Citation: ZHAO Xue-Ting, DONG Yong-Chun, CHENG Bo-Wen, KANG Wei-Min. Coordination Kinetics of Fe³⁺ with Membranes Based on Modified PAN Nanofibers with Different Diameters, and Catalytic Effect of Their Complexes on Decomposition of Organic Dye[J]. Acta Physico-Chimica Sinica, ;2013, 29(12): 2513-2522. doi: 10.3866/PKU.WHXB201310233 shu

Coordination Kinetics of Fe³⁺ with Membranes Based on Modified PAN Nanofibers with Different Diameters, and Catalytic Effect of Their Complexes on Decomposition of Organic Dye

1.
1 Division of Textile Chemistry & Ecology, School of Textiles, Tianjin Polytechnic University, Tianjin 300387, P. R. China;
2 Key Laboratory of Advanced Textile Composites, Ministry of Education, Tianjin Polytechnic University, Tianjin 300387, P. R. China

Received Date: 12 August 2013
Available Online: 23 October 2013
Fund Project: 天津市应用基础与前沿技术重点研究计划(11JCZDJC24600, 11ZCKFGX03200) (11JCZDJC24600, 11ZCKFGX03200)国家自然科学基金(2020773093, 51102178)资助项目 (2020773093, 51102178)

Membranes produced from modified polyacrylonitrile (PAN) nanofibers with different diameters were prepared by electrospinning and amidoximation. They were then used as ligands to coordinate with Fe³⁺ for preparing modified PAN nano-fibrous membrane Fe complexes. The coordination kinetics of three modified PAN nano-fibrous membranes with Fe³⁺ were studied, and the effects of temperature and the Fe³⁺ initial concentration on the coordination kinetics were also examined. Finally, the catalytic activities of the three modified PAN nano- fibrous membrane Fe complexes were evaluated as heterogeneous Fenton catalysts in the degradation of an organic dye. The effect of fiber diameter on the catalytic activity of the complexes was investigated. The results indicated that within the observed temperature and concentration ranges, the equilibrium data for the coordination of Fe³⁺ with the modified PAN nano-fibrous membranes correlated with the Langmuir and Freundlich isotherm equations, but the coordination kinetics showed better agreement with the Lagergren second-order equation. Modified PAN nanofibrous membranes with small diameters showed higher Fe- coordinating capacities and reaction rate constants under the same conditions, indicating that they reacted with Fe³⁺ more easily than the others did. Better catalytic activities for dye degradation were found for the three modified PAN nanofibrous membrane Fe complexes in the dark, and these were further improved by light irradiation. The catalytic activities of the complexes were significantly affected by the nanofiber diameter. The complex prepared using a modified PAN nanofibrous membrane with fibers of an appropriate diameter exhibited the best catalytic activity.
- PAN nano-fibrous membrane,
- Fe³⁺,
- Coordination kinetics,
- Photocatalysis,
- Fenton reaction,
- Dye degradation
1. [1]
  
  (1) Janiak, C. Chem. Soc. Dalton Trans. 2003, 14 (6), 2781.
2. [2]
  (2) Vassilev, K.; Turmanova, S. Polym. Bull. 2008, 60 (2), 243.
3. [3]
  (3) Wu, S. H.; Xie, Q. X.; Zhu, C. Y.; Huang,W. P.; Yang, X. L.;Wu,W. Y. Polym. Mater. Sci. Eng. 2000, 16 (3), 1. [吴世华,解勤兴, 朱常英, 黄唯平, 杨秀檩, 吴文艳. 高分子材料科学与工程, 2000, 16 (3), 1.]
4. [4]
  (4) Espenson, J. H. Chemical Kinetics and Reaction Mechanisms,2nd ed.; McGraw-Hill Inc: New York, 1995; pp 1-3.
5. [5]
  (5) Xu, Y. Chemical Reaction Kinetics; Chemical Industry Press:Beijing, 2005; pp 151-153. [许越. 化学反应动力学. 北京:化学工业出版社, 2005: 151-153.]
6. [6]
  (6) Zhang, D. Y.;Wu, Z. C.; Zhou, K.; Chen, P. G. Polym. Mater. Sci. Eng. 2008, 24 (6), 38. [张宇东, 吴之传, 周凯, 陈培根.高分子材料科学与工程, 2008, 24 (6), 38.]
7. [7]
  (7) Dong, Y. C.;Wu, J. N.; Sun, S. T.; Zheng, X.; Han, Z. B.; Liu,C. Y. Journal of Sichuan University (Engineering Science Edition) 2011, 43 (1), 173. [董永春, 武金娜, 孙苏婷, 郑戌,韩振邦, 刘春燕. 四川大学学报(工程科学版), 2011, 43 (1),173.]
8. [8]
  (8) Han, Z. B.; Dong, Y. C.; Liu, C. Y. Chem. J. Chin. Univ. 2010,31 (5), 986. [韩振邦, 董永春, 刘春燕. 高等学校化学学报,2010, 31 (5), 986.]
9. [9]
  (9) Bagheri, B.; Abdouss, M.; Aslzadeh, M. M.; Shoushtari, A. M.Iran. Polym. J. 2010, 19 (12), 911.
10. [10]
  (10) Feng, Q.;Wang, Q. Q.; Tang, B.;Wei, A. F.;Wang, X. Q.;Wei,Q. F.; Huang, F. L.; Cai, Y. B.; Hou, D. Y.; Bi, S. M. Polym. Int.2013, 62 (2), 251. doi: 10.1002/pi.2013.62.issue-2
11. [11]
  (11) Kampalanonwat, P.; Supaphol, P. ACS Appl. Mater. Inter. 2010,2 (2), 3619.
12. [12]
  (12) Ishtchenko, V. V.; Huddersman, K. D.; Vitkovskaya, R. F. Appl. Catal. A. 2003, 242 (1), 123. doi: 10.1016/S0926-860X(02)00511-2
13. [13]
  (13) Ishtchenko, V. V.; Huddersman, K. D.; Vitkovskaya, R. F. Appl. Catal. A 2003, 242 (2), 221. doi: 10.1016/S0926-860X(02)00512-4
14. [14]
  (14) Vitkovskaya, R. F.; Rumynskaya, I. G.; Romanova, E. P.;Tereshchenko, L. Y. Fiber Chem. 2003, 35 (3), 202. doi: 10.1023/A:1026109923284
15. [15]
  (15) Dong, Y. C.; Du, F.; Han, Z. B. Acta Phys. -Chim. Sin. 2008, 24 (11), 2114. [董永春, 杜芳, 韩振邦. 物理化学学报, 2008,24 (11), 2114.] doi: 10.3866/PKU.WHXB20081130
16. [16]
  (16) Dong, Y. C.; Han, Z. B.; Liu, C. Y.; Du, F. Sci. Total. Environ.2010, 408 (10), 2245. doi: 10.1016/j.scitotenv.2010.01.020
17. [17]
  (17) Han, Z. B.; Dong, Y. C.; Dong, S. M. J. Hazard. Mater. 2011,189 (1-2), 241. doi: 10.1016/j.jhazmat.2011.02.026
18. [18]
  (18) Dong, Y. C.; Dong,W. J.; Han, Z. B. Catal. Today 2011, 175 (1),299. doi: 10.1016/j.cattod.2011.04.026
19. [19]
  (19) Yang, X.W.; Luo, Y. Y. Textbook of Chemical Products: Dyestuffs; Chemical Industry Press: Beijing, 2005; pp 156-541.[杨新玮, 罗钰言. 化工产品手册: 染料. 北京: 化学工业出版社, 2005: 156-541.]
20. [20]
  (20) Li, S. F.; Chen, J. P.;Wu,W. T. J. Mol. Catal. B 2007, 47 (3-4),117. doi: 10.1016/j.molcatb.2007.04.010
21. [21]
  (21) Feng, Q.;Wang, X. Q.;Wei, Q. F.; Hou, D. Y.;Wei, L.; Liu, X.H.;Wang, Z. Q. Fiber. Polym. 2011, 12 (8), 1025. doi: 10.1007/s12221-011-1025-0
22. [22]
  (22) Neghlani, P. K.; Rafizadeh, M.; Taromi, F. A. J. Hazard. Mater.2011, 186 (1), 182. doi: 10.1016/j.jhazmat.2010.10.121
23. [23]
  (23) Lee, K. H.; Kim, H. Y.; Khil, M. S.; Ra, Y. M.; Lee, D. R.Polym. 2003, 44 (4), 1287. doi: 10.1016/S0032-3861(02)00820-0
24. [24]
  (24) Vassilev, K.; Turmanova, S. Polym. Bull. 2005, 1 (5), 575.
25. [25]
  (25) Qin, X. H.;Wang, X.W.; Hu, Z. M.; Liu, Z. F.;Wang, S. Y.Journal of Donghua University (Natural Science) 2005, 31 (6),16. [覃小红, 王新威, 胡祖明, 刘兆峰, 王善元. 东华大学学报(自然科学版), 2005, 31 (6), 16.]
26. [26]
  (26) Yordem, O. S.; Papila, M.; Menceloglu, Y. Z. Mater. Des. 2008,29 (1), 34. doi: 10.1016/j.matdes.2006.12.013
27. [27]
  (27) Wang, N.; Burugapalli, K.; Song,W.; Hall, J.; Moussy, F.;Zheng, Y. D.; Ma, Y. X.;Wu, Z. T.; Li, K. J. Membr. Sci. 2013,427 (10), 207.
28. [28]
  (28) Chen, X.; Chen, N. L. Journal of DongHua University (Natural Science) 2009, 35 (1), 30. [陈霄, 陈南梁. 东华大学学报(自然科学版), 2009, 35 (1), 30.]
1. [1]
  Shijie Li , Ke Rong , Xiaoqin Wang , Chuqi Shen , Fang Yang , Qinghong Zhang . Design of Carbon Quantum Dots/CdS/Ta₃N₅ S-Scheme Heterojunction Nanofibers for Efficient Photocatalytic Antibiotic Removal. Acta Physico-Chimica Sinica, 2024, 40(12): 2403005-. doi: 10.3866/PKU.WHXB202403005
2. [2]
  Guoqiang Chen , Zixuan Zheng , Wei Zhong , Guohong Wang , Xinhe Wu . 熔融中间体运输导向合成富氨基g-C₃N₄纳米片用于高效光催化产H₂O₂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406021-. doi: 10.3866/PKU.WHXB202406021
3. [3]
  Heng Chen , Longhui Nie , Kai Xu , Yiqiong Yang , Caihong Fang . 两步焙烧法制备大比表面积和结晶性增强超薄g-C₃N₄纳米片及其高效光催化产H₂O₂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406019-. doi: 10.3866/PKU.WHXB202406019
4. [4]
  Changjun You , Chunchun Wang , Mingjie Cai , Yanping Liu , Baikang Zhu , Shijie Li . 引入内建电场强化BiOBr/C₃N₅ S型异质结中光载流子分离以实现高效催化降解微污染物. Acta Physico-Chimica Sinica, 2024, 40(11): 2407014-. doi: 10.3866/PKU.WHXB202407014
5. [5]
  Zijian Jiang , Yuang Liu , Yijian Zong , Yong Fan , Wanchun Zhu , Yupeng Guo . Preparation of Nano Zinc Oxide by Microemulsion Method and Study on Its Photocatalytic Activity. University Chemistry, 2024, 39(5): 266-273. doi: 10.3866/PKU.DXHX202311101
6. [6]
  Xuejiao Wang , Suiying Dong , Kezhen Qi , Vadim Popkov , Xianglin Xiang . Photocatalytic CO₂ Reduction by Modified g-C₃N₄. Acta Physico-Chimica Sinica, 2024, 40(12): 2408005-. doi: 10.3866/PKU.WHXB202408005
7. [7]
  Chenye An , Abiduweili Sikandaier , Xue Guo , Yukun Zhu , Hua Tang , Dongjiang Yang . 红磷纳米颗粒嵌入花状CeO₂分级S型异质结高效光催化产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2405019-. doi: 10.3866/PKU.WHXB202405019
8. [8]
  Tong Zhou , Xue Liu , Liang Zhao , Mingtao Qiao , Wanying Lei . Efficient Photocatalytic H₂O₂ Production and Cr(VI) Reduction over a Hierarchical Ti₃C₂/In₄SnS₈ Schottky Junction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309020-. doi: 10.3866/PKU.WHXB202309020
9. [9]
  Yang Xia , Kangyan Zhang , Heng Yang , Lijuan Shi , Qun Yi . 构建双通道路径增强iCOF/Bi₂O₃ S型异质结在纯水体系中光催化合成H₂O₂性能. Acta Physico-Chimica Sinica, 2024, 40(11): 2407012-. doi: 10.3866/PKU.WHXB202407012
10. [10]
  Xinyu Yin , Haiyang Shi , Yu Wang , Xuefei Wang , Ping Wang , Huogen Yu . Spontaneously Improved Adsorption of H₂O and Its Intermediates on Electron-Deficient Mn^(3+δ)+ for Efficient Photocatalytic H₂O₂ Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312007-. doi: 10.3866/PKU.WHXB202312007
11. [11]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
12. [12]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
13. [13]
  Jianyin He , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . ZnCoP/CdLa₂S₄肖特基异质结的构建促进光催化产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2404030-. doi: 10.3866/PKU.WHXB202404030
14. [14]
  Wenxiu Yang , Jinfeng Zhang , Quanlong Xu , Yun Yang , Lijie Zhang . Bimetallic AuCu Alloy Decorated Covalent Organic Frameworks for Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312014-. doi: 10.3866/PKU.WHXB202312014
15. [15]
  Yuanyin Cui , Jinfeng Zhang , Hailiang Chu , Lixian Sun , Kai Dai . Rational Design of Bismuth Based Photocatalysts for Solar Energy Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2405016-. doi: 10.3866/PKU.WHXB202405016
16. [16]
  Ruolin CHENG , Haoran WANG , Jing REN , Yingying MA , Huagen LIANG . Efficient photocatalytic CO₂ cycloaddition over W₁₈O₄₉/NH₂-UiO-66 composite catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 523-532. doi: 10.11862/CJIC.20230349
17. [17]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-. doi: 10.3866/PKU.WHXB202406029
18. [18]
  Jingyu Cai , Xiaoyu Miao , Yulai Zhao , Longqiang Xiao . Exploratory Teaching Experiment Design of FeOOH-RGO Aerogel for Photocatalytic Benzene to Phenol. University Chemistry, 2024, 39(4): 169-177. doi: 10.3866/PKU.DXHX202311028
19. [19]
  Ke Li , Chuang Liu , Jingping Li , Guohong Wang , Kai Wang . 钛酸铋/氮化碳无机有机复合S型异质结纯水光催化产过氧化氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2403009-. doi: 10.3866/PKU.WHXB202403009
20. [20]
  Qin Hu , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . Ni掺杂构建电子桥及激活MoS₂惰性基面增强光催化分解水产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2406024-. doi: 10.3866/PKU.WHXB202406024

Get Citation

PDF

XML

Metrics

PDF Downloads(570)
Abstract views(652)
HTML views(5)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Coordination Kinetics of Fe3+ with Membranes Based on Modified PAN Nanofibers with Different Diameters, and Catalytic Effect of Their Complexes on Decomposition of Organic Dye

Metrics

通讯作者: 陈斌, bchen63@163.com

Coordination Kinetics of Fe³⁺ with Membranes Based on Modified PAN Nanofibers with Different Diameters, and Catalytic Effect of Their Complexes on Decomposition of Organic Dye