Citation: ABULIMITI Bumaliya, ZHU Rong-Shu, QIU Xue-Jun, QIN Chen, ZHANG Bing. Studies of Ultrafast Dynamics of 3-Picoline with Femtosecond Time-Resolved Photoelectron Imaging[J]. Acta Physico-Chimica Sinica, ;2014, 30(1): 22-27. doi: 10.3866/PKU.WHXB201311122 shu

Studies of Ultrafast Dynamics of 3-Picoline with Femtosecond Time-Resolved Photoelectron Imaging

ABULIMITI Bumaliya ^1,2,3 ,
ZHU Rong-Shu ^1, ,
QIU Xue-Jun ^2,3 ,
QIN Chen ^2,3 ,
ZHANG Bing ^2,3,

1.
1 Environmental Science and Engineering Research Center, Harbin Institute of Technology Shenzhen Graduate School, Shenzhen 518055, Guangdong Province, P. R. China;
2 State Key Laboratory of Magnetic Resonance and Atomic and Molecular Physics, Wuhan Institute of Physics and Mathematics, Chinese Academy of Sciences, Wuhan 430071, P. R. China;
3 University of Chinese Academy of Sciences, Beijing 100049, P. R. China

Received Date: 29 August 2013
Available Online: 12 November 2013
Fund Project: 国家自然科学基金(91121006，21273274)资助项目 (91121006，21273274)

The ultrafast dynamics of excited states in 3-picoline were studied using femtosecond timeresolved photoelectron imaging, coupled with time-resolved mass spectroscopy. An ultrafast internal conversion from the S₂ state to the vibrationally excited S₁ state in about 910 fs was observed. This secondary-populated S₁ state further deactivates to the S₀ state in 2.77 ps. The photoelectron energy and angular distributions show ionizations from the singlet 3p Rydberg states. Two 400 nm photon excitations to the 3s Rydberg state suggest that this state probably decays to the ground state in 62 fs.
- Picoline,
- Photoelectron imaging,
- Internal conversion,
- Pump-probe,
- Time-resolved spectroscopy
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