Citation: ZHOU Yang, HU Xian-Chao, LI Li-Qing, CHEN Xi-Rong. Palladium Nanoparticles Supported on Hollow Mesoporous Tungsten Trioxide Microsphere as Electrocatalyst for Formic Acid Oxidation[J]. Acta Physico-Chimica Sinica, ;2014, 30(1): 83-87. doi: 10.3866/PKU.WHXB201311012 shu

Palladium Nanoparticles Supported on Hollow Mesoporous Tungsten Trioxide Microsphere as Electrocatalyst for Formic Acid Oxidation

1.
1 Engineering Research Center of High-Efficiency Development and Application Technology of Tungsten Resources, Jiangxi University of Science and Technology, Ganzhou 341000, Jiangxi Province, P. R. China;
2 Metallurgical and Chemical Engineering Institute, Jiangxi University of Science and Technology, Ganzhou 341000, Jiangxi Province, P. R. China;
3 Research Center of Analysis and Measurement, Zhejiang University of Technology, Hangzhou 310032, P. R. China

Received Date: 11 August 2013
Available Online: 1 November 2013
Fund Project: 江西理工大学博士后科研基金，浙江省科技厅项目(2013C37104) (2013C37104)江西省自然科学基金(20132BAB213009)资助 (20132BAB213009)

Hollow mesoporous tungsten trioxide microsphere (HMTTS) was synthesized by spay drying method and employed as the support material for Pd catalyst. The catalyst was characterized by X-ray powder diffraction (XRD), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). The Pd nanoparticles had a face-centered cubic crystal structure and were well dispersed on the external walls of HMTTS. The as-prepared Pd/HMTTS catalyst exhibits higher electrocatalytic activity and od stability during formic acid oxidation in comparison to Pd/WO₃ catalyst. The enhanced catalytic performance is attributed to the unique structure and surface properties of HMTTS and the hydrogen spillover effect which greatly accelerates the direct dehydrogenation of formic acid on palladium.
- Direct formic acid fuel cell,
- Formic acid oxidation,
- Tungsten trioxide,
- Electrocatalyst,
- Mesoporous material
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