Citation: LI Ling-Liang, ZHANG Fu-Jun, WANG Zi-Xuan, AN Qiao-Shi, WANG Jian, XU Zheng. Organic Visible-Blind Ultraviolet Photodetectors Based on Rare Earth Complex[J]. Acta Physico-Chimica Sinica, ;2013, 29(12): 2624-2629. doi: 10.3866/PKU.WHXB201310301 shu

Organic Visible-Blind Ultraviolet Photodetectors Based on Rare Earth Complex

1.
Key Laboratory of Luminescence and Optical Information, Ministry of Education, Beijing Jiaotong University, Beijing 100044, P. R. China

Received Date: 29 July 2013
Available Online: 30 October 2013
Fund Project: 高等学校基本科研业务基金(2013JBZ004) (2013JBZ004) 北京市自然科学基金(2122050) (2122050)国家自然科学基金(613770029)资助项目 (613770029)

Anew type of organic visible-blind ultraviolet (UV) photodetector based on tri(dibenzoylmethane)(4, 7-biphenyl-1,10-phenanthroline)europium (Ⅲ) [Eu(DBM)₃BPhen] as an electron donor and [6,6]-phenyl-C-61-butyric acid methyl ester ([60]PCBM) as an electron acceptor was fabricated. A peak response of 26 mA·W^-1 and external quantum efficiency of 9.1% were obtained under illumination with 360 nm UV light at 2.1 mW·cm^-2. This was because of the high UV absorption of Eu(DBM)₃BPhen and the long lifetime, 300 μs, of Eu³⁺ ions, resulting in high exciton dissociation efficiency. Distinct photoluminescence quenching and photoconductivity of Eu(DBM)₃BPhen were obtained by doping with [60]PCBM. A strong persistent photoconductivity was observed, which could be attributed to low charge carrier transportation and slow release of trapped exciton states in the blend films after the UV light is turned off.
- Organic visible-blind,
- Ultraviolet photodetector,
- Persistent photoconductivity
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沈阳化工大学材料科学与工程学院沈阳 110142