Citation: LI Ya-Jing, SUN Xiao-Feng, YE Qing, LIU Bai-Chen, WU Yao-Guo. Preparation and Properties of a Novel Hemicellulose-Based Magnetic Hydrogel[J]. Acta Physico-Chimica Sinica, ;2014, 30(1): 111-120. doi: 10.3866/PKU.WHXB201310313 shu

Preparation and Properties of a Novel Hemicellulose-Based Magnetic Hydrogel

1.
Key Laboratory of Space Applied Physics and Chemistry, Ministry of Education, Northwestern Polytechnical University, Xi'an 710129, P. R. China

Received Date: 29 July 2013
Available Online: 31 October 2013
Fund Project: 国家自然科学基金(20707016)，陕西省青年科技新星项目(2012KJXX-10) (20707016)，陕西省青年科技新星项目(2012KJXX-10)西北工业大学研究生种子基金(Z2013154)资助 (Z2013154)

Hydrogels are important functional materials with many potential applications. Anovel hemicellulosebased magnetic hydrogel was synthesized using a graft copolymer method, with H₂O₂-Vc as a redox initiator system to initiate the hemicellulosic derivative and surface-modified Fe₃O₄ particles as the magnetic component. The structures and morphologies of the prepared magnetic hydrogels were investigated using Fourier-transform infrared (FTIR) spectroscopy, X-ray photoelectron spectroscopy (XPS), and scanning electron microscopy (SEM). The crystal structure of the modified Fe₃O₄ particles and the magnetic behaviors of the hemicellulosebased magnetic hydrogels were analyzed using X-ray diffraction (XRD) and a vibration sample magnetometer (VSM), respectively. The results showed that the Fe₃O₄ particles were well dispersed in the hydrogel matrix and the prepared hydrogels had paramagnetic properties. The effects of the acrylic acid/hemicellulose ratio and the amounts of Fe₃O₄ particles and cross-linker on the swelling ratio of the hydrogels were studied, and the swelling mechanism of the hydrogels was explored. The swelling behaviors of the hydrogels were simulated using Fickian and Schott kinetic models in a pH 8 buffer solution. The pore size and swelling ratio of the prepared hydrogels increased with increasing the pH value because the ―COOH groups in the hydrogels were converted to ―COO^- at higher pH values. In addition, the prepared hydrogels were used to adsorb lysozyme; the adsorption capacity of the magnetic hydrogel was much higher than that of a non-magnetic hydrogel, and the equilibrium adsorption data fitted the Freundlich and Temkin isotherm models well.
- Hemicellulose,
- Fe₃O₄,
- Hydrogel,
- Swelling kinetics,
- Lysozyme,
- Adsorption
1. [1]
  
  (1) Suzuki, D.; Yamakawa, S. Langmuir 2012, 28 (29), 10629.
2. [2]
  (2) Shang, J.; Shao, Z.; Chen, X. Biomacromolecules 2008, 9 (4),1208.
3. [3]
  (3) Xiang, M.; He, C. C.;Wang, H. L. Acta Phys. -Chim. Sin. 2011,27 (5), 1267. [相梅, 贺昌城, 汪辉亮. 物理化学学报, 2011,27 (5), 1267.] doi: 10.3866/PKU.WHXB20110429
4. [4]
  (4) Jin, S. P.; Liu, M. Z.; Chen, S. L.; Bian, F. L.; Chen, Y.;Wang,B.; Zhan, F. L.; Liu, S. X. Acta Phys. -Chim. Sin. 2007, 23 (3),438. [金淑萍, 柳明珠, 陈世兰, 卞凤玲, 陈勇, 王斌, 詹发禄, 刘守信. 物理化学学报, 2007, 23 (3), 438.] doi: 10.3866/PKU.WHXB20070330
5. [5]
  (5) Cho, E. C.; Kim, J.W.; Fernandez-Nieves, A.;Weitz, D. A.Nano Letters 2007, 8 (1), 168.
6. [6]
  (6) Ozay, O.; Ekici, S.; Baran, Y.; Kubilay, S.; Aktas, N.; Sahiner,N. Desalination 2010, 260 (1-3), 57.
7. [7]
  (7) Zhai, D.; Liu, B.; Shi, Y.; Pan, L.;Wang, Y.; Li,W.; Zhang, R.;Yu, G. ACS Nano 2013, 7 (4), 3540.
8. [8]
  (8) Ramanujan, R. V.; Lao, L. L. Smart Materials and Structures2006, 15 (4), 952. doi: 10.1088/0964-1726/15/4/008
9. [9]
  (9) Yang, J. Y.; Zhou, X. S.; Fang, J. Carbohydrate Polymers 2011,86 (3), 1113. doi: 10.1016/j.carbpol.2011.05.043
10. [10]
  (10) Kim, J. K.; Kim, K. I.; Basavaraja, C.; Rabai, G.; Huh, D. S.J. Phys. Chem. B 2013, 117 (20), 6294.
11. [11]
  (11) Peng, C. L.; Shih, Y. H.; Liang, K. S.; Chiang, P. F.; Yeh, C. H.;Tang, I. C.; Yao, C. J.; Lee, S. Y.; Luo, T. Y.; Shieh, M. J. Mol. Pharmaceutics 2013, 10 (5), 1854. doi: 10.1021/mp3006424
12. [12]
  (12) Sivakumaran, D.; Maitland, D.; Hoare, T. Biomacromolecules2011, 12 (11), 4112. doi: 10.1021/bm201170h
13. [13]
  (13) Ding, Z.; Salim, A.; Ziaie, B. Anal. Chem. 2010, 82 (8), 3377.doi: 10.1021/ac100579v
14. [14]
  (14) Pronyk, C.; Mazza, G. Ind. Eng. Chem. Res. 2010, 49 (14),6367. doi: 10.1021/ie1003625
15. [15]
  (15) Lindblad, M. S.; Albertsson, A. C.; Ranucci, E.; Laus, M.;Giani, E. Biomacromolecules 2005, 6 (2), 684. doi: 10.1021/bm049515z
16. [16]
  (16) Sun, X. F.;Wang, H. H.; Jing, Z. X.; Mohanathas, R. Carbohyd. Polym. 2013, 92 (2), 1357. doi: 10.1016/j.carbpol.2012.10.032
17. [17]
  (17) Park, J. H.; Bae, Y. H. Biomaterials 2002, 23 (8), 1797. doi: 10.1016/S0142-9612(01)00306-4
18. [18]
  (18) Zhang, J. H. Journal of Henan Normal University (Natural Science) 2004, 32 (3), 57. [张建合. 河南师范大学学报(自然科学版) 2004, 32 (3), 57.]
19. [19]
  (19) Liu, T. Y.; Hu, S. H.; Liu, K. H.; Liu, D. M.; Chen, C. Y. Journal of Magnetism and Magnetic Materials 2006, 304 (1), 397.
20. [20]
  (20) Li, X. M.; Zhang, J. H.; Cui, Y. D.; Liao, L.W.; Jia, Z. Y.; Yin,G. Q.; Guo, P. Journal of Xinyang Normal University (Natural Science) 2007, 20 (2), 174. [黎新明, 张建合, 崔英德, 廖列文, 贾振宇, 尹国强, 郭鹏. 信阳师范学院学报(自然科学版)2007, 20 (2), 174.]
21. [21]
  (21) Sun, X. F.; Sun, R.; Fowler, P.; Baird, M. S. J. Agr. Food Chem.2005, 53 (4), 860. doi: 10.1021/jf040456q
22. [22]
  (22) Sun, X. F.; Sun, R.; Tomkinson, J.; Baird, M. S. Carbohyd. Polym. 2003, 53, 485.
23. [23]
  (23) Ren, J. L.; Sun, R. C.; Liu, C. F.; Cao, Z. N.; Luo,W. Carbohyd. Polym. 2007, 70 (4), 406. doi: 10.1016/j.carbpol.2007.04.022
24. [24]
  (24) Sun, R. C.; Fang, J. M.; Tomkinson, J. Carbohyd. Polym. 2001,44 (1), 29. doi: 10.1016/S0144-8617(00)00196-X
25. [25]
  (25) Xuan, S. H.;Wang, Y. X.; Yu, J. C. Chemistry of Materials2009, 21 (21), 5079. doi: 10.1021/cm901618m
26. [26]
  (26) Takami, S.; Sato, T.; Mousavand, T.; Ohara, S. Materials Letters2007, 61 (26), 4769. doi: 10.1016/j.matlet.2007.03.024
27. [27]
  (27) Sun, X. F.; Li, Y. J. Functional Modification and Preparation ofSuperparamagnetic Fe3O4. In Buiding Materials and Structural Engineering II, Proceedings of the International Conference,Beijing, May 25-26, 2013; Xu, B., Li H. Y., Eds.; AdvancedMaterials Research: Beijing, 2013.
28. [28]
  (28) Frickel, N.; Messing, R.; Gelbrich, T.; Schmidt, A. M. Langmuir2009, 26 (4), 2839.
29. [29]
  (29) Perez de Vargas-Sansalvador, I. M.; Canfarotta, F.; Piletsky, S.A. Synthesis of Monodisperse Polymeric Nano- andMicroparticles and Their Application in Bioanalysis, InBioanalytical Reviews; Springer: Heidelberg, 2013; pp 1-24.doi: 10.1007/11663_2013_4
30. [30]
  (30) Li, Y.; Leng, T.; Lin, H.; Deng, C.; Xu, X.; Yao, N.; Yang, P.;Zhang, X. J. Proteome. Res. 2007, 6 (11), 4498. doi: 10.1021/pr070167s
31. [31]
  (31) Wang, Z.;Wu, L.; Zhou, J.; Shen, B.; Jiang, Z. RSC Adv. 2013, 3 (10), 3309. doi: 10.1039/c2ra23404a
32. [32]
  (32) Wang, Y. P.; Yuan, K.; Pei, X.W. Acta Poly. Sin. 2005, No. 4,584. [王云普, 袁昆, 裴小维. 高分子学报, 2005, No. 4,584.]
33. [33]
  (33) Ye, Q.; Sun, X. F.; Jing, Z. X.;Wang, G. Z.; Li, Y. J. Modern Chemical Industry 2012, 32 (5), 62. [叶青, 孙晓锋, 景占鑫, 王广征, 李亚婧. 现代化工, 2012, 32 (5), 62.]
34. [34]
  (34) Chen, Y. F.; Yi, M. Radiat. Phys. Chem. 2001, 61 (1), 65. doi: 10.1016/S0969-806X(00)00374-1
35. [35]
  (35) Dalaran, M.; Emik, S.; Guclu, G.; Iyim, T. B.; Ozgumus, S.Desalination 2011, 279 (1-3), 170. doi: 10.1016/j.desal.2011.06.004
36. [36]
  (36) Katime, I.; Novoa, R.; Zuluaga, F. Eur. Polym. J. 2001, 37 (7),1465. doi: 10.1016/S0014-3057(01)00004-0
37. [37]
  (37) Quintana, J. R.; Valderruten, N. E.; Katime, I. Langmuir 1999,15 (14), 4728. doi: 10.1021/la980982+
38. [38]
  (38) Bayram lu, G.; Y?lmaz, M.; Ar?ca, M. Y. Biochem. Eng. J.2003, 13 (1), 35. doi: 10.1016/S1369-703X(02)00098-0
39. [39]
  (39) Vijayaraghavan, K.; Padmesh, T. V. N.; Palanivelu, K.; Velan,M. J. Hazard. Mater. 2006, 133 (1-3), 304. doi: 10.1016/j.jhazmat.2005.10.016
40. [40]
  (40) Johnson, R. D.; Arnold, F. H. Biochimica et Biophysica Acta- Protein Structure and Molecular Enzymology 1995, 1247 (2),293. doi: 10.1016/0167-4838(95)00006-G
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