Citation: LÜ Yong-Ge, LI Yong, TA Na, SHEN Wen-Jie. Morphology-Controlled Synthesis of Co₃O₄ Nanocubes and Their Catalytic Performance in CO Oxidation[J]. Acta Physico-Chimica Sinica, ;2014, 30(2): 382-388. doi: 10.3866/PKU.WHXB201312032 shu

Morphology-Controlled Synthesis of Co₃O₄ Nanocubes and Their Catalytic Performance in CO Oxidation

1.
State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning Province, P. R. China

Received Date: 14 October 2013
Available Online: 3 December 2013
Fund Project: 国家自然科学基金(20923001，21025312)资助项目 (20923001，21025312)

Co₃O₄ nanocubes that were exclusively terminated with {100} facets of edge size 10 nm were solvothermally fabricated in a mixed solution of ethanol and triethylamine. Analyses of the structural evolution of the intermediates at different intervals during the synthesis, together with an examination of the influences of the cobalt precursor and solvent on the product structure, showed that the formation of Co₃O₄ nanocubes followed a dissolution-recrystallization mechanism. After calcination at 200 ℃, the as-synthesized Co₃O₄ material retained a cubic morphology with the same edge size, but calcination at 400 ℃ resulted in the formation of spherical Co₃O₄ particles of diameter about 13 nm. The Co₃O₄ nanocubes exhibited inferior activity in room-temperature CO oxidation compared with Co₃O₄ nanoparticles ({111} facets), primarily as a result of the exposure of the less- reactive {100} facets, demonstrating the morphology effect of Co₃O₄ nanomaterials.
- Co₃O₄,
- Solvothermal synthesis,
- Morphology-dependence,
- Nanocube,
- CO oxidation
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沈阳化工大学材料科学与工程学院沈阳 110142

Morphology-Controlled Synthesis of Co3O4 Nanocubes and Their Catalytic Performance in CO Oxidation

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通讯作者: 陈斌, bchen63@163.com

Morphology-Controlled Synthesis of Co₃O₄ Nanocubes and Their Catalytic Performance in CO Oxidation