Citation: LI Ya-Jing, SUN Xiao-Feng, YE Qing, LIU Bai-Chen, WU Yao-Guo. Preparation and Properties of a Novel Hemicellulose-Based Magnetic Hydrogel[J]. Acta Physico-Chimica Sinica, ;2014, 30(1): 111-120. doi: 10.3866/PKU.WHXB201310313 shu

Preparation and Properties of a Novel Hemicellulose-Based Magnetic Hydrogel

1.
Key Laboratory of Space Applied Physics and Chemistry, Ministry of Education, Northwestern Polytechnical University, Xi'an 710129, P. R. China

Received Date: 29 July 2013
Available Online: 31 October 2013
Fund Project: 国家自然科学基金(20707016)，陕西省青年科技新星项目(2012KJXX-10) (20707016)，陕西省青年科技新星项目(2012KJXX-10)西北工业大学研究生种子基金(Z2013154)资助 (Z2013154)

Hydrogels are important functional materials with many potential applications. Anovel hemicellulosebased magnetic hydrogel was synthesized using a graft copolymer method, with H₂O₂-Vc as a redox initiator system to initiate the hemicellulosic derivative and surface-modified Fe₃O₄ particles as the magnetic component. The structures and morphologies of the prepared magnetic hydrogels were investigated using Fourier-transform infrared (FTIR) spectroscopy, X-ray photoelectron spectroscopy (XPS), and scanning electron microscopy (SEM). The crystal structure of the modified Fe₃O₄ particles and the magnetic behaviors of the hemicellulosebased magnetic hydrogels were analyzed using X-ray diffraction (XRD) and a vibration sample magnetometer (VSM), respectively. The results showed that the Fe₃O₄ particles were well dispersed in the hydrogel matrix and the prepared hydrogels had paramagnetic properties. The effects of the acrylic acid/hemicellulose ratio and the amounts of Fe₃O₄ particles and cross-linker on the swelling ratio of the hydrogels were studied, and the swelling mechanism of the hydrogels was explored. The swelling behaviors of the hydrogels were simulated using Fickian and Schott kinetic models in a pH 8 buffer solution. The pore size and swelling ratio of the prepared hydrogels increased with increasing the pH value because the ―COOH groups in the hydrogels were converted to ―COO^- at higher pH values. In addition, the prepared hydrogels were used to adsorb lysozyme; the adsorption capacity of the magnetic hydrogel was much higher than that of a non-magnetic hydrogel, and the equilibrium adsorption data fitted the Freundlich and Temkin isotherm models well.
- Hemicellulose,
- Fe₃O₄,
- Hydrogel,
- Swelling kinetics,
- Lysozyme,
- Adsorption
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