Citation: LIANG Qian, ZHAO Zhen, LIU Jian, WEI Yue-Chang, JIANG Gui-Yuan, DUAN Ai-Jun. Pd Nanoparticles Deposited on Metal-Organic Framework of MIL-53(Al)：an Active Catalyst for CO Oxidation[J]. Acta Physico-Chimica Sinica, ;2014, 30(1): 129-134. doi: 10.3866/PKU.WHXB201311201 shu

Pd Nanoparticles Deposited on Metal-Organic Framework of MIL-53(Al)：an Active Catalyst for CO Oxidation

1.
State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Beijing 102249, P. R. China

Received Date: 26 August 2013
Available Online: 20 November 2013
Fund Project: 国家自然科学基金(21073235，21173270，21177160) (21073235，21173270，21177160)国家高技术研究发展计划(863) (2013AA061902)资助项目 (863) (2013AA061902)

Pd nanoparticles (NPs) supported on a metal-organic framework (MOF), MIL-53(Al) (MIL: Materials of Institut Lavoisier), were prepared using the incipient wetness impregnation method. The structures of the synthesized Pd/MIL-53(Al) catalysts were determined using X-ray diffraction (XRD), transmission electron microscopy (TEM), and X-ray photoelectron spectroscopy (XPS). The same peaks were observed in the XRD patterns of Pd/MIL-53(Al) before and after the catalytic reaction, confirming that the integrity of the MIL-53(Al) support was maintained. The TEM results indicated that the crystalline porous structure of MIL-53(Al) favored the formation of highly dispersed Pd NPs of average size 2.21 nm. The heterogeneous catalytic composite materials exhibited high activities for CO oxidation, with full conversion at 115 ℃. The catalytic activity and structure of Pd/MIL-53(Al) were stable after several reaction runs.
- Metal-organic framework,
- MIL-53(Al),
- Palladium nanoparticle,
- Heterogeneous catalysis,
- CO oxidation
1. [1]
  
  (1) Wang, R.; He, H.; Liu, L. C.; Dai, H. X.; Zhao, Z. Catal. Sci. Technol. 2012, 2, 575. doi: 10.1039/c2cy00417h
2. [2]
  (2) Li, L.;Wang, A. Q.; Qiao, B. T.; Lin, J.; Huang, Y. Q.;Wang, X.D.; Zhang, T. J. Catal. 2013, 299, 90. doi: 10.1016/j.jcat.2012.11.019
3. [3]
  (3) Zhan, Y. Y.; Cai, G. H.; Zheng, Y.; Shen, X. N.; Zheng, Y.;Wei,K. M. Acta Phys. -Chim. Sin. 2008, 24, 171. [詹瑛瑛, 蔡国辉,郑勇, 沈小女, 郑瑛, 魏可镁. 物理化学学报, 2008, 24,171.] doi: 10.3866/PKU.WHXB20080131
4. [4]
  (4) Liang, Q.; Liu, J.;Wei, Y. C.; Zhao, Z.; MacLachlan, J. M.Chem. Commun. 2013, 49, 8928. doi: 10.1039/c3cc44500c
5. [5]
  (5) Wei, Y. C.; Liu, J.; Zhao, Z.; Chen, Y.; Xu, C.; Duan, A. J.;Jiang, G. Y.; He, H. Angew. Chem. Int. Edit. 2011, 50, 2326. doi: 10.1002/anie.201006014
6. [6]
  (6) Müller, M.; Turner, S.; Lebedev, O. I.;Wang, Y.; Tendeloo, G.;Fischer, R. A. Eur. J. Inorg. Chem. 2011, 1876.
7. [7]
  (7) Jiang, H.; Akita, T.; Ishida, T.; Haruta, M.; Xu, Q. J. Am. Chem. Soc. 2011, 133, 1304. doi: 10.1021/ja1099006
8. [8]
  (8) Hermannsdorfer, J.; Kempe, R. Chem. Eur. J. 2011, 17, 8071.doi: 10.1002/chem.v17.29
9. [9]
  (9) Gu, X.; Lu, Z.; Jiang, H.; Akita, T.; Xu, Q. J. Am. Chem. Soc.2011, 133, 11822. doi: 10.1021/ja200122f
10. [10]
  (10) Bourrelly, S.; Llewellyn, P. L.; Serre, C.; Millange, F.; Loiseau,T.; Ferey, G. J. Am. Chem. Soc. 2005, 127, 13519. doi: 10.1021/ja054668v
11. [11]
  (11) Esken, D.; Turner, S.; Lebedev, O. I.; Tendeloo, G. V.; Fischer,R. A. Chem. Mater. 2010, 22, 6393. doi: 10.1021/cm102529c
12. [12]
  (12) Luz, I.; Xamena, F. X.; Corma, A. J. Catal. 2010, 276, 134. doi: 10.1016/j.jcat.2010.09.010
13. [13]
  (13) Tanabe, K. K.; Cohen, S. M. Inorg. Chem. 2010, 49, 6766. doi: 10.1021/ic101125m
14. [14]
  (14) Aguado, S.; Canivet, J.; Schuurman, Y.; Farrusseng, D. J. Catal.2011, 248, 207.
15. [15]
  (15) Schaate, A.; Roy, P.; dt, A.; Lippke, J.;Waltz, F.;Wiebcke,M.; Behrens, P. Chem. Eur. J. 2011, 17, 6643. doi: 10.1002/chem.v17.24
16. [16]
  (16) Phan, N.; Le, K.; Phan, T. D. Appl. Catal. A-Gen. 2010, 382,246. doi: 10.1016/j.apcata.2010.04.053
17. [17]
  (17) Gao, S.; Zhao, N.; Shu, M.; Che, S. Appl. Catal. A-Gen. 2010,388, 196. doi: 10.1016/j.apcata.2010.08.045
18. [18]
  (18) Ishida, T.; Nagaoka, M.; Akita, T.; Haruta, M. Chem. Eur. J.2008, 14, 8456. doi: 10.1002/chem.v14:28
19. [19]
  (19) Liu, H. L.; Liu, Y. L.; Li, Y.W.; Tang, Z. Y.; Jiang, H. F. J. Phys. Chem. C 2010, 114, 13362.
20. [20]
  (20) Xamena, F.; Abad, A.; Corma, A.; Garcia, H. J. Catal. 2007,250, 294. doi: 10.1016/j.jcat.2007.06.004
21. [21]
  (21) Dang, T. T.; Zhu, Y.; Ghosh, S. C.; Chen, A.; Chai, C.; Seayad,A. M. Chem. Commun. 2012, 48, 1805. doi: 10.1039/c2cc16808a
22. [22]
  (22) Huang, Y.; Lin, Z.; Cao, R. Chem. Eur. J. 2011, 17, 12706. doi: 10.1002/chem.201101705
23. [23]
  (23) Zhang, M.; Guan, J.; Zhang, B.; Su, D.;Williams, C. T.; Liang,C. Catal. Lett. 2012, 42, 313.
24. [24]
  (24) esten, M. G.; Alcaniz, J.; Fernandez, E. V.; Gupta, K.;Stavitski, E.; Bekkum, H.; Gascon, J.; Kapteijn, F. J. Catal.2011, 281, 177. doi: 10.1016/j.jcat.2011.04.015
25. [25]
  (25) Zhou, Y. X.; Liang, S. G.; Song, J. L.;Wu, T. B.; Hu, S. Q.; Liu,H. Z.; Jiang, T.; Han, B. X. Acta Phys. -Chim. Sin. 2010, 26,939. [周印羲, 梁曙光, 宋金良, 吴天斌, 胡素琴, 刘会贞,姜涛, 韩布兴. 物理化学学报, 2010, 26, 939.] doi: 10.3866/PKU.WHXB20100406
26. [26]
  (26) Jiang, H.; Liu, B.; Akita, T.; Haruta, M.; Sakurai, H.; Xu, Q.J. Am. Chem. Soc. 2009, 131, 11302. doi: 10.1021/ja9047653
27. [27]
  (27) El-Shall, M.; Abdelsayed, V.; Khder, A. S.; Hassan, H.; El-Kaderi, H.; Reich, T. J. Mater. Chem. 2009, 19, 7625. doi: 10.1039/b912012b
28. [28]
  (28) Ye, J.; Liu, C. Chem. Commun. 2011, 47, 2167. doi: 10.1039/c0cc04944a
29. [29]
  (29) Loiseau, T.; Serre, C.; Huguenard, C.; Fink, G.; Taulelle, F.;Henry, M.; Bataille, T.; Ferey, G. Chem. Eur. J. 2004, 10, 1373.
30. [30]
  (30) Chan-Thaw, C. A.; Katekomol, P. D.; Thomas, A. L. Nano Lett.2010, 10, 537. doi: 10.1021/nl904082k
31. [31]
  (31) Zhou, Y.; Xiang, Z. H.; Cao, D. P.; Liu, C. J. Chem. Commun.2013, 49, 5633. doi: 10.1039/c3cc00287j
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