Citation: LIANG Qian, ZHAO Zhen, LIU Jian, WEI Yue-Chang, JIANG Gui-Yuan, DUAN Ai-Jun. Pd Nanoparticles Deposited on Metal-Organic Framework of MIL-53(Al)：an Active Catalyst for CO Oxidation[J]. Acta Physico-Chimica Sinica, ;2014, 30(1): 129-134. doi: 10.3866/PKU.WHXB201311201 shu

Pd Nanoparticles Deposited on Metal-Organic Framework of MIL-53(Al)：an Active Catalyst for CO Oxidation

1.
State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Beijing 102249, P. R. China

Received Date: 26 August 2013
Available Online: 20 November 2013
Fund Project: 国家自然科学基金(21073235，21173270，21177160) (21073235，21173270，21177160)国家高技术研究发展计划(863) (2013AA061902)资助项目 (863) (2013AA061902)

Pd nanoparticles (NPs) supported on a metal-organic framework (MOF), MIL-53(Al) (MIL: Materials of Institut Lavoisier), were prepared using the incipient wetness impregnation method. The structures of the synthesized Pd/MIL-53(Al) catalysts were determined using X-ray diffraction (XRD), transmission electron microscopy (TEM), and X-ray photoelectron spectroscopy (XPS). The same peaks were observed in the XRD patterns of Pd/MIL-53(Al) before and after the catalytic reaction, confirming that the integrity of the MIL-53(Al) support was maintained. The TEM results indicated that the crystalline porous structure of MIL-53(Al) favored the formation of highly dispersed Pd NPs of average size 2.21 nm. The heterogeneous catalytic composite materials exhibited high activities for CO oxidation, with full conversion at 115 ℃. The catalytic activity and structure of Pd/MIL-53(Al) were stable after several reaction runs.
- Metal-organic framework,
- MIL-53(Al),
- Palladium nanoparticle,
- Heterogeneous catalysis,
- CO oxidation
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