Citation: WANG Chang-Shun, KAN Cai-Xia, NI Yuan, XU Hai-Ying. Facile Preparation and Growth Mechanism of New-Type ld Nanoplates[J]. Acta Physico-Chimica Sinica, ;2014, 30(1): 194-204. doi: 10.3866/PKU.WHXB201311053 shu

Facile Preparation and Growth Mechanism of New-Type ld Nanoplates

1.
1 Department of Applied Physics, College of Science, Nanjing University of Aeronautics and Astronautics, Nanjing 211106, P. R. China;
2 Key Laboratory for Intelligent Nano Materials and Devices of the Ministry of Education, Nanjing University of Aeronautics and Astronautics, Nanjing 211106, P. R. China

Received Date: 23 August 2013
Available Online: 5 November 2013
Fund Project: 南京航空航天大学基本科研项目(NZ2013204)资助 (NZ2013204)

When a sticky gel consisting of an aqueous HAuCl₄ solution mixed with poly-vinylpyrrolidone (PVP) surfactant is kept at room temperature (about 30 ℃), the HAuCl₄ is reduced by the PVP, resulting in the formation of nanostructures. In this study, ld nanoplates with new shapes, which were single crystalline, several micrometers wide, and tens of nanometers thick, were mass-synthesized by adjusting the crystal growth conditions. For example, through inducing temperature decrease (10-20 ℃) in the early stage of crystal growth, the product is dominated by star-like ld nanoplates, together with other new shapes such as shields, concave and convex triangles, corner snipped shapes, triple branched shapes, and shapes that are step-rich in the side plane. Based on theoretical calculations, we present the growth mechanism of these new ld nanoplates. Under certain growth conditions, the (111) plane of the ld crystal can grow not only along the <110> direction into regular triangular or hexa nal nanoplates, but also along other directions such as <211> and <321>, to give new nanoplates with high-index side facets.
- ld nanoplate,
- Poly-vinylpyrrolidone,
- Star-like shape,
- Growth mechanism,
- High-index facet
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