, R.; Wang, C. C.;Duan, W. H.; Qiu, X. H.; Sun, B.; Zhang, P.; Jia, J. F.; Xue, Q.K. Phys. Rev. Lett. 2007, 99, 256601. doi: 10.1103/PhysRevLett.99.256601
26. [26]
  (26) Ma, X. C.; Jiang, P.; Qi, Y.; Jia, J. F.; Yang, Y.; Duan, W. H.; Li,W. X.; Bao, X. H.; Zhang, S. B.; Xue, Q. K. Proc. Natl. Acad. Sci. U. S. A. 2007, 104, 9204. doi: 10.1073/pnas.0611024104
27. [27]
  (27) Song, C. L.; Wang, Y. L.; Ning, Y. X.; Jia, J. F.; Chen, X.; Sun,B.; Zhang, P.; Xue, Q. K.; Ma, X. C. J. Am. Chem. Soc. 2010,132, 1456. doi: 10.1021/ja908040g
28. [28]
  (28) Altfeder, I. B.; Matveev, K. A.; Chen, D. M. Phys. Rev. Lett.1997, 78, 2815. doi: 10.1103/PhysRevLett.78.2815
29. [29]
  (29) Sader, J. E.; Jarvis, S. P. Appl. Phys. Lett. 2004, 84, 1801. doi: 10.1063/1.1667267
30. [30]
  (30) Chen, C. J. Nanotechnology 2005, 16, S27.
31. [31]
  (31) Weiymouth, A. J.; Wutscher, T.; Welker, J.; Hofmann, T.;Giessibl, F. J. Phys. Rev. Lett. 2011, 106, 226801. doi: 10.1103/PhysRevLett.106.226801
32. [32]
  (32) Guggisberg, M.; Bammerlin, M.; Loppacher, C.; Pfeiffer, O.;Abdurixit, A.; Barwich, V.; Bennewitz, R.; Baratoff, A.; Meyer,E.; Güntherodt, H. J. Phys. Rev. B 2000, 61, 11151. doi: 10.1103/PhysRevB.61.11151
1. [1]
  Rui Li , Jiayu Zhang , Anyang Li . Two Levels of Understanding of Chemical Bonds: a Case of the Bonding Model of Hypervalent Molecules. University Chemistry, 2024, 39(2): 392-398. doi: 10.3866/PKU.DXHX202308051
2. [2]
  Jiarong Feng , Yejie Duan , Chu Chu , Dezhen Xie , Qiu'e Cao , Peng Liu . Preparation and Application of a Streptomycin Molecularly Imprinted Electrochemical Sensor: A Suggested Comprehensive Analytical Chemical Experiment. University Chemistry, 2024, 39(8): 295-305. doi: 10.3866/PKU.DXHX202401016
3. [3]
  Linhan Tian , Changsheng Lu . Discussion on Sextuple Bonding in Diatomic Motifs of Chromium Family Elements. University Chemistry, 2024, 39(8): 395-402. doi: 10.3866/PKU.DXHX202401056
4. [4]
  Ruming Yuan , Pingping Wu , Laiying Zhang , Xiaoming Xu , Gang Fu . Patriotic Devotion, Upholding Integrity and Innovation, Wholeheartedly Nurturing the New: The Ideological and Political Design of the Experiment on Determining the Thermodynamic Functions of Chemical Reactions by Electromotive Force Method. University Chemistry, 2024, 39(4): 125-132. doi: 10.3866/PKU.DXHX202311057
5. [5]
  Dongju Zhang , Rongxiu Zhu . Construction of Ideological and Political Education in Quantum Chemistry Course: Several Teaching Cases to Reveal the Universal Connection of Things. University Chemistry, 2024, 39(7): 272-277. doi: 10.3866/PKU.DXHX202311032
6. [6]
  Peifeng Su , Xin Lu . Development of Undergraduate Quantum Mechanics Module in Chemistry Department under the “Double First Class” Initiative. University Chemistry, 2024, 39(8): 99-103. doi: 10.3866/PKU.DXHX202401087
7. [7]
  Jia Huo , Jia Li , Yongjun Li , Yuzhi Wang . Ideological and Political Design of Physical Chemistry Teaching: Chemical Potential of Any Component in an Ideal-Dilute Solution. University Chemistry, 2024, 39(2): 14-20. doi: 10.3866/PKU.DXHX202307075
8. [8]
  Jia Zhou . Constructing Potential Energy Surface of Water Molecule by Quantum Chemistry and Machine Learning: Introduction to a Comprehensive Computational Chemistry Experiment. University Chemistry, 2024, 39(3): 351-358. doi: 10.3866/PKU.DXHX202309060
9. [9]
  Miaomiao He , Zhiqing Ge , Qiang Zhou , Jiaqing He , Hong Gong , Lingling Li , Pingping Zhu , Wei Shao . Exploring the Fascinating Realm of Quantum Dots. University Chemistry, 2024, 39(6): 231-237. doi: 10.3866/PKU.DXHX202310040
10. [10]
  Chunai Dai , Yongsheng Han , Luting Yan , Zhen Li , Yingze Cao . Ideological and Political Design of Solid-liquid Contact Angle Measurement Experiment. University Chemistry, 2024, 39(2): 28-33. doi: 10.3866/PKU.DXHX202306065
11. [11]
  Huan LI , Shengyan WANG , Long Zhang , Yue CAO , Xiaohan YANG , Ziliang WANG , Wenjuan ZHU , Wenlei ZHU , Yang ZHOU . Growth mechanisms and application potentials of magic-size clusters of groups Ⅱ-Ⅵ semiconductors. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1425-1441. doi: 10.11862/CJIC.20240088
12. [12]
  Tiantian MA , Sumei LI , Chengyu ZHANG , Lu XU , Yiyan BAI , Yunlong FU , Wenjuan JI , Haiying YANG . Methyl-functionalized Cd-based metal-organic framework for highly sensitive electrochemical sensing of dopamine. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 725-735. doi: 10.11862/CJIC.20230351
13. [13]
  Danqing Wu , Jiajun Liu , Tianyu Li , Dazhen Xu , Zhiwei Miao . Research Progress on the Simultaneous Construction of C—O and C—X Bonds via 1,2-Difunctionalization of Olefins through Radical Pathways. University Chemistry, 2024, 39(11): 146-157. doi: 10.12461/PKU.DXHX202403087
14. [14]
  Lu XU , Chengyu ZHANG , Wenjuan JI , Haiying YANG , Yunlong FU . Zinc metal-organic framework with high-density free carboxyl oxygen functionalized pore walls for targeted electrochemical sensing of paracetamol. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 907-918. doi: 10.11862/CJIC.20230431
15. [15]
  Jing SU , Bingrong LI , Yiyan BAI , Wenjuan JI , Haiying YANG , Zhefeng Fan . Highly sensitive electrochemical dopamine sensor based on a highly stable In-based metal-organic framework with amino-enriched pores. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1337-1346. doi: 10.11862/CJIC.20230414
16. [16]
  Jianjun Liu , Xue Yang , Chi Zhang , Xueyu Zhao , Zhiwei Zhang , Yongmei Chen , Qinghong Xu , Shao Jin . Preparation and Fluorescence Characterization of CdTe Semiconductor Quantum Dots. University Chemistry, 2024, 39(7): 307-315. doi: 10.3866/PKU.DXHX202311031
17. [17]
  Jiaqi AN , Yunle LIU , Jianxuan SHANG , Yan GUO , Ce LIU , Fanlong ZENG , Anyang LI , Wenyuan WANG . Reactivity of extremely bulky silylaminogermylene chloride and bonding analysis of a cubic tetragermylene. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1511-1518. doi: 10.11862/CJIC.20240072
18. [18]
  Shipeng WANG , Shangyu XIE , Luxian LIANG , Xuehong WANG , Jie WEI , Deqiang WANG . Piezoelectric effect of Mn, Bi co-doped sodium niobate for promoting cell proliferation and bacteriostasis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1919-1931. doi: 10.11862/CJIC.20240094
19. [19]
  Yaling Chen . Basic Theory and Competitive Exam Analysis of Dynamic Isotope Effect. University Chemistry, 2024, 39(8): 403-410. doi: 10.3866/PKU.DXHX202311093
20. [20]
  YanYuan Jia , Rong Rong , Jie Liu , Jing Guo , GuoYu Jiang , Shuo Guo . Unity is Strength, and Independence Shines: A Science Popularization Experiment on AIE and ACQ Effects. University Chemistry, 2024, 39(9): 349-358. doi: 10.12461/PKU.DXHX202402035

Get Citation

PDF

XML

Metrics

PDF Downloads(706)
Abstract views(1462)
HTML views(121)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142