Citation:
ABULIMITI Bumaliya, ZHU Rong-Shu, QIU Xue-Jun, QIN Chen, ZHANG Bing. Studies of Ultrafast Dynamics of 3-Picoline with Femtosecond Time-Resolved Photoelectron Imaging[J]. Acta Physico-Chimica Sinica,
;2014, 30(1): 22-27.
doi:
10.3866/PKU.WHXB201311122
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The ultrafast dynamics of excited states in 3-picoline were studied using femtosecond timeresolved photoelectron imaging, coupled with time-resolved mass spectroscopy. An ultrafast internal conversion from the S2 state to the vibrationally excited S1 state in about 910 fs was observed. This secondary-populated S1 state further deactivates to the S0 state in 2.77 ps. The photoelectron energy and angular distributions show ionizations from the singlet 3p Rydberg states. Two 400 nm photon excitations to the 3s Rydberg state suggest that this state probably decays to the ground state in 62 fs.
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