Citation: WANG Chang-Shun, KAN Cai-Xia, NI Yuan, XU Hai-Ying. Facile Preparation and Growth Mechanism of New-Type ld Nanoplates[J]. Acta Physico-Chimica Sinica, ;2014, 30(1): 194-204. doi: 10.3866/PKU.WHXB201311053 shu

Facile Preparation and Growth Mechanism of New-Type ld Nanoplates

1.
1 Department of Applied Physics, College of Science, Nanjing University of Aeronautics and Astronautics, Nanjing 211106, P. R. China;
2 Key Laboratory for Intelligent Nano Materials and Devices of the Ministry of Education, Nanjing University of Aeronautics and Astronautics, Nanjing 211106, P. R. China

Received Date: 23 August 2013
Available Online: 5 November 2013
Fund Project: 南京航空航天大学基本科研项目(NZ2013204)资助 (NZ2013204)

When a sticky gel consisting of an aqueous HAuCl₄ solution mixed with poly-vinylpyrrolidone (PVP) surfactant is kept at room temperature (about 30 ℃), the HAuCl₄ is reduced by the PVP, resulting in the formation of nanostructures. In this study, ld nanoplates with new shapes, which were single crystalline, several micrometers wide, and tens of nanometers thick, were mass-synthesized by adjusting the crystal growth conditions. For example, through inducing temperature decrease (10-20 ℃) in the early stage of crystal growth, the product is dominated by star-like ld nanoplates, together with other new shapes such as shields, concave and convex triangles, corner snipped shapes, triple branched shapes, and shapes that are step-rich in the side plane. Based on theoretical calculations, we present the growth mechanism of these new ld nanoplates. Under certain growth conditions, the (111) plane of the ld crystal can grow not only along the <110> direction into regular triangular or hexa nal nanoplates, but also along other directions such as <211> and <321>, to give new nanoplates with high-index side facets.
- ld nanoplate,
- Poly-vinylpyrrolidone,
- Star-like shape,
- Growth mechanism,
- High-index facet
1. [1]
  
  (1) Lal, S.; Link, S.; Halas, N. J. Nat. Photonics 2007, 1, 641.doi: 10.1038/nphoton.2007.223
2. [2]
  (2) De, M.; Ghosh, P. S.; Rotello, V. M. Adv. Mater. 2008, 20,4225. doi: 10.1002/adma.v20:22
3. [3]
  (3) Zijlstra, P.; Chon, J.W.; Gu, M. Nature 2009, 459, 410.doi: 10.1038/nature08053
4. [4]
  (4) Vigderman, L.; Khanal, B. P.; Zubarev, E. R. Adv. Mater. 2012,24, 4811. doi: 10.1002/adma.201201690
5. [5]
  (5) Liu, X.W.;Wang, D. S.; Li, Y. D. Nano Today 2012, 7, 448.doi: 10.1016/j.nantod.2012.08.003
6. [6]
  (6) ng, J. X.; Li, G. D.; Tang, Z. Y. Nano Today 2012, 7, 564.doi: 10.1016/j.nantod.2012.10.008
7. [7]
  (7) Dykman, L.; Khlebtsov, N. Chem. Soc. Rev. 2012, 41, 2256.doi: 10.1039/c1cs15166e
8. [8]
  (8) Rycenga, M.; Cobley, C. M.; Zeng, J.; Li,W. Y.; Moran, C. H.;Zhang, Q.; Qin, D.; Xia, Y. N. Chem. Rev. 2011, 111, 3669. doi: 10.1021/cr100275d
9. [9]
  (9) Dreaden, E. C.; Alkilany, A. M.; Huang, X. H.; Murphy, C. J.;El-Sayed, M. A. Chem. Soc. Rev. 2012, 41, 2740. doi: 10.1039/c1cs15237h
10. [10]
  (10) Li, Z.; Zhang, S.; Halas, N. J.; Nordlander, P.; Xu, H. Small2011, 7, 593. doi: 10.1002/smll.v7.5
11. [11]
  (11) Auguie, B.; Barnes,W. L. Phys. Rev. Lett. 2008, 101, 143902.doi: 10.1103/PhysRevLett.101.143902
12. [12]
  (12) Naumov, I. I.; Li, Z. Y.; Bratkovsky, A. M. Appl. Phys. Lett.2010, 96, 033105. doi: 10.1063/1.3273859
13. [13]
  (13) Ray, P. C. Chem. Rev. 2010, 110, 5332. doi: 10.1021/cr900335q
14. [14]
  (14) Ming, T.; Zhao, L.; Xiao, M. D.;Wang, J. F. Small 2010, 6,2514. doi: 10.1002/smll.201000920
15. [15]
  (15) Yu, Y. Y.; Chang, S. S.; Lee, C. L.;Wang, C. R. C. J. Phys. Chem. B 1997, 101, 6661. doi: 10.1021/jp971656q
16. [16]
  (16) Link, S.; Mohamed, M. B.; El-Sayed, M. A. J. Phys. Chem. B1999, 103, 3073.
17. [17]
  (17) van der Zande, B. M. I.; Bohmer, M. R.; Fokkink, L. G. J.;Schonenberger, C. Langmuir 2000, 16, 451. doi: 10.1021/la9900425
18. [18]
  (18) Jana, N. R.; Gearheart, L.; Murphy, C. J. J. Phys. Chem. B 2001,105, 4065.
19. [19]
  (19) Busbee, B. D.; Obare, S. O.; Murphy, C. J. Adv. Mater. 2003, 15,414. doi: 10.1002/adma.200390095
20. [20]
  (20) Sun, Y. G.; Xia, Y. N. Adv. Mater. 2002, 14, 833. doi: 10.1002/1521-4095(20020605)14:11<833::AID-ADMA833>3.0.CO;2-K
21. [21]
  (21) Chen, S. H.; Carroll, D. L. Nano Lett. 2002, 2, 1003. doi: 10.1021/nl025674h
22. [22]
  (22) Sun, Y. G.; Mayers, B.; Xia, Y. N. Nano Lett. 2003, 3, 675.doi: 10.1021/nl034140t
23. [23]
  (23) Okada, N.; Hamanaka, Y.; Nakamura, A.; Pastoriza-Santos, I.;Liz-Marzan, L. M. J. Phys. Chem. B 2004, 108, 8751. doi: 10.1021/jp048193q
24. [24]
  (24) Kan, C. X.; Zhu, X. G.;Wang, G. H. J. Phys. Chem. B 2006,110, 4651. doi: 10.1021/jp054800d
25. [25]
  (25) Li, C. C.; Sato, R.; Kanehara, M.; Zeng, H. B.; Bando, Y.;Teranishi, T. Angew. Chem. Int. Edit. 2009, 48, 6883.doi: 10.1002/anie.v48:37
26. [26]
  (26) Sau, T. K.; Rogach, A. L. Adv. Mater. 2010, 22, 1781. doi: 10.1002/adma.v22:16
27. [27]
  (27) Chen, A. Q.; Deprince, A. E., III; Demortiere, A.; Joshi-Imre,A.; Shevchenko, E. V.; Gray, S. K.;Welp, U.; Vlasko-Vlasov, V.K. Small 2011, 7, 2365. doi: 10.1002/smll.v7.16
28. [28]
  (28) Tao, A. R.; Habas, S.; Yang, P. D. Small 2008, 4, 310.
29. [29]
  (29) Tian, N.; Zhou, Z. Y.; Sun, S. G.; Ding, Y.;Wang, Z. L. Science2007, 316, 732. doi: 10.1126/science.1140484
30. [30]
  (30) Xia, Y. N.; Xiong, Y. J.; Lim, B.; Skrabalak, S. E. Angew. Chem. Int. Edit. 2009, 48, 60. doi: 10.1002/anie.200802248
31. [31]
  (31) Homan, K. A.; Chen, J.; Schiano, A.; Mohamed, M.;Willets, K.A.; Murugesan, S.; Stevenson, K. J.; Emelianov, S. Adv. Funct. Mater. 2011, 21, 1673. doi: 10.1002/adfm.201001556
32. [32]
  (32) Kan, C. X.;Wang, C. S.; Li, H. C.; Qi, J. S.; Zhu, J. J.; Li, Z. S.;Shi, D. N. Small 2010, 6, 1768. doi: 10.1002/smll.201000600
33. [33]
  (33) Xia, Y. N.; Xia, X. H.;Wang, Y.; Xie, S. F. MRS Bull. 2013, 38,335. doi: 10.1557/mrs.2013.84
34. [34]
  (34) Morriss, R. H.; Bottoms,W. R.; Peacock, R. J. J. Appl. Phys.1968, 39, 3016. doi: 10.1063/1.1656724
35. [35]
  (35) Kan, C. X.;Wang, C. S.; Zhu, J. J.; Li, H. C. J. Solid State Chem. 2010, 183, 858. doi: 10.1016/j.jssc.2010.01.021
36. [36]
  (36) Washio, I.; Xiong, Y. J.; Yin, Y. D.; Xia, Y. N. Adv. Mater. 2006,18, 1745.
37. [37]
  (37) Courty, A.; Henry, A. I.; ubet, N.; Pileni, M. P. Nat. Mater.2007, 6, 900. doi: 10.1038/nmat2004
38. [38]
  (38) Radha, B.; Kulkarni, G. U. Crystal Growth & Design 2011, 11,320. doi: 10.1021/cg1015548
39. [39]
  (39) Jin, R. C.; Cao, Y. C.; Hao, E.; Metraux, G. S.; Schatz, G. C.;Mirkin, C. A. Nature 2003, 425, 487. doi: 10.1038/nature02020
40. [40]
  (40) Li, C. C.; Cai,W. P.; Cao, B. Q.; Sun, F. Q.; Li, Y.; Kan, C. X.;Zhang, L. D. Adv. Funct. Mater. 2006, 16, 83.
41. [41]
  (41) Yao, L. Z. Foundation of Crystal Growth; University of Scienceand Technology of China Press: Hefei, 1995; pp 258-310, 409-429. [姚连增. 晶体生长基础. 合肥: 中国科学技术大学出版社, 1995: 258-310; 409-429.]
42. [42]
  (42) Kan, C. X.; Cai,W. P.; Li, C. C.; Zhang, L. D. J. Mater. Res.2004, 20, 320.
43. [43]
  (43) Kamat, P. V. J. Phys. Chem. B 2002, 106, 7729. doi: 10.1021/jp0209289
44. [44]
  (44) Wiley, B.; Sun, Y. G.; Chen, J. Y.; Cang, H.; Li, Z. Y.; Li, X. D.;Xia, Y. N. MRS Bull. 2005, 30, 356. doi: 10.1557/mrs2005.98
45. [45]
  (45) Germain, V.; Li, J.; Ingert, D.;Wang, Z. L.; Pileni, M. P. J. Phys. Chem. B 2003, 107, 8717. doi: 10.1021/jp0303826
46. [46]
  (46) Aherne, D.; Ledwith, D. M.; Gara, M.; Kelly, J. M. Adv. Funct. Mater. 2008, 18, 2005. doi: 10.1002/adfm.v18:14
47. [47]
  (47) Duan, J. Y.; Zhang, Q. X.;Wang, Y. L.; Guan, J. G. Acta Phys. - Chim. Sin. 2009, 25, 1405. [段君元, 章桥新, 王一龙, 官建国.物理化学学报, 2009, 25, 1405.] doi: 10.3866/PKU.WHXB20090731
48. [48]
  (48) Wang, Z. L. J. Phys. Chem. B 2000, 104, 1153. doi: 10.1021/jp993593c
49. [49]
  (49) Xue, C.; Metraux, G. S.; Millstone, J. E.; Mirkin, C. A. J. Am. Chem. Soc. 2008, 130, 8337. doi: 10.1021/ja8005258
50. [50]
  (50) Xiong, Y. J.;Washio, I.; Chen, J. Y.; Cai, H. G.; Li, Z. Y.; Xia, Y.N. Langmuir 2006, 22, 8563. doi: 10.1021/la061323x
51. [51]
  (51) Nam, H. S.; Hwang, N. M.; Yu, B. D.; Yoon, J. K. Phys. Rev. Lett. 2002, 89, 275502. doi: 10.1103/PhysRevLett.89.275502
52. [52]
  (52) Cao, Y. L.; Ding, X. L.; Li, H. C.; Yi, Z. G.;Wang, X. F.; Zhu, J.J.; Kan, C. X. Acta Phys. -Chim. Sin. 2011, 27, 1273. [曹艳丽,丁孝龙, 李红臣, 伊兆广, 王祥夫, 朱杰君, 阚彩侠. 物理化学学报, 2011, 27, 1273.] doi: 10.3866/PKU.WHXB20110604
53. [53]
  (53) Hoppe, C. E.; Lazzari, M.; Pardinas-Blanco, I.; Lopez-Quintela,M. A. Langmuir 2006, 22, 7027. doi: 10.1021/la060885d
54. [54]
  (54) Wang, C. S.; Kan, C. X.; Zhu, J. J.; Zeng, X. L.;Wang, X. F.; Li,H. C.; Shi, D. N. Journal of Nanomaterials 2010, 969030.
55. [55]
  (55) Delley, B. J. Chem. Phys. 2000, 113, 7756. doi: 10.1063/1.1316015
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