Citation: LI Ling-Liang, ZHANG Fu-Jun, WANG Zi-Xuan, AN Qiao-Shi, WANG Jian, XU Zheng. Organic Visible-Blind Ultraviolet Photodetectors Based on Rare Earth Complex[J]. Acta Physico-Chimica Sinica, ;2013, 29(12): 2624-2629. doi: 10.3866/PKU.WHXB201310301 shu

Organic Visible-Blind Ultraviolet Photodetectors Based on Rare Earth Complex

1.
Key Laboratory of Luminescence and Optical Information, Ministry of Education, Beijing Jiaotong University, Beijing 100044, P. R. China

Received Date: 29 July 2013
Available Online: 30 October 2013
Fund Project: 高等学校基本科研业务基金(2013JBZ004) (2013JBZ004) 北京市自然科学基金(2122050) (2122050)国家自然科学基金(613770029)资助项目 (613770029)

Anew type of organic visible-blind ultraviolet (UV) photodetector based on tri(dibenzoylmethane)(4, 7-biphenyl-1,10-phenanthroline)europium (Ⅲ) [Eu(DBM)₃BPhen] as an electron donor and [6,6]-phenyl-C-61-butyric acid methyl ester ([60]PCBM) as an electron acceptor was fabricated. A peak response of 26 mA·W^-1 and external quantum efficiency of 9.1% were obtained under illumination with 360 nm UV light at 2.1 mW·cm^-2. This was because of the high UV absorption of Eu(DBM)₃BPhen and the long lifetime, 300 μs, of Eu³⁺ ions, resulting in high exciton dissociation efficiency. Distinct photoluminescence quenching and photoconductivity of Eu(DBM)₃BPhen were obtained by doping with [60]PCBM. A strong persistent photoconductivity was observed, which could be attributed to low charge carrier transportation and slow release of trapped exciton states in the blend films after the UV light is turned off.
- Organic visible-blind,
- Ultraviolet photodetector,
- Persistent photoconductivity
1. [1]
  
  (1) Forrest, S. R. Nature 2004, 428, 911. doi: 10.1038/nature02498
2. [2]
  (2) ng, X. O.; Tong, M. H.; Park, S. H.; Liu, M.; Jen, A.; Heeger,A. J. Sensors 2010, 10, 6488. doi: 10.3390/s100706488
3. [3]
  (3) Wu, S. H.; Li,W. L.; Chu, B.; Lee, C. S.; Su, Z. S.;Wang, J. B.;Ren, Q. J.; Hu, Z. Z.; Zhang, Z. Q. Appl. Phys. Lett. 2010, 97,023306. doi: 10.1063/1.3463483
4. [4]
  (4) Zhu, L.; Dai, Q.; Hu, Z. F.; Zhang, X. Q.;Wang, Y. S. Opt. Lett.2011, 36, 1821. doi: 10.1364/OL.36.001821
5. [5]
  (5) Zhu, L.;Wang,W. S.; Yao, Z. G.; Zhang, X. Q.;Wang, Y. S.IEEE Trans. Electron Devices 2012, 59, 3583. doi: 10.1109/TED.2012.2219864
6. [6]
  (6) Zhang, J. L.; Nan, Y. X.; Li, H. G.; Qiu,W. M.; Yang, X.;Wu,G.; Chen, H. Z.;Wang, M. Sensors and Actuators B: Chemical2012, 162, 321. doi: 10.1016/j.snb.2011.12.088
7. [7]
  (7) Kalyani, N. T.; Dhoble, S. J. Renewable & Sustainable Energy Reviews 2012, 16, 2696. doi: 10.1016/j.rser.2012.02.021
8. [8]
  (8) Canzler, T.W.; Kido, J. Org. Electron 2006, 7, 29. doi: 10.1016/j.orgel.2005.10.004
9. [9]
  (9) Zhang, F. J.; Zhuo, Z. L.; Zhang, J.;Wang, X.; Xu, X.W.;Wang, Z. X.; Xin, Y. S.;Wang, J.;Wang, J.; Tang,W. H.; Xu, Z.;Wang, Y. S. Solar Energy Materials and Solar Cells 2012, 97,71. doi: 10.1016/j.solmat.2011.09.006
10. [10]
  (10) Zhang, F. J.; Xu, X.W.; Tang,W. H.; Zhang, J.; Zhuo, Z. L.;Wang, J.;Wang, J.; Xu, Z.;Wang, Y. S. Solar Energy Materials and Solar Cells 2011, 95, 1785. doi: 10.1016/j.solmat.2011.02.002
11. [11]
  (11) Zhuo, Z. L.; Zhang, F. J.; Lv, Y. G.; Xu, Z.; Lu, L. F.; Li, J. M.;Wang, Y. S. Phys. Scr. 2010, 82, 055703. doi: 10.1088/0031-8949/82/05/055703
12. [12]
  (12) Li, B.; Ma, D. G.; Zhang, H. J.; Zhao, X. J.; Ni, J. Z. Acta Phys. -Chim. Sin. 1998, 14, 305. [李斌, 马东阁, 张洪杰,赵晓江, 倪嘉缵. 物理化学学报, 1998, 14, 305.] doi: 10.3866/PKU.WHXB19980404
13. [13]
  (13) Huang, L.; Cheng, L.; Yu, H.; Zhou, L.; Sun, J.; Zhong, H.; Li,X.; Zhang, J.; Tian, Y.; Zheng, Y.; Yu, T.;Wang, J.; Chen, B.Physica B: Condensed Matter 2011, 406, 2745. doi: 10.1016/j.physb.2011.04.019
14. [14]
  (14) Huang, L.; Cheng, L.; Yu, H.; Zhang, J.; Zhou, L.; Sun, J.;Zhong, H.; Li, X.; Tian, Y.; Zheng, Y.; Yu, T.; Li, C.; Zhong, H.;Liu,W.; Zhang, L.;Wang, J.; Chen, B. Opt. Commun. 2012,285, 1476. doi: 10.1016/j.optcom.2011.10.006
15. [15]
  (15) Zhuo, Z. L.; Zhang, F. J.; Xu, X.W.;Wang, J.; Lu, L. F.; Xu, Z.Acta Phys. -Chim. Sin. 2011, 27, 875. [卓祖亮, 张福俊, 许晓伟, 王健, 卢丽芳, 徐征. 物理化学学报, 2011, 27, 875.]doi: 10.3866/PKU.WHXB20110414
16. [16]
  (16) Kajii, H.; Katsura, A.; Ohmori, H.; Sato, Y.; Hamasaki, T.;Ohmori, Y. J. Non-Cryst. Solids 2012, 358, 2504. doi: 10.1016/j.jnoncrysol.2011.12.097
17. [17]
  (17) Li, Y. F. Accounts of Chemical Research 2012, 45, 723. doi: 10.1021/ar2002446
18. [18]
  (18) Cai, S.; Parish, G.; Dell, J. M.; Nener, B. D. J. Appl. Phys. 2004,96, 1019.
19. [19]
  (19) Verbakel, F.; Meskers, S. C. J.; Janssen, R. A. J. Appl. Phys. Lett. 2006, 89, 102103. doi: 10.1063/1.2345612
20. [20]
  (20) Reyes, P. I.; Ku, C. J.; Duan, Z. Q.; Xu, Y.; Garfunkel, E.; Lu, Y.C. Appl. Phys. Lett. 2012, 101, 031118. doi: 10.1063/1.4737648
21. [21]
  (21) Dasgupta, S.; Knaak, C.; Moser, J.; Bichler, M.; Roth, S. F.;Morral, A. F. I.; Abstreiter, G.; Grayson, M. Appl. Phys. Lett.2007, 91, 142120. doi: 10.1063/1.2794012
22. [22]
  (22) Hirsch, M. L. T.;Wolk, J. A.;Walukiewicz,W.; Haller, E. E.Appl. Phys. Lett. 1997, 71, 1098. doi: 10.1063/1.119738
23. [23]
  (23) Kim, C. H.; Kisiel, K.; Jung, J.; Ulanski, J.; Tondelier, D.;Geffroy, B.; Bonnassieux, Y.; Horowitz, G. Synth. Met. 2012,162, 460. doi: 10.1016/j.synthmet.2011.12.021
24. [24]
  (24) Nardes, A. M.; Ferguson, A. J.; Whitaker, J. B.; Larson, B.W.;Larsen, R. E.; Maturová, K.; Graf, P. A.; Boltalina, O. V.;Strauss, S. H.; Kopidakis, N. Adv. Funct. Mater. 2012, 22,4115. doi: 10.1002/adfm.v22.19
25. [25]
  (25) Kim, C. H.; Choi, M. H.; Lee, S. H.; Jang, J.; Kirchmeyer, S.Appl. Phys. Lett. 2010, 96, 123301. doi: 10.1063/1.3372619
26. [26]
  (26) Li, L.; Zhang, F.; An, Q.;Wang, Z.;Wang, J.; Tang, A.; Peng,H.; Xu, Z.;Wang, Y. Opt. Lett. 2013, 38, 3823. doi: 10.1364/OL.38.003823
1. [1]
  Yuhang Zhang , Weiwei Zhao , Hongwei Liu , Junpeng Lü . 基于低维材料的自供电光电探测器研究进展. Acta Physico-Chimica Sinica, 2025, 41(3): 2310004-. doi: 10.3866/PKU.WHXB202310004
2. [2]
  Yao Ma , Xin Zhao , Hongxu Chen , Wei Wei , Liang Shen . Progress and Perspective of Perovskite Thin Single Crystal Photodetectors. Acta Physico-Chimica Sinica, 2025, 41(4): 100030-. doi: 10.3866/PKU.WHXB202309045
3. [3]
  Xingchao Zhao , Xiaoming Li , Ming Liu , Zijin Zhao , Kaixuan Yang , Pengtian Liu , Haolan Zhang , Jintai Li , Xiaoling Ma , Qi Yao , Yanming Sun , Fujun Zhang . 倍增型全聚合物光电探测器及其在光电容积描记传感器上的应用. Acta Physico-Chimica Sinica, 2025, 41(1): 2311021-. doi: 10.3866/PKU.WHXB202311021
4. [4]
  .
  CCS Chemistry 综述推荐│绿色氧化新思路：光/电催化助力有机物高效升级
  . CCS Chemistry, 2025, 7(10.31635/ccschem.024.202405369): -.
5. [5]
  Wenxiu Yang , Jinfeng Zhang , Quanlong Xu , Yun Yang , Lijie Zhang . Bimetallic AuCu Alloy Decorated Covalent Organic Frameworks for Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312014-. doi: 10.3866/PKU.WHXB202312014
6. [6]
  Aiai WANG , Lu ZHAO , Yunfeng BAI , Feng FENG . Research progress of bimetallic organic framework in tumor diagnosis and treatment. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1825-1839. doi: 10.11862/CJIC.20240225
7. [7]
  Feng Sha , Xinyan Wu , Ping Hu , Wenqing Zhang , Xiaoyang Luan , Yunfei Ma . Design of Course Ideology and Politics for the Comprehensive Organic Synthesis Experiment of Benzocaine. University Chemistry, 2024, 39(2): 110-115. doi: 10.3866/PKU.DXHX202307082
8. [8]
  Xinyu Zhu , Meili Pang . Application of Functional Group Addition Strategy in Organic Synthesis. University Chemistry, 2024, 39(3): 218-230. doi: 10.3866/PKU.DXHX202308106
9. [9]
  Tianyun Chen , Ruilin Xiao , Xinsheng Gu , Yunyi Shao , Qiujun Lu . Synthesis, Crystal Structure, and Mechanoluminescence Properties of Lanthanide-Based Organometallic Complexes. University Chemistry, 2024, 39(5): 363-370. doi: 10.3866/PKU.DXHX202312017
10. [10]
  Shicheng Yan . Experimental Teaching Design for the Integration of Scientific Research and Teaching: A Case Study on Organic Electrooxidation. University Chemistry, 2024, 39(11): 350-358. doi: 10.12461/PKU.DXHX202408036
11. [11]
  Yong Wang , Yingying Zhao , Boshun Wan . Analysis of Organic Questions in the 37th Chinese Chemistry Olympiad (Preliminary). University Chemistry, 2024, 39(11): 406-416. doi: 10.12461/PKU.DXHX202403009
12. [12]
  Ran HUO , Zhaohui ZHANG , Xi SU , Long CHEN . Research progress on multivariate two dimensional conjugated metal organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2063-2074. doi: 10.11862/CJIC.20240195
13. [13]
  Bin HE , Hao ZHANG , Lin XU , Yanghe LIU , Feifan LANG , Jiandong PANG . Recent progress in multicomponent zirconium?based metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2041-2062. doi: 10.11862/CJIC.20240161
14. [14]
  Xiaofang DONG , Yue YANG , Shen WANG , Xiaofang HAO , Yuxia WANG , Peng CHENG . Research progress of conductive metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 14-34. doi: 10.11862/CJIC.20240388
15. [15]
  Meiqing Yang , Lu Wang , Haozi Lu , Yaocheng Yang , Song Liu . Recent Advances of Functional Nanomaterials for Screen-Printed Photoelectrochemical Biosensors. Acta Physico-Chimica Sinica, 2025, 41(2): 100018-. doi: 10.3866/PKU.WHXB202310046
16. [16]
  Peiran ZHAO , Yuqian LIU , Cheng HE , Chunying DUAN . A functionalized Eu³⁺ metal-organic framework for selective fluorescent detection of pyrene. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 713-724. doi: 10.11862/CJIC.20230355
17. [17]
  Tiantian MA , Sumei LI , Chengyu ZHANG , Lu XU , Yiyan BAI , Yunlong FU , Wenjuan JI , Haiying YANG . Methyl-functionalized Cd-based metal-organic framework for highly sensitive electrochemical sensing of dopamine. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 725-735. doi: 10.11862/CJIC.20230351
18. [18]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
19. [19]
  Wendian XIE , Yuehua LONG , Jianyang XIE , Liqun XING , Shixiong SHE , Yan YANG , Zhihao HUANG . Preparation and ion separation performance of oligoether chains enriched covalent organic framework membrane. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1528-1536. doi: 10.11862/CJIC.20240050
20. [20]
  Liang TANG , Jingfei NI , Kang XIAO , Xiangmei LIU . Synthesis and X-ray imaging application of lanthanide-organic complex-based scintillators. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1892-1902. doi: 10.11862/CJIC.20240139

Get Citation

PDF

XML

Metrics

PDF Downloads(645)
Abstract views(837)
HTML views(25)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142