Citation: SHEN Qi, FAN Ying-Ju, YIN Long, SUN Zhong-Xi. Two-Dimensional Continuous Online In situ ATR-FTIR Spectroscopic Investigation of Adsorption of Butyl Xanthate on CuO Surfaces[J]. Acta Physico-Chimica Sinica, ;2014, 30(2): 359-364. doi: 10.3866/PKU.WHXB201312041 shu

Two-Dimensional Continuous Online In situ ATR-FTIR Spectroscopic Investigation of Adsorption of Butyl Xanthate on CuO Surfaces

1.
School of Chemistry and Chemical Engineering, University of Jinan, Jinan 250022, P. R. China

Received Date: 18 July 2013
Available Online: 4 December 2013
Fund Project: 国家自然科学基金(51274104，50874052) (51274104，50874052)国家重点基础研究发展规划项目(973)(2011CB933700)资助 (973)(2011CB933700)

In this study, a continuous online in situ attenuated total reflection Fourier- transform infrared (ATR-FTIR) spectroscopic technique was used to monitor the behavior of butyl xanthate adsorbed on CuO nanoparticle surfaces. A red-shift phenomenon, i.e., the absorption peak at 1200 cm^-1 shifted to 1193 cm^-1, was observed in the FTIR spectra. However, there was no obvious change in the peak intensity after desorption using ultrapure deionized water, indicating that butyl xanthate was chemisorbed on the CuO surface. We determined the order of the spectral intensity changes in the adsorption process using twodimensional (2D) IR spectroscopy. The 2D asynchronous spectra showed that the spectral intensity of the characteristic peak at 1265 cm^-1 changed first. This may be attributable to the combined peaks of dixanthogen and xanthate molecular aggregates at the surfaces. The adsorption kinetics was studied by monitoring the intensity changes of the xanthate characteristic peak at 1200 cm^-1. The adsorption kinetic data showed that the maximum chemisorption capacity of CuO for butyl xanthate was 529 mg·g^-1, and the adsorption kinetics can be described by a pseudo-second-order reaction model.
- Two-dimensional infrared spectroscopy,
- In situ attenuated total reflection Fourier-transform infrared,
- Online,
- CuO,
- Butyl xanthate,
- Adsorption kinetics 0001
1. [1]
  
  (1) Sawant, P.; Kovalev, E.; Klug, J. T.; Efrima, S. Langmuir 2001,17, 2913. doi: 10.1021/la0014961
2. [2]
  (2) Li, Z.; Yoon, R. Minerals Engineering 2012, 36-38, 126.
3. [3]
  (3) Feng, B.; Feng, Q. M.; Lu, Y. P.; Lv, P. C. Minerals Engineering2012, 39, 48. doi: 10.1016/j.mineng.2012.05.022
4. [4]
  (4) Hao, F.; Davey, K. J.; Bruckard,W. J.;Woodcock, J. T. Int . J .Miner. Process. 2008, 89, 71. doi: 10.1016/j.minpro.2008.07.004
5. [5]
  (5) Souto, R. M.; Laz, M. M.; nzalez, S. J. Phys. Chem. B 1997,101, 508. doi: 10.1021/jp962144z
6. [6]
  (6) Liu, X. Q.; Li, Z.; Zhang, Q.; Li, F.; Kong, T. Materials Letters2012, 72, 49. doi: 10.1016/j.matlet.2011.12.077
7. [7]
  (7) Ghadimkhani, G.; Tacconi, N.; Chanmanee,W.; Janakyab, C.;Rajeshwar, K. Chem. Commun. 2013, 49, 1297. doi: 10.1039/c2cc38068d
8. [8]
  (8) Cornel, J.; Lindenberg, C.; Mazzotti, M. Ind. Eng. Chem. Res.2008, 47, 4870. doi: 10.1021/ie800236v
9. [9]
  (9) McQuillan, A. J. Adv. Mater. 2001, 13, 1034. doi: 10.1002/1521-4095(200107)13:12/13<1034::AID-ADMA1034>3.0.CO;2-7
10. [10]
  (10) Beaussart, A.; Petrone, P.; Mierczynska-Vasilev, A.; McQuillan,A. J.; Beattie, D. A. Langmuir 2012, 28, 4233. doi: 10.1021/la204652f
11. [11]
  (11) Michelmore, A.; ng,W.; Jenkins, P.; Ralston, J. Phys. Chem. Chem. Phys. 2000, 2, 2985. doi: 10.1039/b001213k
12. [12]
  (12) Kirwan, L. J.; Fawell, P. D.; Bronswijk,W. Langmuir 2003, 19,5802. doi: 10.1021/la027012d
13. [13]
  (13) Brimaud, S.; Jusys, Z.; Behm, R. J. Electrocatalysis 2011, 2,69. doi: 10.1007/s12678-011-0040-7
14. [14]
  (14) Ge, D. L.; Fan, Y. J.; Yin, L.; Sun, Z. X. Acta Phys. -Chim. Sin.2013, 29, 371. [葛东来, 范迎菊, 尹龙, 孙中溪. 物理化学学报, 2013, 29, 371.] doi: 10.3866/PKU.WHXB201211146
15. [15]
  (15) Noda, I.; Dowrey, A. E.; Marcott, C. Applied Spectroscopy1993, 47, 1317. doi: 10.1366/0003702934067513
16. [16]
  (16) Noda, I. Bull. Am. Phys. Soc. 1986, 31, 520.
17. [17]
  (17) Noda, I. Appl. Spectroscopy 1990, 44, 550. doi: 10.1366/0003702904087398
18. [18]
  (18) Shen, Y.;Wu, P. Y. J. Phys. Chem. B 2003, 107, 4224. doi: 10.1021/jp0269975
19. [19]
  (19) Beattie, D. A.; Chapelet, J. K.; Grafe, M.; Skinner,W. M.;Smith, E. Environ. Sci. Technol. 2008, 42, 9191. doi: 10.1021/es801767b
20. [20]
  (20) Chandra, A. P.; Puskar, L.; Simpson, D. J.; Gerson, A. R. Int. J. Miner. Process. 2012, 114-117, 16.
21. [21]
  (21) Leppinen, J. O.; Basilio, C. I.; Yoon, R. H. Int. J. Miner. Process. 1989, 26, 259. doi: 10.1016/0301-7516(89)90032-X
22. [22]
  (22) Popov, S. R.; Vocinic, D. R. Int. J. Miner. Process. 1990, 30,229.
23. [23]
  (23) Hellstrom, P.; Holmgren, A.; Öberg, S. J. Phys. Chem. C 2007,111, 16920. doi: 10.1021/jp074254j
24. [24]
  (24) Hao, F. P.; Ewen Silvester, E.; David, G. Anal. Chem. 2000, 72,4836. doi: 10.1021/ac991277o
25. [25]
  (25) Larsson, M. L.; Holmgren, A.; Forsling,W. Langmuir 2000, 16,8129. doi: 10.1021/la000454+
26. [26]
  (26) Fredriksson, A.; Holmgren, A. Colloid Surface A 2007, 302,96. doi: 10.1016/j.colsurfa.2007.02.005
27. [27]
  (27) Yang, Y. L.; Yan,W.; Jing, C. Y. Langmuir 2012, 28, 14588. doi: 10.1021/la303413j
1. [1]
  Shasha Ma , Zujin Yang , Jianyong Zhang . Facile Synthesis of FeBTC Metal-Organic Gel and Its Adsorption of Cr₂O₇²⁻: A Physical Chemistry Innovation Experiment. University Chemistry, 2024, 39(8): 314-323. doi: 10.3866/PKU.DXHX202401008
2. [2]
  Tianlong Zhang , Rongling Zhang , Hongsheng Tang , Yan Li , Hua Li . Online Monitoring and Mechanistic Analysis of 3,5-diamino-1,2,4-triazole (DAT) Synthesis via Raman Spectroscopy: A Recommendation for a Comprehensive Instrumental Analysis Experiment. University Chemistry, 2024, 39(6): 303-311. doi: 10.3866/PKU.DXHX202312006
3. [3]
  Yang Wang , Yunpeng Fu , Xiaoji Liu , Guotao Zhang , Guobin Li , Wanqiang Liu , Jinglun Wang . Structural Analysis of Nitrile Solutions Based on Infrared Spectroscopy Probes. University Chemistry, 2025, 40(4): 367-374. doi: 10.12461/PKU.DXHX202406113
4. [4]
  Shiyang He , Dandan Chu , Zhixin Pang , Yuhang Du , Jiayi Wang , Yuhong Chen , Yumeng Su , Jianhua Qin , Xiangrong Pan , Zhan Zhou , Jingguo Li , Lufang Ma , Chaoliang Tan . 铂单原子功能化的二维Al-TCPP金属-有机框架纳米片用于增强光动力抗菌治疗. Acta Physico-Chimica Sinica, 2025, 41(5): 100046-. doi: 10.1016/j.actphy.2025.100046
5. [5]
  Shule Liu . Application of SPC/E Water Model in Molecular Dynamics Teaching Experiments. University Chemistry, 2024, 39(4): 338-342. doi: 10.3866/PKU.DXHX202310029
6. [6]
  Yaling Chen . Basic Theory and Competitive Exam Analysis of Dynamic Isotope Effect. University Chemistry, 2024, 39(8): 403-410. doi: 10.3866/PKU.DXHX202311093
7. [7]
  Jiayu Gu , Siqi Wang , Jun Ling . Kinetics of Living Copolymerization: A Brief Discussion. University Chemistry, 2025, 40(4): 100-107. doi: 10.12461/PKU.DXHX202406012
8. [8]
  Juntao Yan , Liang Wei . 2D S-Scheme Heterojunction Photocatalyst. Acta Physico-Chimica Sinica, 2024, 40(10): 2312024-. doi: 10.3866/PKU.WHXB202312024
9. [9]
  Ran HUO , Zhaohui ZHANG , Xi SU , Long CHEN . Research progress on multivariate two dimensional conjugated metal organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2063-2074. doi: 10.11862/CJIC.20240195
10. [10]
  Huanhuan XIE , Yingnan SONG , Lei LI . Two-dimensional single-layer BiOI nanosheets: Lattice thermal conductivity and phonon transport mechanism. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 702-708. doi: 10.11862/CJIC.20240281
11. [11]
  Jiahui CHEN , Tingting ZHENG , Xiuyun ZHANG , Wei LÜ . Research progress of near-infrared absorption inorganic nanomaterials in photothermal and photodynamic therapy of tumors. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2396-2414. doi: 10.11862/CJIC.20240106
12. [12]
  Jinfu Ma , Hui Lu , Jiandong Wu , Zhongli Zou . Teaching Design of Electrochemical Principles Course Based on “Cognitive Laws”: Kinetics of Electron Transfer Steps. University Chemistry, 2024, 39(3): 174-177. doi: 10.3866/PKU.DXHX202309052
13. [13]
  Yeyun Zhang , Ling Fan , Yanmei Wang , Zhenfeng Shang . Development and Application of Kinetic Reaction Flasks in Physical Chemistry Experimental Teaching. University Chemistry, 2024, 39(4): 100-106. doi: 10.3866/PKU.DXHX202308044
14. [14]
  Qi Wang , Yicong Gao , Feng Lu , Quli Fan . Preparation and Performance Characterization of the Second Near-Infrared Phototheranostic Probe: A New Design and Teaching Practice of Polymer Chemistry Comprehensive Experiment. University Chemistry, 2024, 39(11): 342-349. doi: 10.12461/PKU.DXHX202404141
15. [15]
  Baohua LÜ , Yuzhen LI . Anisotropic photoresponse of two-dimensional layered α-In₂Se₃(2H) ferroelectric materials. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1911-1918. doi: 10.11862/CJIC.20240105
16. [16]
  Runhua Chen , Qiong Wu , Jingchen Luo , Xiaolong Zu , Shan Zhu , Yongfu Sun . 缺陷态二维超薄材料用于光/电催化CO₂还原的基础与展望. Acta Physico-Chimica Sinica, 2025, 41(3): 2308052-. doi: 10.3866/PKU.WHXB202308052
17. [17]
  Huayan Liu , Yifei Chen , Mengzhao Yang , Jiajun Gu . 二维材料基超级电容器的容量与倍率性能提升策略. Acta Physico-Chimica Sinica, 2025, 41(6): 100063-. doi: 10.1016/j.actphy.2025.100063
18. [18]
  Ying Chen , Xingyuan Xia , Lei Tian , Mengying Yin , Ling-Ling Zheng , Qian Fu , Daishe Wu , Jian-Ping Zou . Constructing built-in electric field via CuO/NiO heterojunction for electrocatalytic reduction of nitrate at low concentrations to ammonia. Chinese Chemical Letters, 2024, 35(12): 109789-. doi: 10.1016/j.cclet.2024.109789
19. [19]
  Xuzhen Wang , Xinkui Wang , Dongxu Tian , Wei Liu . Enhancing the Comprehensive Quality and Innovation Abilities of Graduate Students through a “Student-Centered, Dual Integration and Dual Drive” Teaching Model: A Case Study in the Course of Chemical Reaction Kinetics. University Chemistry, 2024, 39(6): 160-165. doi: 10.3866/PKU.DXHX202401074
20. [20]
  Dexin Tan , Limin Liang , Baoyi Lv , Huiwen Guan , Haicheng Chen , Yanli Wang . Exploring Reverse Teaching Practices in Physical Chemistry Experiment Courses: A Case Study on Chemical Reaction Kinetics. University Chemistry, 2024, 39(11): 79-86. doi: 10.12461/PKU.DXHX202403048

Get Citation

PDF

XML

Metrics

PDF Downloads(535)
Abstract views(1219)
HTML views(90)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142