Citation: WANG Jian-Tao, WANG Yao, HUANG Bin, YANG Juan-Yu, TAN Ao, LU Shi-Gang. Silicon Supported on Stable Si-O-C Skeleton in High-Performance Lithium-Ion Battery Anode Materials[J]. Acta Physico-Chimica Sinica, ;2014, 30(2): 305-310. doi: 10.3866/PKU.WHXB201312022 shu

Silicon Supported on Stable Si-O-C Skeleton in High-Performance Lithium-Ion Battery Anode Materials

1.
R&D Center for Vehicle Battery and Energy Storage, General Research Institute for Nonferrous Metals, Beijing 100088, P. R. China

Received Date: 24 October 2013
Available Online: 2 December 2013
Fund Project: 国家高技术研究发展计划(863) (2011AA11A256，2013AA050903，2013AA050906)资助项目 (863) (2011AA11A256，2013AA050903，2013AA050906)

A Si/SiOC/graphite composite structure with high efficiency and long-term cycling stability was synthesized using a cost- effective method. In this structure, a SiOC network with od chemical stability acts as a skeleton to support and segregate Si nanostructures. The graphite incorporated in the Si/SiOC composite is used as a conductive material to enhance the electrical conductivity. Such Si/SiOC/graphite composite anodes show excellent cycling stability, with a specific capacity of ~637.3 mAh·g^-1 and ~86% capacity retention over 100 cycles at a rate of 0.3C. The design of this new structure has the potential to provide a basis for the development of other functional composite materials.
- Si/SiOC/graphite,
- Composite material,
- Lithium-ion battery,
- Anode,
- Long-term cycling
1. [1]
  
  (1) Armand, M.; Tarascon, J. M. Nature 2008, 451, 652. doi: 10.1038/451652a
2. [2]
  (2) Maier, J. Nat. Mater. 2005, 4, 805. doi: 10.1038/nmat1513
3. [3]
  (3) Kang, B.; Ceder, G. Nature 2009, 458, 190. doi: 10.1038/nature07853
4. [4]
  (4) Arico, A. S.; Bruce, P.; Scrosati, B.; Tarascon, J. M.;Schalkwijk,W. V. Nat. Mater. 2005, 4, 366. doi: 10.1038/nmat1368
5. [5]
  (5) Wu, H. B.; Zhang, Y.; Yuan, C. L.;Wei, X. P.; Yin, J. L.;Wang,G. L.; Cao, D. X.; Zhang, Y. M.; Yang, B. F.; She, P. L. Acta Phys. -Chim. Sin. 2013, 29, 1247. [武洪彬, 张莹, 袁聪俐,韦小培, 殷金玲, 王贵领, 曹殿学, 张益明, 杨宝峰, 佘佩亮.物理化学学报, 2013, 29, 1247.] doi: 10.3866/PKU.WHXB201303211
6. [6]
  (6) Ding, P.; Xu, Y. L.; Sun, X. F. Acta Phys. -Chim. Sin. 2013, 29,293. [丁朋, 徐友龙, 孙孝飞. 物理化学学报, 2013, 29,293.] doi: 10.3866/PKU.WHXB201211142
7. [7]
  (7) Chan, C. K.; Peng, H. L.; Liu, G.; Mcilwrath, K.; Zhang, X. F.;Huggins, R. A.; Cui, Y. Nature Nanotech. 2008, 3, 31. doi: 10.1038/nnano.2007.411
8. [8]
  (8) Poizot, P.; Laruelle, S.; Grugeon, S.; Dupont, L.; Tarascon, J. M.Nature 2000, 407, 496. doi: 10.1038/35035045
9. [9]
  (9) Taberna, L.; Mitra, S.; Poizot, P.; Simon, P.; Tarascon, J. M. Nat. Mater. 2006, 5, 567. doi: 10.1038/nmat1672
10. [10]
  (10) Oumellal, Y.; Rougier, A.; Nazri, G. A.; Tarascon, J. M.;Aymard, L. Nat. Mater. 2008, 7 , 916. doi: 10.1038/nmat2288
11. [11]
  (11) Jiang, D. D.; Fu, Y. B.; Ma, X. H. Acta Phys. -Chim. Sin. 2009,25, 1481. [姜冬冬, 付延鲍, 马晓华. 物理化学学报, 2009,25, 1481.] doi: 10.3866/PKU.WHXB20090817
12. [12]
  (12) Fan, X. Y.; Zhuang, Q. C.;Wei, G. Z.; Ke, F. S.; Huang, L.;Dong, Q. F.; Sun, S. G. Acta Phys. -Chim. Sin. 2009, 25, 611.[樊小勇, 庄全超, 魏国祯, 柯福生, 黄令, 董全峰, 孙世刚. 物理化学学报, 2009, 25, 611.] doi: 10.3866/PKU.WHXB20090403
13. [13]
  (13) Li, Y.; Xie, H. Q.; Tu, J. P. Acta Phys. -Chim. Sin. 2009, 25, 365.[黎阳, 谢华清, 涂江平. 物理化学学报, 2009, 25, 365.] doi: 10.3866/PKU.WHXB20090229
14. [14]
  (14) Kasavajjula, U.;Wang, C.; Appleby, A. J. J. Power Sources2007, 163, 1003. doi: 10.1016/j.jpowsour.2006.09.084
15. [15]
  (15) Hu, Y. S.; Demir-Cakan, R.; Titirici, M. M.; Müller, J. O.;Schlögl, R.; Antonietti, M.; Maier, J. Angew. Chem. Int. Edit.2008, 47, doi: 1645. doi: 10.1002/anie.200704287
16. [16]
  (16) Ng, S. H.;Wang, J.;Wexler, D.; Konstantinov, K.; Guo, Z. P.;Liu, H. K. Angew. Chem. Int. Edit. 2006, 45, 6896. doi: 10.1002/anie.200601676
17. [17]
  (17) Dimov, N.; Kugino, S.; Yoshio, M. Electrochim. Acta 2003, 48,1579. doi: 10.1016/S0013-4686(03)00030-6
18. [18]
  (18) Lee, J. K.; Smith, K. B.; Hayner, C. M.; Kung, H. H. Chem. Commun. 2010, 46, 2025. doi: 10.1039/b919738a
19. [19]
  (19) Zhou, X.; Yin, Y. X.;Wan, L. J.; Guo, Y. G. Chem. Commun.2012, 48, 2198. doi: 10.1039/c2cc17061b
20. [20]
  (20) Xiang, H.; Zhang, K.; Ji, G.; Lee, J. Y.; Zou, C.; Chen, X.;Wu,J. Carbon 2011, 49, 1787. doi: 10.1016/j.carbon.2011.01.002
21. [21]
  (21) Liu, Y.; Matsumura, T.; Imanishi, N.; Hirano, A.; Ichikawa, T.;Takeda, Y. Electrochem. Solid-State Lett. 2005, 8, A599.doi: 10.1149/1.2039954
22. [22]
  (22) Yu, Y.; Gu, L.; Zhu, C.; Tsukimoto, S.; Van Aken, P. A.; Maier,J. Adv. Mater. 2010, 22, 2247. doi: 10.1002/adma.200903755
23. [23]
  (23) Hiroshi, F.; Hisashi, O.; Takakazu, H.; Kiyoshi, K. ACS App. Mater. Inter. 2010, 2, 998. doi: 10.1021/am100030f
24. [24]
  (24) Hiroshi, F.; Hisashi, O.; Takakazu, H.; Kiyoshi, K. J. Electro. Society 2011, 158, A550. doi: 10.1149/1.3567956
25. [25]
  (25) Hiroshi, F.; Hisashi, O.; Takakazu, H.; Kiyoshi, K. J. Power Sources 2011, 196, 371. doi: 10.1016/j.jpowsour.2010.06.077
1. [1]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
2. [2]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
3. [3]
  Yuting ZHANG , Zunyi LIU , Ning LI , Dongqiang ZHANG , Shiling ZHAO , Yu ZHAO . Nickel vanadate anode material with high specific surface area through improved co-precipitation method: Preparation and electrochemical properties. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2163-2174. doi: 10.11862/CJIC.20240204
4. [4]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
5. [5]
  Yifeng Xu , Jiquan Liu , Bin Cui , Yan Li , Gang Xie , Ying Yang . “Xiao Li’s School Adventures: The Working Principles and Safety Risks of Lithium-ion Batteries”. University Chemistry, 2024, 39(9): 259-265. doi: 10.12461/PKU.DXHX202404009
6. [6]
  Siyu Zhang , Kunhong Gu , Bing'an Lu , Junwei Han , Jiang Zhou . Hydrometallurgical Processes on Recycling of Spent Lithium-lon Battery Cathode: Advances and Applications in Sustainable Technologies. Acta Physico-Chimica Sinica, 2024, 40(10): 2309028-. doi: 10.3866/PKU.WHXB202309028
7. [7]
  Aoyu Huang , Jun Xu , Yu Huang , Gui Chu , Mao Wang , Lili Wang , Yongqi Sun , Zhen Jiang , Xiaobo Zhu . Tailoring Electrode-Electrolyte Interfaces via a Simple Slurry Additive for Stable High-Voltage Lithium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 100037-. doi: 10.3866/PKU.WHXB202408007
8. [8]
  Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn_0.8Fe_0.2PO₄/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252
9. [9]
  Xueyu Lin , Ruiqi Wang , Wujie Dong , Fuqiang Huang . 高性能双金属氧化物负极的理性设计及储锂特性. Acta Physico-Chimica Sinica, 2025, 41(3): 2311005-. doi: 10.3866/PKU.WHXB202311005
10. [10]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
11. [11]
  Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO₂/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1461-1473. doi: 10.11862/CJIC.20240189
12. [12]
  Zhanggui DUAN , Yi PEI , Shanshan ZHENG , Zhaoyang WANG , Yongguang WANG , Junjie WANG , Yang HU , Chunxin LÜ , Wei ZHONG . Preparation of UiO-66-NH₂ supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317
13. [13]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
14. [14]
  Jie XIE , Hongnan XU , Jianfeng LIAO , Ruoyu CHEN , Lin SUN , Zhong JIN . Nitrogen-doped 3D graphene-carbon nanotube network for efficient lithium storage. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1840-1849. doi: 10.11862/CJIC.20240216
15. [15]
  Jiaxuan Zuo , Kun Zhang , Jing Wang , Xifei Li . 锂离子电池Ni-Co-Mn基正极材料前驱体的形核调控及机制. Acta Physico-Chimica Sinica, 2025, 41(1): 2404042-. doi: 10.3866/PKU.WHXB202404042
16. [16]
  Yu Guo , Zhiwei Huang , Yuqing Hu , Junzhe Li , Jie Xu . 钠离子电池中铁基异质结构负极材料的最新研究进展. Acta Physico-Chimica Sinica, 2025, 41(3): 2311015-. doi: 10.3866/PKU.WHXB202311015
17. [17]
  Zhenming Xu , Mingbo Zheng , Zhenhui Liu , Duo Chen , Qingsheng Liu . Experimental Design of Project-Driven Teaching in Computational Materials Science: First-Principles Calculations of the LiFePO₄ Cathode Material for Lithium-Ion Batteries. University Chemistry, 2024, 39(4): 140-148. doi: 10.3866/PKU.DXHX202307022
18. [18]
  Bowen Yang , Rui Wang , Benjian Xin , Lili Liu , Zhiqiang Niu . C-SnO₂/MWCNTs Composite with Stable Conductive Network for Lithium-based Semi-Solid Flow Batteries. Acta Physico-Chimica Sinica, 2025, 41(2): 100015-. doi: 10.3866/PKU.WHXB202310024
19. [19]
  Ning DING , Siyu WANG , Shihua YU , Pengcheng XU , Dandan HAN , Dexin SHI , Chao ZHANG . Crystalline and amorphous metal sulfide composite electrode materials with long cycle life: Preparation and performance of hybrid capacitors. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1784-1794. doi: 10.11862/CJIC.20240146
20. [20]
  Zhuo Wang , Xue Bai , Kexin Zhang , Hongzhi Wang , Jiabao Dong , Yuan Gao , Bin Zhao . MOF模板法合成氮掺杂碳材料用于增强电化学钠离子储存和去除. Acta Physico-Chimica Sinica, 2025, 41(3): 2405002-. doi: 10.3866/PKU.WHXB202405002

Get Citation

PDF

XML

Metrics

PDF Downloads(697)
Abstract views(1172)
HTML views(120)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142