Citation: WANG Jian-Tao, WANG Yao, HUANG Bin, YANG Juan-Yu, TAN Ao, LU Shi-Gang. Silicon Supported on Stable Si-O-C Skeleton in High-Performance Lithium-Ion Battery Anode Materials[J]. Acta Physico-Chimica Sinica, ;2014, 30(2): 305-310. doi: 10.3866/PKU.WHXB201312022 shu

Silicon Supported on Stable Si-O-C Skeleton in High-Performance Lithium-Ion Battery Anode Materials

1.
R&D Center for Vehicle Battery and Energy Storage, General Research Institute for Nonferrous Metals, Beijing 100088, P. R. China

Received Date: 24 October 2013
Available Online: 2 December 2013
Fund Project: 国家高技术研究发展计划(863) (2011AA11A256，2013AA050903，2013AA050906)资助项目 (863) (2011AA11A256，2013AA050903，2013AA050906)

A Si/SiOC/graphite composite structure with high efficiency and long-term cycling stability was synthesized using a cost- effective method. In this structure, a SiOC network with od chemical stability acts as a skeleton to support and segregate Si nanostructures. The graphite incorporated in the Si/SiOC composite is used as a conductive material to enhance the electrical conductivity. Such Si/SiOC/graphite composite anodes show excellent cycling stability, with a specific capacity of ~637.3 mAh·g^-1 and ~86% capacity retention over 100 cycles at a rate of 0.3C. The design of this new structure has the potential to provide a basis for the development of other functional composite materials.
- Si/SiOC/graphite,
- Composite material,
- Lithium-ion battery,
- Anode,
- Long-term cycling
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沈阳化工大学材料科学与工程学院沈阳 110142