Citation: HUO Sheng-Juan, CHEN Li-Hong, ZHU Qing, FANG Jian-Hui. Surface-Enhanced Infrared Absorption Spectroscopy Study of Anticorrosion Behavior of 2-Mercaptobenzothiazole on Copper[J]. Acta Physico-Chimica Sinica, ;2013, 29(12): 2565-2572. doi: 10.3866/PKU.WHXB201310294 shu

Surface-Enhanced Infrared Absorption Spectroscopy Study of Anticorrosion Behavior of 2-Mercaptobenzothiazole on Copper

1.
Department of Chemistry, College of Sciences, Shanghai University, Shanghai 200444, P. R. China

Received Date: 26 August 2013
Available Online: 29 October 2013
Fund Project: 国家自然科学基金(21103105) (21103105)

2-Mercaptobenzothiazole (MBT) is a highly efficient inhibitor of Cu. However, the inhibition mechanism is still unclear. In this paper, the anticorrosive effect of MBT on a Cu surface at the macroscopic level was evaluated using a polarization curve technique. The potential-dependent adsorption geometries of MBT at the molecular level were investigated using electrochemical surface-enhanced infrared reflection absorption spectroscopy in attenuated total reflection mode, together with theoretical calculations. The results indicated that the MBT molecules were adsorbed on the Cu surface vertically, in a thiolate form, through exocyclic S atoms at a potential negative of 0 V (vs saturated calomel electrode (SCE)). At a potential positive of 0 V (vs SCE), electrons were transferred between MBT and the Cu substrate, meaning that MBT molecules can interact with the Cu surface via exocyclic S and endocyclic N atoms to form a polymer film, resulting in the formation of a compact protecting layer to prevent Cu dissolution.
- Surface-enhanced infrared absorption spectroscopy,
- Attenuated total reflection (ATR) mode,
- 2-Mercaptobenzothiazole,
- Copper,
- Inhibition mechanism
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沈阳化工大学材料科学与工程学院沈阳 110142