Citation: DONG Li-Li, WANG Ying-Yong, TONG Xi-Li, JIN Guo-Qiang, GUO Xiang-Yun. Synthesis and Characterization of Boron-Doped SiC for Visible Light Driven Hydrogen Production[J]. Acta Physico-Chimica Sinica, ;2014, 30(1): 135-140. doi: 10.3866/PKU.WHXB201311052 shu

Synthesis and Characterization of Boron-Doped SiC for Visible Light Driven Hydrogen Production

1.
1 State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, P. R. China;
2 University of Chinese Academy of Sciences, Beijing 100049, P. R. China

Received Date: 22 August 2013
Available Online: 5 November 2013
Fund Project: 国家自然科学基金(21173251，21203233)，中国科学院山西煤炭化学研究所创新基金(Y1SC6R1991) (21173251，21203233)，中国科学院山西煤炭化学研究所创新基金(Y1SC6R1991)煤转化国家重点实验室自主项目(2013BWZ006)资助 (2013BWZ006)

Boron-doped β-SiC (B_xSiC) photocatalysts were prepared by in-situ carbothermal reduction, and their photocatalytic performances for H₂ evolution under visible light irradiation were investigated. The crystal structure, surface property, morphology, and band gap structure of the B_xSiC photocatalysts were studied using X-ray diffraction, X-ray photoelectron spectroscopy, scanning electron microscopy, and ultraviolet-visible absorption spectroscopy. The characterization results indicate that B atoms have doped into the SiC lattice and substituted Si sites, leading to the formation of a shallow acceptor level above the valence band of SiC, resulting in a narrowed band gap energy. The shallow acceptor level acts as a hole trap, preventing the recombination of photo-excited electrons and holes. Therefore, the photocatalytic H₂ evolution activity of B-doped SiC was greatly improved compared with that of SiC. The highest hydrogen evolution rate was obtained when the B/Si molar ratio was 0.05.
- β-SiC,
- B doping,
- Photocatalysis,
- Hydrogen evolution,
- Visible light
1. [1]
  
  (1) Maeda, K.; Teramura, K.; Lu, D. L.; Takata, T.; Saito, N.; Inoue,Y.; Domen, K. Nature 2006, 440, 295. doi: 10.1038/440295a
2. [2]
  (2) Nowotny, J.; Sorrell, C. C.; Sheppard, L. R.; Bak, T. Int. J. Hydrog. Energy 2005, 30, 521. doi: 10.1016/j.ijhydene.2004.06.012
3. [3]
  (3) Chen, X. B.; Shen, S. H.; Guo, L. J.; Mao, S. S. Chem. Rev.2010, 110, 6503. doi: 10.1021/cr1001645
4. [4]
  (4) Kudo, A.; Miseki, Y. Chem. Soc. Rev. 2009, 38, 253. doi: 10.1039/b800489g
5. [5]
  (5) Wang, Q.; Liu, H.; Jiang, L.; Yuan, J.; Shangguan,W. Catal. Lett. 2009, 131, 160. doi: 10.1007/s10562-009-9949-3
6. [6]
  (6) Gao, Y. T.;Wang, Y. Q.;Wang, Y. X. React. Kinet. Catal. Lett.2007, 91, 12.
7. [7]
  (7) Hao, J. Y.;Wang, Y. Y.; Tong, X. L.; Jin, G. Q.; Guo, X. Y. Int. J. Hydrog. Energy 2012, 37, 15038. doi: 10.1016/j.ijhydene.2012.08.021
8. [8]
  (8) Yang, J. J.; Zeng, X. P.; Chen, L. J.; Yuan,W. X. Appl. Phys. Lett. 2013, 102, 083101. doi: 10.1063/1.4792695
9. [9]
  (9) Wu, X. L.; Xiong, S. J.; Zhu, J.;Wang, J.; Shen, J. C.; Chu, P. K.Nano Lett. 2009, 9, 4053. doi: 10.1021/nl902226u
10. [10]
  (10) Li, Y. X.; Ma, G. F.; Peng, S. Q.; Lu, G. X.; Li, S. B. Appl. Surf. Sci. 2008, 254, 6831. doi: 10.1016/j.apsusc.2008.04.075
11. [11]
  (11) Ruschenschmidt, K.; Bracht, H.; Laube, M.; Stolwijk, N. A.;Pensl, G. Physica B 2001, 308, 734.
12. [12]
  (12) Persson, C.; Lindefelt, U.; Sernelius, B. E. J. Appl. Phys. 1999,86, 4419. doi: 10.1063/1.371380
13. [13]
  (13) Agathopoulos, S. Ceram. Int. 2012, 38, 3309. doi: 10.1016/j.ceramint.2011.12.040
14. [14]
  (14) Shimoda, K.; Park, J. S.; Hinoki, T.; Kohyama, A. Appl. Surf. Sci. 2007, 253, 9450. doi: 10.1016/j.apsusc.2007.06.023
15. [15]
  (15) Oswald, S.;Wirth, H. Surf. Interface Anal. 1999, 27, 136.
16. [16]
  (16) Seo,W. S.; Koumoto, K.; Arai, S. J. Am. Ceram. Soc. 1998, 81,1255.
17. [17]
  (17) Cerovic, L.; Milonjic, S. K.; Zec, S. P. Ceram. Int. 1995, 21,271. doi: 10.1016/0272-8842(95)99793-B
18. [18]
  (18) Chen, J.; Tang,W.; Xin, L.; Shi, Q. Appl. Phys. A-Mater. 2011,102, 213. doi: 10.1007/s00339-010-5943-2
19. [19]
  (19) Zhou,W. M.; Yan, L. J.;Wang, Y.; Zhang, Y. F. Appl. Phys. Lett.2006, 89, 013105. doi: 10.1063/1.2219139
20. [20]
  (20) Fukumoto, A. Phys. Rev. B 1996, 53, 4458. doi: 10.1103/PhysRevB.53.4458
21. [21]
  (21) Weingartner, R.; Bickermann, M.; Bushevoy, S.; Hofmann, D.;Rasp, M.; Straubinger, T. L.;Wellmann, P. J.;Winnacker, A.Mater. Sci. Eng. B 2001, 80, 357. doi: 10.1016/S0921-5107(00)00599-7
22. [22]
  (22) Sebastian, P. J.; Matthews, N. R.; Mathew, X.; Pattabi, M.;Turner, J. Int. J. Hydrog. Energy 2001, 26, 123. doi: 10.1016/S0360-3199(00)00047-1
23. [23]
  (23) Akikusa, J.; Khan, S. U. M. Int. J. Hydrog. Energy 2002, 27,863. doi: 10.1016/S0360-3199(01)00191-4
24. [24]
  (24) Sayama, K.; Nomura, A.; Arai, T.; Sugita, T.; Abe, R.; Yanagida,M.; Oi, T.; Iwasaki, Y.; Abe, Y.; Sugihara, H. J. Phys. Chem. B2006, 110, 11352. doi: 10.1021/jp057539+
25. [25]
  (25) Kanhere, P.; Zheng, J.W.; Chen, Z. Int. J. Hydrog. Energy 2012,37, 4889. doi: 10.1016/j.ijhydene.2011.12.056
26. [26]
  (26) Li,W. Z.; Li, J.;Wang, X.; Chen, Q. Y. Appl. Surf. Sci. 2012,263, 157. doi: 10.1016/j.apsusc.2012.09.021
27. [27]
  (27) Yuan,W. H.; Liu, X. C.; Li, L. Acta Phys. -Chim. Sin. 2013, 29,151. [袁文辉, 刘晓晨, 李莉. 物理化学学报, 2013, 29,151.] doi: 10.3866/PKU.WHXB201210093
28. [28]
  (28) Sun, X. J.; Liu, H.; Dong, J. H.;Wei, J. Z.; Zhang, Y. Catal. Lett. 2010, 135, 219. doi: 10.1007/s10562-010-0302-7
29. [29]
  (29) Husin, H.; Chen, H. M.; Su,W. N.; Pan, C. J.; Chuang,W. T.;Sheu, H. S.; Hwang, B. J. Appl. Catal. B-Environ. 2011, 102,343. doi: 10.1016/j.apcatb.2010.12.024
30. [30]
  (30) Yan, S.; Huang, Q. D.; Lin, J. D.; Yuan, Y. Z.; Liao, D.W. Acta Phys. -Chim. Sin. 2011, 27, 2406. [闫石, 黄勤栋, 林敬东,袁友珠, 廖代伟. 物理化学学报, 2011, 27, 2406.] doi: 10.3866/PKU.WHXB20110929
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