Citation: WANG Xiu-Ping, ZHOU De-Feng, YANG Guo-Cheng, SUN Shi-Cheng, LI Zhao-Hui. Structure and Electrical Properties of Ce_0.8Nd_0.2O_1.9-La_0.95Sr_0.05Ga_0.9Mg_0.1O_3-δ Solid Composite Electrolytes[J]. Acta Physico-Chimica Sinica, ;2014, 30(1): 95-101. doi: 10.3866/PKU.WHXB201311141 shu

Structure and Electrical Properties of Ce_0.8Nd_0.2O_1.9-La_0.95Sr_0.05Ga_0.9Mg_0.1O_3-δ Solid Composite Electrolytes

1.
School of Chemistry and Life Science, Changchun University of Technology, Changchun 130012, P. R. China

Received Date: 11 August 2013
Available Online: 14 November 2013
Fund Project: 国家自然科学基金(20871023) (20871023)吉林省科技发展计划(20101549，20130102001JC)资助项目 (20101549，20130102001JC)

Ce_0.8Nd_0.2O_1.9 (NDC) and La_0.95Sr_0.05Ga_0.9Mg_0.1O_3-δ (LSGM) electrolytes were each prepared using a sol-gel method. NDC-LSGM composite electrolytes were then prepared by adding 0-15% (w, mass fraction) precalcined LSGM powders to NDC sols. The microstructure and phase composition of the pellets were characterized using X-ray diffraction (XRD), field-emission scanning electron microscopy (FE-SEM), and energydispersive X-ray spectroscopy (EDS). The electrical conductivities of the pellets were measured using alternative current (AC) impedance spectroscopy. The results showed that all the composites were composed of the cubic fluorite structure, perovskite structure, and secondary phases. The LSGM additive significantly promoted grain growth. The grain boundary conduction increased greatly as a result of the presence of phase interfaces and mitigation of the harmful effects of SiO₂ impurities. NL10 was found to have the highest conductivities (σ_gb=12.15×10^-4 S·cm^-1, σ_t=3.49×10^-4 S·cm^-1 at 400 ℃); these values are 7.62 and 1.91 times higher than those of NDC (σ_gb=1.41×10^-4 S·cm^-1, σ_t=1.2×10^-4 S·cm^-1). The enhancement of the total conductivity of NL10 is mainly attributed to the large increase in grain boundary conductivity.
- Composite electrolyte,
- Neodymium-doped ceria,
- AC impedance spectroscopy,
- Grain boundary conductivity,
- Lanthanum gallate
1. [1]
  
  (1) M-Hernandez, A.; V-Castillo, J.; Mogni, L.; Caneiro, A. Int. J. Hydrog. Energy 2011, 36 (24), 15704.
2. [2]
  (2) Hart, N. T.; Brandon, N. P.; Day, M. J.; Lapeña-Rey, N.J. Power Sources 2002, 106 (1-2), 42. doi: 10.1016/S0378-7753(01)01035-7
3. [3]
  (3) Steele, B. C. H. Solid State Ionics 2000, 129 (1-4), 95. doi: 10.1016/S0167-2738(99)00319-7
4. [4]
  (4) Yan, D. Y.; Liu, X. M.; Bai, X. Y.; Pei, L.; Zheng, M. Z.; Zhu, C.J.; Su,W. H. J. Power Sources 2010, 195, 6488.
5. [5]
  (5) Molenda, J.; wierczek, K.; Zaj c,W. J. Power Sources 2007,173 (2), 660.
6. [6]
  (6) Badwal, S. P. S.; Ciacchi, F. T.; Drennan, J. Solid State Ionics1999, 121 (1-4), 253. doi: 10.1016/S0167-2738(99)00044-2
7. [7]
  (7) Abrantes, J. C. C.; Pérez-Coll, D.; Núñez, P.; Frade, J. R.Electrochim. Acta 2003, 48 (19), 2761. doi: 10.1016/S0013-4686(03)00395-5
8. [8]
  (8) Xia, Y. J.; Bai, Y. J.;Wu, X. J.; Zhou, D. F.; Liu, X. J.; Meng, J.Int. J. Hydrog. Energy 2011, 36, 6840. doi: 10.1016/j.ijhydene.2011.02.118
9. [9]
  (9) Zhao, Y. C.; Xu, Z. R.; Xia, C.; Li, Y. D. Int. J. Hydrog. Energy2013, 38, 1553. doi: 10.1016/j.ijhydene.2012.11.004
10. [10]
  (10) Fan, L. D.;Wang, C. Y.; Chen, M. M.; Zhu, B. J. Power Sources2013, 234, 154. doi: 10.1016/j.jpowsour.2013.01.138
11. [11]
  (11) Kwon, T. H.; Lee, T.; Yoo, H. I. Solid State Ionics 2011, 195 (1),25. doi: 10.1016/j.ssi.2011.05.002
12. [12]
  (12) Cho, S.; Kim, Y. N.; Kim, J. H.; Manthiram, A.;Wang, H. Y.Electrochim. Acta 2011, 56 (16), 5472. doi: 10.1016/j.electacta.2011.03.039
13. [13]
  (13) Jang,W. S.; Hyun, S. H.; Kim, S. G. J. Mater. Sci. 2002, 37 (12), 2535. doi: 10.1023/A:1015451910081
14. [14]
  (14) Inoue, T.; Setoguchi, T.; Eguchi, K.; Arai, H. Solid State Ionics1989, 35 (3-4), 285. doi: 10.1016/0167-2738(89)90310-X
15. [15]
  (15) Ishihara, T.; Matsuda, H.; Takita, Y. J. Am. Chem. Soc. 1994,116, 3801. doi: 10.1021/ja00088a016
16. [16]
  (16) Huang, K.; Tichy, R. S.; odenough, J. B. J. Am. Ceram. Soc.1998, 81, 2565. doi: 10.1111/j.1151-2916.1998.tb02662.x
17. [17]
  (17) Kharton, V. V.; Marques, F. M. B.; Atkinson, A. Solid State Ionics 2004, 174 (1-4), 135. doi: 10.1016/j.ssi.2004.06.015
18. [18]
  (18) Zhang, X. G.; Ohara, S.; Okawa, H.; Maric, R.; Fukui, T. Solid State Ionics 2001, 139 (1-2), 145. doi: 10.1016/S0167-2738(00)00833-X
19. [19]
  (19) Xu, D.; Liu, X. M.; Zhu, C. J.;Wang, D. J.; Yan, D. T.;Wang,D. Y.; Su,W. H. J. Rare Earth 2008, 26, 241. doi: 10.1016/S1002-0721(08)60073-3
20. [20]
  (20) Xu, D.; Liu, X. M.;Wang, D. J.; Yi, G. Y.; Gao, Y.; Zhang, D.S.; Su,W. H. J. Alloy. Compd. 2007, 429, 292. doi: 10.1016/j.jallcom.2006.04.009
21. [21]
  (21) Jo, S. H.; Muralidharan, P.; Kim, D. K. J. Alloy. Compd. 2010,491, 416. doi: 10.1016/j.jallcom.2009.10.207
22. [22]
  (22) Hao, G. Y.; Liu, X. M.;Wang, H. P.; Be, H. L.; Pei, L.; Su,W.H. Solid State Ionics 2012, 225, 81. doi: 10.1016/j.ssi.2012.03.005
23. [23]
  (23) Medvedev, D.; Mara u, V.; Pikalova, E.; Demin, A.; Tsiakaras,P. J. Power Sources 2013, 221, 217. doi: 10.1016/j.jpowsour.2012.07.120
24. [24]
  (24) Xu, D.; Liu, X. M.;Wang, D. J.; Zhu, C. J.; Yan, D. T.; Pei, L.;Su,W. H. Chem. J. Chin. Univ. 2008, 29, 1523. [徐丹, 刘晓梅, 王德军, 朱成军, 严端廷, 裴力, 苏文辉. 高等学校化学学报, 2008, 29, 1523.]
25. [25]
  (25) Zhang, T. S.; Hing, P.; Huang, H. T.; Kilner, J. J. Eur. Ceram. Soc. 2002, 22, 27. doi: 10.1016/S0955-2219(01)00240-0
26. [26]
  (26) Li, J. G.; Ikegami, T.; Mori, T. Acta Materialia 2004, 52 (8),2221. doi: 10.1016/j.actamat.2004.01.014
27. [27]
  (27) Pikalova, E. Yu. Murashkina, A. A.; Mara u, V. I.; Demin, A.K.; Strekalovsky, V. N.; Tsiakaras, P. E. Int. J. Hydrog. Energy2011, 36 (10), 6175. doi: 10.1016/j.ijhydene.2011.01.132
28. [28]
  (28) Kahlauoi, M.; Inoubli, A.; Chefi, S.; Kouki, A.; Madani, A.;Chefi, C. Ceram. Int. 2013, 39 (6), 6175. doi: 10.1016/j.ceramint.2013.01.036
29. [29]
  (29) Zhou, D. F.; Zhu, J. X.; Xia, Y. J.; Zhao, G. C.; Meng, J. Chin. J. Inorg. Chem. 2010, 26 (1), 91. [周德凤, 朱建新, 夏燕杰, 赵桂春, 孟健. 无机化学学报, 2010, 26 (1), 91.]
30. [30]
  (30) Guo, X.;Waser, R. Prog. Mater. Sci. 2006, 51 (2), 151. doi: 10.1016/j.pmatsci.2005.07.001
31. [31]
  (31) Wang, X. D.; Mab, Y.; Raza, R.; Muhammed, M.; Zhu, B.Electrochem. Commun. 2008, 10, 1617. doi: 10.1016/j.elecom.2008.08.023
32. [32]
  (32) Zhang, Z.; Zhang, H.; Liu, C. F.; Liu, Y. L.; Li, Z. C. Materials Science and Engineering of Powder Metalluray 2011, 16 (5),682. [张哲, 张鸿, 刘超峰, 刘玉龙, 李志成. 粉末冶金材料科学与工程, 2011, 16 (5), 682.]
33. [33]
  (33) Guo, X.; Sigle,W.; Maier, J. J. Am. Ceram. Soc. 2003, 86, 77.doi: 10.1111/jace.2003.86.issue-1
34. [34]
  (34) Zhang, T. S.; Ma, J.; Chan, S. H.; Kilner, J. A. Solid State Ionics2005, 176 (3-4), 377. doi: 10.1016/j.ssi.2004.07.022
35. [35]
  (35) Schouler, E.; Giroud, G.; Kleitz, M. J. Chem. Phys. 1973, 70,1309.
36. [36]
  (36) Rahmawati, F.; Prijamboedi, B.; Soepriyanto, S.; Ismunandar.Int. J. Min. Met. Mater. 2012, 19 (9), 863. doi: 10.1007/s12613-012-0640-0
37. [37]
  (37) Cho, Y. H.; Cho, P. S.; Auchterlonie, G.; Kim, D. K.; Lee, J. H.;Kim, D. Y.; Park, H. M.; Drennan, J. Acta Materialia 2007, 55 (14), 4807. doi: 10.1016/j.actamat.2007.05.001
38. [38]
  (38) Kim, D. K.; Cho, P. S.; Lee, J. H.; Kim, D. Y.; Park, H. M.;Auchterlonie, G.; Drennan, J. Electrochem. Solid State Lett.2007, 10 (5), 91. doi: 10.1149/1.2710959
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沈阳化工大学材料科学与工程学院沈阳 110142

Structure and Electrical Properties of Ce0.8Nd0.2O1.9-La0.95Sr0.05Ga0.9Mg0.1O3-δ Solid Composite Electrolytes

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通讯作者: 陈斌, bchen63@163.com

Structure and Electrical Properties of Ce_0.8Nd_0.2O_1.9-La_0.95Sr_0.05Ga_0.9Mg_0.1O_3-δ Solid Composite Electrolytes