Citation: SHEN Qi, FAN Ying-Ju, YIN Long, SUN Zhong-Xi. Two-Dimensional Continuous Online In situ ATR-FTIR Spectroscopic Investigation of Adsorption of Butyl Xanthate on CuO Surfaces[J]. Acta Physico-Chimica Sinica, ;2014, 30(2): 359-364. doi: 10.3866/PKU.WHXB201312041 shu

Two-Dimensional Continuous Online In situ ATR-FTIR Spectroscopic Investigation of Adsorption of Butyl Xanthate on CuO Surfaces

1.
School of Chemistry and Chemical Engineering, University of Jinan, Jinan 250022, P. R. China

Received Date: 18 July 2013
Available Online: 4 December 2013
Fund Project: 国家自然科学基金(51274104，50874052) (51274104，50874052)国家重点基础研究发展规划项目(973)(2011CB933700)资助 (973)(2011CB933700)

In this study, a continuous online in situ attenuated total reflection Fourier- transform infrared (ATR-FTIR) spectroscopic technique was used to monitor the behavior of butyl xanthate adsorbed on CuO nanoparticle surfaces. A red-shift phenomenon, i.e., the absorption peak at 1200 cm^-1 shifted to 1193 cm^-1, was observed in the FTIR spectra. However, there was no obvious change in the peak intensity after desorption using ultrapure deionized water, indicating that butyl xanthate was chemisorbed on the CuO surface. We determined the order of the spectral intensity changes in the adsorption process using twodimensional (2D) IR spectroscopy. The 2D asynchronous spectra showed that the spectral intensity of the characteristic peak at 1265 cm^-1 changed first. This may be attributable to the combined peaks of dixanthogen and xanthate molecular aggregates at the surfaces. The adsorption kinetics was studied by monitoring the intensity changes of the xanthate characteristic peak at 1200 cm^-1. The adsorption kinetic data showed that the maximum chemisorption capacity of CuO for butyl xanthate was 529 mg·g^-1, and the adsorption kinetics can be described by a pseudo-second-order reaction model.
- Two-dimensional infrared spectroscopy,
- In situ attenuated total reflection Fourier-transform infrared,
- Online,
- CuO,
- Butyl xanthate,
- Adsorption kinetics 0001
1. [1]
  
  (1) Sawant, P.; Kovalev, E.; Klug, J. T.; Efrima, S. Langmuir 2001,17, 2913. doi: 10.1021/la0014961
2. [2]
  (2) Li, Z.; Yoon, R. Minerals Engineering 2012, 36-38, 126.
3. [3]
  (3) Feng, B.; Feng, Q. M.; Lu, Y. P.; Lv, P. C. Minerals Engineering2012, 39, 48. doi: 10.1016/j.mineng.2012.05.022
4. [4]
  (4) Hao, F.; Davey, K. J.; Bruckard,W. J.;Woodcock, J. T. Int . J .Miner. Process. 2008, 89, 71. doi: 10.1016/j.minpro.2008.07.004
5. [5]
  (5) Souto, R. M.; Laz, M. M.; nzalez, S. J. Phys. Chem. B 1997,101, 508. doi: 10.1021/jp962144z
6. [6]
  (6) Liu, X. Q.; Li, Z.; Zhang, Q.; Li, F.; Kong, T. Materials Letters2012, 72, 49. doi: 10.1016/j.matlet.2011.12.077
7. [7]
  (7) Ghadimkhani, G.; Tacconi, N.; Chanmanee,W.; Janakyab, C.;Rajeshwar, K. Chem. Commun. 2013, 49, 1297. doi: 10.1039/c2cc38068d
8. [8]
  (8) Cornel, J.; Lindenberg, C.; Mazzotti, M. Ind. Eng. Chem. Res.2008, 47, 4870. doi: 10.1021/ie800236v
9. [9]
  (9) McQuillan, A. J. Adv. Mater. 2001, 13, 1034. doi: 10.1002/1521-4095(200107)13:12/13<1034::AID-ADMA1034>3.0.CO;2-7
10. [10]
  (10) Beaussart, A.; Petrone, P.; Mierczynska-Vasilev, A.; McQuillan,A. J.; Beattie, D. A. Langmuir 2012, 28, 4233. doi: 10.1021/la204652f
11. [11]
  (11) Michelmore, A.; ng,W.; Jenkins, P.; Ralston, J. Phys. Chem. Chem. Phys. 2000, 2, 2985. doi: 10.1039/b001213k
12. [12]
  (12) Kirwan, L. J.; Fawell, P. D.; Bronswijk,W. Langmuir 2003, 19,5802. doi: 10.1021/la027012d
13. [13]
  (13) Brimaud, S.; Jusys, Z.; Behm, R. J. Electrocatalysis 2011, 2,69. doi: 10.1007/s12678-011-0040-7
14. [14]
  (14) Ge, D. L.; Fan, Y. J.; Yin, L.; Sun, Z. X. Acta Phys. -Chim. Sin.2013, 29, 371. [葛东来, 范迎菊, 尹龙, 孙中溪. 物理化学学报, 2013, 29, 371.] doi: 10.3866/PKU.WHXB201211146
15. [15]
  (15) Noda, I.; Dowrey, A. E.; Marcott, C. Applied Spectroscopy1993, 47, 1317. doi: 10.1366/0003702934067513
16. [16]
  (16) Noda, I. Bull. Am. Phys. Soc. 1986, 31, 520.
17. [17]
  (17) Noda, I. Appl. Spectroscopy 1990, 44, 550. doi: 10.1366/0003702904087398
18. [18]
  (18) Shen, Y.;Wu, P. Y. J. Phys. Chem. B 2003, 107, 4224. doi: 10.1021/jp0269975
19. [19]
  (19) Beattie, D. A.; Chapelet, J. K.; Grafe, M.; Skinner,W. M.;Smith, E. Environ. Sci. Technol. 2008, 42, 9191. doi: 10.1021/es801767b
20. [20]
  (20) Chandra, A. P.; Puskar, L.; Simpson, D. J.; Gerson, A. R. Int. J. Miner. Process. 2012, 114-117, 16.
21. [21]
  (21) Leppinen, J. O.; Basilio, C. I.; Yoon, R. H. Int. J. Miner. Process. 1989, 26, 259. doi: 10.1016/0301-7516(89)90032-X
22. [22]
  (22) Popov, S. R.; Vocinic, D. R. Int. J. Miner. Process. 1990, 30,229.
23. [23]
  (23) Hellstrom, P.; Holmgren, A.; Öberg, S. J. Phys. Chem. C 2007,111, 16920. doi: 10.1021/jp074254j
24. [24]
  (24) Hao, F. P.; Ewen Silvester, E.; David, G. Anal. Chem. 2000, 72,4836. doi: 10.1021/ac991277o
25. [25]
  (25) Larsson, M. L.; Holmgren, A.; Forsling,W. Langmuir 2000, 16,8129. doi: 10.1021/la000454+
26. [26]
  (26) Fredriksson, A.; Holmgren, A. Colloid Surface A 2007, 302,96. doi: 10.1016/j.colsurfa.2007.02.005
27. [27]
  (27) Yang, Y. L.; Yan,W.; Jing, C. Y. Langmuir 2012, 28, 14588. doi: 10.1021/la303413j
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