Citation: CAI Zhi-Bin, LIU Li-Fen, KONG Cheng, ZHU Yao-Xin. Synthesis, Characterization and Two-Photon Absorption Properties of Novel Blue Up-Converted Fluorescent Molecules[J]. Acta Physico-Chimica Sinica, ;2014, 30(1): 164-170. doi: 10.3866/PKU.WHXB201311051 shu

Synthesis, Characterization and Two-Photon Absorption Properties of Novel Blue Up-Converted Fluorescent Molecules

  • Received Date: 16 August 2013
    Available Online: 5 November 2013

    Fund Project: 国家自然科学基金(21103151) (21103151)浙江省重点科技创新团队(2010R50018)资助项目 (2010R50018)

  • Three new acceptor-donor-acceptor (A-D-A) up-converted fluorescent molecules were designed and synthesized. Their structures were characterized using Fourier transform infrared and hydrogen nuclear magnetic resonance spectroscopy, mass spectrometry, and elemental analysis. The linear absorption spectra, single-photon excited fluorescence spectra, and fluorescence quantum yields were measured in different solvents. The two-photon absorption and up-converted fluorescent properties were studied using a femtosecond laser. The results showed that the fluorescence quantum yields were 0.20-0.68, the two-photon absorption cross-sections were 16×10-50-101×10-50 cm4·s·photon-1, and they exhibited strong blue up-converted fluorescence.

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