Citation: WANG Yue-Hui, WANG Ting, ZHOU Ji. Studies of Enhanced Fluorescence Effects of Europium(Ⅲ) Dipicolinic Acid Complex by Silver Nanoparticles[J]. Acta Physico-Chimica Sinica, ;2014, 30(1): 28-33. doi: 10.3866/PKU.WHXB201311011 shu

Studies of Enhanced Fluorescence Effects of Europium(Ⅲ) Dipicolinic Acid Complex by Silver Nanoparticles

1.
1 Department of Chemistry and Biology Engineering, University of Electronic Science and Technology of Zhongshan Institute, Zhongshan 528402, Guangdong Province, P. R. China;
2 Beijing General Research Institute for Nonferrous Metals, Beijing 100088, P. R. China;
3 State Key Laboratory of New Ceramics and Fine Processing, Department of Materials Science and Engineering, Tsinghua University, Beijing 100084, P. R. China

Received Date: 22 July 2013
Available Online: 1 November 2013
Fund Project: 国家自然科学基金(61302044)，广东省自然科学基金(S2012010010646) (61302044)，广东省自然科学基金(S2012010010646)电子科技大学中山学院科研启动基金(407YKQ06)资助项目 (407YKQ06)

The enhanced fluorescence effect of silver nanoparticles on a europium complex, Eu(Ⅲ)DPA, where DPA is dipicolinic acid (C₇H₅NO₄), with deionized (DI) water, heavy water, ethanol, and dimethylformamide as solvents, was studied. The results indicated that with increasing silver nanoparticle concentration, the intensities of the electric dipole transition (⁵D₀→⁷F₂)and magnetic dipole transition (⁵D₀→⁷F₁) first increased and then decreased, and the enhancement efficiency of ⁵D₀→⁷F₂ was higher than that of ⁵D₀→⁷F₁. The enhanced fluorescence effect of silver nanoparticles on Eu(Ⅲ)DPA was maximum in ethanol. In the DI water, heavy water, and ethanol solution systems, the asymmetric ratio increased significantly, but there was little change in the dimethylformamide solution system. The observed silver nanoparticle dependence of the luminescent intensity of Eu(Ⅲ)DPA was considered to be the result of stronger coupling between the surface plasmon resonance and the excited luminescence centers, and reabsorption of the surface plasmon resonance of silver nanoparticles.
- Silver nanoparticle,
- Europium complex,
- Localized surface plasmons resonance,
- Enhanced fluorescence,
- Solvent
1. [1]
  
  (1) Malicka, J.; Gryaynski, I.; Fang J.; Kusba, J.; Lakowicz, J. R.Anal. Biochem. 2003, 315, 160. doi: 10.1016/S0003-2697(02)00710-8
2. [2]
  (2) Podolskiy, V. A.; Sarychev, A. K.; Narimanov, E. E. J. Optic A2005, 7, S32.
3. [3]
  (3) Wang, Y. H.; Shen, J. H. Acta Phys. -Chim. Sin. 2012, 28, 1314.[王悦辉, 沈建红. 物理化学学报, 2012, 28, 1314.] doi: 10.3866/PKU.WHXB201203292
4. [4]
  (4) Ipe, B. I.; Mahima, S.; Thomas, K. G. J. Am. Chem. Soc. 2003,125, 7174. doi: 10.1021/ja0341182
5. [5]
  (5) Maier, S. A.; Kik, P. G.; Atwater, H. A.; Meltzer, S.; Harel, E.;Koel, B. E.; Requicha, A. A. G. Nature Materials 2003, 2, 229.
6. [6]
  (6) Haes, A. J.; Chang, L.; Klein,W. L.; Van-Duyne, R. P. J. Am. Chem. Soc. 2005, 127, 2264.
7. [7]
  (7) Fu, Y.; Zhang, J.; Lakowicz, J. R. Biochemical and Biophysical Research Communications 2008, 376, 712. doi: 10.1016/j.bbrc.2008.09.062
8. [8]
  (8) Szmacinski, H.; Ray, K.; Lakowicz, J. R. Analytical Biochemistry 2009, 385, 358. doi: 10.1016/j.ab.2008.11.025
9. [9]
  (9) Fu, Y.; Jian, Z.; Lakowicz, J. R. J. Phys. Chem. C 2011, 115,7202. doi: 10.1021/jp109617h
10. [10]
  (10) Kumar, J.; Thomas, K. G. J. Phys. Chem. Lett. 2011, 2, 610. doi: 10.1021/jz2000613
11. [11]
  (11) Ming, T.; Zhao, L.; Chen, H. J.;Woo, K. C.;Wang, J. F.; Lin, H.Q. Nano Lett. 2011, 11, 2296. doi: 10.1021/nl200535y
12. [12]
  (12) Fu, Y.; Zhang, J.; Lakowicz, J. R. J. Am. Chem. Soc. 2010, 132,5540. doi: 10.1021/ja9096237
13. [13]
  (13) Fu, Y.; Lakowicz, J. R. J. Phys. Chem. C 2010, 114, 7492. doi: 10.1021/jp911407c
14. [14]
  (14) Szmacinski, H.; Lakowicz, J. R. Anal. Chem. 2008, 80, 6260.doi: 10.1021/ac8003055
15. [15]
  (15) Zhang, J.; Fu,Y.; Liang, D.; Zhao, R.Y.; Lakowicz, J. R. Anal. Chem. 2009, 81, 883. doi: 10.1021/ac801932m
16. [16]
  (16) Aslan, K.; Geddes, C. D. Anal. Chem. 2009, 81, 6913. doi: 10.1021/ac900973r
17. [17]
  (17) Lakowicz, J. R.; Malicka, J. D.; Auria, S. Anal. Biochem. 2003,320, 13. doi: 10.1016/S0003-2697(03)00351-8
18. [18]
  (18) Gryczynski, Z.; Borejdo, J.; Calander, N. Anal. Biochem. 2006,356, 125.
19. [19]
  (19) Lakowicz, J. R. Anal. Biochem. 2001, 298, 1.
20. [20]
  (20) Nabika, H. S.; Deki, S. Eur. Phys. J. D 2003, 24, 369.
21. [21]
  (21) Nabika, H.; Deki, S. J. Phys. Chem. B 2003, 107, 9161. doi: 10.1021/jp035741b
22. [22]
  (22) Selvan, S. T.; Hayakawa, T.; Nogami, M. J. Phys .Chem. B1999, 103, 7064. doi: 10.1021/jp9902755
23. [23]
  (23) Wang, Y. H.; Zhou, X. R.; Zhou, J. Materials Letters 2008, 62,3582. doi: 10.1016/j.matlet.2008.04.005
24. [24]
  (24) Wang, Y. H.; Zhou, J.;Wang, T. Materials Letters 2008, 62,1937. doi: 10.1016/j.matlet.2007.10.045
25. [25]
  (25) Wang, Y. H.; Zhou, J.;Wang, T. Chin. J. Inorg. Chem. 2008, 24,409. [王悦辉, 周济, 王婷. 无机化学学报, 2008, 24,409.]
26. [26]
  (26) Swarnabala, G.; Rajasekharan, M. V. Inorg. Chem. 1998, 37,1483. doi: 10.1021/ic971261l
27. [27]
  (27) Rexwinkel, S. C.; Meskers, S. C. J.; Dekkers, H. P. J. M.; Riehl,J. P. J. Phys. Chem. 1992, 96, 5725.
28. [28]
  (28) Tang, R. R.; Yan, Z. E.; u, C. C.; Luo,Y. M. Chem. J. Chin. Univ. 2006, 27, 472. [唐瑞仁, 严子耳, 郭灿城, 罗一鸣. 高等学校化学学报, 2006, 27, 472.]
1. [1]
  Lijuan Wang , Yuping Ning , Jian Li , Sha Luo , Xiongfei Luo , Ruiwen Wang . Enhancing the Advanced Nature of Natural Product Chemistry Laboratory Courses with New Research Findings: A Case Study of the Application of Berberine Hydrochloride in Photodynamic Antimicrobial Films. University Chemistry, 2024, 39(11): 241-250. doi: 10.12461/PKU.DXHX202403017
2. [2]
  Peiran ZHAO , Yuqian LIU , Cheng HE , Chunying DUAN . A functionalized Eu³⁺ metal-organic framework for selective fluorescent detection of pyrene. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 713-724. doi: 10.11862/CJIC.20230355
3. [3]
  Liyang ZHANG , Dongdong YANG , Ning LI , Yuanyu YANG , Qi MA . Crystal structures, luminescent properties and Hirshfeld surface analyses of three cadmium(Ⅱ) complexes based on 2-(3-(pyridin-2-yl)-1H-pyrazol-1-yl)benzoate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1943-1952. doi: 10.11862/CJIC.20240079
4. [4]
  Kexin Dong , Chuqi Shen , Ruyu Yan , Yanping Liu , Chunqiang Zhuang , Shijie Li . Integration of Plasmonic Effect and S-Scheme Heterojunction into Ag/Ag₃PO₄/C₃N₅ Photocatalyst for Boosted Photocatalytic Levofloxacin Degradation. Acta Physico-Chimica Sinica, 2024, 40(10): 2310013-. doi: 10.3866/PKU.WHXB202310013
5. [5]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
6. [6]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
7. [7]
  Liang TANG , Jingfei NI , Kang XIAO , Xiangmei LIU . Synthesis and X-ray imaging application of lanthanide-organic complex-based scintillators. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1892-1902. doi: 10.11862/CJIC.20240139
8. [8]
  Yuanpei ZHANG , Jiahong WANG , Jinming HUANG , Zhi HU . Preparation of magnetic mesoporous carbon loaded nano zero-valent iron for removal of Cr(Ⅲ) organic complexes from high-salt wastewater. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1731-1742. doi: 10.11862/CJIC.20240077
9. [9]
  Liang MA , Honghua ZHANG , Weilu ZHENG , Aoqi YOU , Zhiyong OUYANG , Junjiang CAO . Construction of highly ordered ZIF-8/Au nanocomposite structure arrays and application of surface-enhanced Raman spectroscopy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1743-1754. doi: 10.11862/CJIC.20240075
10. [10]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
11. [11]
  Heng Chen , Longhui Nie , Kai Xu , Yiqiong Yang , Caihong Fang . 两步焙烧法制备大比表面积和结晶性增强超薄g-C₃N₄纳米片及其高效光催化产H₂O₂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406019-. doi: 10.3866/PKU.WHXB202406019
12. [12]
  Yingran Liang , Fei Wang , Jiabao Sun , Hongtao Zheng , Zhenli Zhu . Construction and Application of a New Experimental Device for Determination of Alkaline Metal Elements by Plasma Atomic Emission Spectrometry Based on Solution Cathode Glow Discharge: An Alternative Approach for Fundamental Teaching Experiments in Emission Spectroscopy. University Chemistry, 2024, 39(5): 380-387. doi: 10.3866/PKU.DXHX202312024
13. [13]
  Qiuyang LUO , Xiaoning TANG , Shu XIA , Junnan LIU , Xingfu YANG , Jie LEI . Application of a densely hydrophobic copper metal layer in-situ prepared with organic solvents for protecting zinc anodes. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1243-1253. doi: 10.11862/CJIC.20240110
14. [14]
  Yuhao SUN , Qingzhe DONG , Lei ZHAO , Xiaodan JIANG , Hailing GUO , Xianglong MENG , Yongmei GUO . Synthesis and antibacterial properties of silver-loaded sod-based zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 761-770. doi: 10.11862/CJIC.20230169
15. [15]
  Yongming Guo , Jie Li , Chaoyong Liu . Green Improvement and Educational Design in the Synthesis and Characterization of Silver Nanoparticles. University Chemistry, 2024, 39(3): 258-265. doi: 10.3866/PKU.DXHX202309057
16. [16]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
17. [17]
  Juan WANG , Zhongqiu WANG , Qin SHANG , Guohong WANG , Jinmao LI . NiS and Pt as dual co-catalysts for the enhanced photocatalytic H₂ production activity of BaTiO₃ nanofibers. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1719-1730. doi: 10.11862/CJIC.20240102
18. [18]
  Zhuomin Zhang , Hanbing Huang , Liangqiu Lin , Jingsong Liu , Gongke Li . Course Construction of Instrumental Analysis Experiment: Surface-Enhanced Raman Spectroscopy for Rapid Detection of Edible Pigments. University Chemistry, 2024, 39(2): 133-139. doi: 10.3866/PKU.DXHX202308034
19. [19]
  Haiyuan Wang , Yiming Tang , Haoran Guo , Guohui Chen , Yajing Sun , Chao Zhao , Zhen Zhang . Comprehensive Chemistry Experimental Teaching Design Based on the Integration of Science and Education: Preparation and Catalytic Properties of Silver Nanomaterials. University Chemistry, 2024, 39(10): 219-228. doi: 10.12461/PKU.DXHX202404067
20. [20]
  Qin Hou , Jiayi Hou , Aiju Shi , Xingliang Xu , Yuanhong Zhang , Yijing Li , Juying Hou , Yanfang Wang . Preparation of Cuprous Iodide Coordination Polymer and Fluorescent Detection of Nitrite: A Comprehensive Chemical Design Experiment. University Chemistry, 2024, 39(8): 221-229. doi: 10.3866/PKU.DXHX202312056

Get Citation

PDF

XML

Metrics

PDF Downloads(723)
Abstract views(897)
HTML views(22)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142