Citation: HUANG Xian-Dan, LI Li, WEI Qiu-Ying, ZHANG Wen-Zhi, LU Lu. Preparation of Three-Dimensionally Ordered Macroporous Composite Bi₂O₃/TiO₂ and Its Photocatalytic Degradation of Crystal Violet under Multiple Modes[J]. Acta Physico-Chimica Sinica, ;2013, 29(12): 2615-2623. doi: 10.3866/PKU.WHXB201310221 shu

Preparation of Three-Dimensionally Ordered Macroporous Composite Bi₂O₃/TiO₂ and Its Photocatalytic Degradation of Crystal Violet under Multiple Modes

HUANG Xian-Dan ¹ ,
LI Li ^1,2, ,
WEI Qiu-Ying ¹ ,
ZHANG Wen-Zhi ¹ ,
LU Lu ¹

1.
1 College of Materials Science and Engineering, Qiqihar University, Qiqihar 161006, Heilongjiang Province, P. R. China;
2 Key Laboratory of Composite Modified Material of Colleges in Heilongjang Provence, Qiqihar 161006, Heilongjiang Province, P. R. China

Received Date: 16 July 2013
Available Online: 22 October 2013
Fund Project: 国家自然科学基金(21376126) (21376126) 黑龙江省自然科学基金(B201106) (B201106) 黑龙江省教育厅科学技术研究项目(12511592) (12511592) 黑龙江省政府博士后资助经费(LBH-Z11108) (LBH-Z11108)黑龙江省普通高校绿色化工技术重点实验室开放课题(2013 年)资助 (2013 年)

Polystyrene latex (PS) spheres and EO₂₀PO₇₀O₂₀ (P123) were used as dual template agents, with TiO₂ as the matrix, to prepare a three-dimensionally ordered macroporous (3DOM) composite Bi₂O₃/TiO₂, using a sol-gel method and post-processing calcination. The phase structures, chemical composition, morphology, and surface physicochemical properties were characterized using X-ray diffraction (XRD), Fourier-transform infrared (FT-IR), ultraviolet-visible diffuse reflectance (UV-Vis DRS) and X-ray photoelectron spectroscopies (XPS), inductively coupled plasma atomic emission spectroscopy (ICP-AES), scanning electron microscopy (SEM), and N₂ adsorption-desorption measurements. The results show that the composite is well crystallized and has a highly ordered porous structure with mesoporous walls; it is a 3DOM material. The light absorption of 3DOM-Bi₂O₃/TiO₂ is red-shifted by about 60 nm to the visible region compared with TiO₂. In the photocatalytic degradation of crystal violet using various methods, namely ultraviolet, visible-light, and microwave-assisted irradiation, the activity of 3DOM-Bi₂O₃/TiO₂ is significantly higher than those of P25, Bi₂O₃, and Bi₂O₃/TiO₂. The 3DOM-Bi₂O₃/TiO₂ composite also shows od photocatalytic activity in the degradations of various dyes under ultraviolet irradiation. The 3DOM-Bi₂O₃/TiO₂ activity is well retained after three cycles.
- Polystyrene,
- Three-dimensionally ordered macroporous,
- Bi₂O₃/TiO₂,
- Photocatalysis,
- Crystal violet
1. [1]
  
  (1) Gan, Y. P.; Qin, H. P.; Huang, H.; Tao, X. Y.; Fang, J.W.;Zhang,W. K. Acta Phys. -Chim. Sin. 2013, 29 (2), 403. [甘永平, 秦怀鹏, 黄辉, 陶新永, 方俊武, 张文魁. 物理化学学报,2013, 29 (2), 403.] doi: 10.3866/PKU.WHXB201211022
2. [2]
  (2) Cao, X. X.; Chen, Y. L.; Lin, B. Z.; Gao, B. F. J. Inorg. Mater.2012, 27 (12), 1302. [操小鑫, 陈亦琳, 林碧洲, 高碧芬. 无机材料学报, 2012, 27 (12), 1302.]
3. [3]
  (3) Qiu,W.; Ren, C. J.; ng, M. C.; Hou, Y. Z.; Chen, Y. Q. Acta Phys. -Chim. Sin. 2011, 27 (6), 1487. [仇伟, 任成军, 龚茂初, 侯云泽, 陈耀强. 物理化学学报, 2011, 27 (6), 1487.] doi: 10.3866/PKU.WHXB20110621
4. [4]
  (4) Zhai, X. H.; Long, H. J.; Dong, J. Z.; Cao, Y. A. Acta Phys. - Chim. Sin. 2010, 26 (3), 663. [翟晓辉, 龙绘锦, 董江舟, 曹亚安. 物理化学学报, 2010, 26 (3), 663.] doi: 10.3866/PKU.WHXB20100317
5. [5]
  (5) Li, A. C.; Li, G. H.; Zheng, Y.; Ma, L. L.; Zhen, Y. J. Acta Phys. -Chim. Sin. 2012, 28 (2), 458. [李爱昌, 李桂花, 郑琰, 马玲玲, 郑彦俊. 物理化学学报, 2012, 28 (2), 458.] doi: 10.3866/PKU.WHXB201112081
6. [6]
  (6) Zou,W.; Hao,W. C.; Xin, X.;Wang, T. M. Chin. J. Inorg. Chem. 2009, 25 (11), 1971. [邹文, 郝伟昌, 信心, 王天民. 无机化学学报, 2009, 25 (11), 1971.]
7. [7]
  (7) Ma, Z. Y.; Yao, B. H.; He, Y. Q.; Bai, H. N.; Gao, Y. H. J. Funct. Mater. 2013, 4 (44), 507. [马占营, 姚秉华, 何抑清, 白海妮,高奕红. 功能材料, 2013, 4 (44), 507.]
8. [8]
  (8) Bessekhouad, Y.; Robert, D.;Weber, J. Y. Catal. Today 2005,101 (4), 315.
9. [9]
  (9) Song, L. M.; Zhang, S. J.;Wu, X. Q.;Wei, Q.W. J. Am. Chem. Soc. 2012, 51 (13), 4922.
10. [10]
  (10) Ghule, L. A.; Shirke, B. S.; Sapnar, K. B.; Dhole, S. D.;Hankare, P. P.; Garadkar, K. M. J. Mater. Sci.: Mater. Electron.2011, 22 (8), 1120. doi: 10.1007/s10854-010-0270-0
11. [11]
  (11) Cho, S.; Jang, J.W.; Jung, S. H.; Lee, B. R.; Oh, E.; Lee, K. H.Langmuir 2009, 25 (6), 3825. doi: 10.1021/la804009g
12. [12]
  (12) Wan, L. S.; Lv, J.; Ke, B. B.; Xu, Z. K. J. Am. Chem. Soc. 2010,2 (12), 3759.
13. [13]
  (13) Velev, O. D.; Kaler, E.W. Adv. Mater. 2000, 12 (7), 531.
14. [14]
  (14) Klein, S. M.; Manoharan, V. N.; Pine, D. J. Langmuir 2005, 21 (15), 6669. doi: 10.1021/la0469957
15. [15]
  (15) Manoharan, V. N.; Imhof, A.; Thorne, J. D. Adv. Mater. 2001, 13 (6), 447.
16. [16]
  (16) Li, L.; Zhao, Y. H.; Li, E. S.; Z, N.; Ma, H. Y.; Liu, B. Chem. J. Chin. Univ. 2011, 32 (6), 1323. [李莉, 赵月红, 李恩帅,禚娜, 马慧媛, 刘波. 高等学校化学学报, 2011, 32 (6),1323.]
17. [17]
  (17) Li, L.; Zhao, Y. H.; Lu, L.; Ma, H. Y.; Liu, B. Chin. J. Inorg. Chem. 2012, 28 (6), 1131. [李莉, 赵月红, 路露, 马慧媛,刘波. 无机化学学报, 2012, 28 (6), 1131.]
18. [18]
  (18) Deng, Z.W.; Chen, M.; Zhou, S. X.; You, B.;W, L. M.Langmuir 2006, 22 (14), 6403. doi: 10.1021/la060944n
19. [19]
  (19) Ma, T. Y.; Zhang, X. J.; Shao, G. S.; Cao, J. L.; Yuan, Z. Y. J. Phys. Chem. C 2008, 112 (8), 3090. doi: 10.1021/jp710636x
20. [20]
  (20) Shim, S. E.; Cha, Y. J.; Byun, J. M.; Choe, S. J. Appl. Polym. Sci. 1999, 71 (13), 2259.
21. [21]
  (21) Li, L.; Zhang, X. F.; Ma, Y.; Zhang,W. Z.; Guo, Y. X. CIESC Journal 2008, 59 (12), 3067. [李莉, 张秀芬, 马禹, 张文治, 郭一荇. 化工学报, 2008, 59 (12), 3067.]
22. [22]
  (22) Yang, J. C.; Michael, J. J.; Jimmy,W. M. Polymer 2002, 43 (19),5125. doi: 10.1016/S0032-3861(02)00390-7
23. [23]
  (23) Fang, J. F.; Xuan, Y. M.; Li, Q. Sci. China Technol. Sci. 2010,53 (11), 3088. doi: 10.1007/s11431-010-4110-5
24. [24]
  (24) Demirors, A. F.; Eser, B. E.; Omer, D. Langmuir 2005, 21 (9),4156. doi: 10.1021/la047136l
25. [25]
  (25) Shi, J. Y.; Chen, J.; Feng, Z. C.; Chen, T.; Lian, Y. X.;Wang, X.L.; Li, C. J. Phys. Chem. C 2007, 111 (2), 693. doi: 10.1021/jp065744z
26. [26]
  (26) Wang, T.; Jiang, X.;Wu, Y. X. Ind. Eng. Chem. Res. 2009, 48 (13), 6224. doi: 10.1021/ie801974y
27. [27]
  (27) Vu, D.; Li, X.; Li, Z. Y.;Wang, C. J. Chem. Eng. Data 2013, 58 (1), 71. doi: 10.1021/je301017q
28. [28]
  (28) Bian, Z. F.; Zhu, J.;Wang, S. H. J. Phys. Chem . C 2008, 112 (16), 6258.
29. [29]
  (29) Wang, C. M.; Sun, Z. Y.; Ma, L. Y.; Su, M. Simultaneous Anal. Chem. 2011, 83 (6), 2217.
30. [30]
  (30) Abdallah,W. A.; Taylor, S. D. J. Phys. Chem. C 2008, 112 (48),18963.
31. [31]
  (31) Harison, P. G.; Lloy, N. C.; Darill,W. J. Phys. Chem. B 1998,102 (52), 10672. doi: 10.1021/jp9822135
32. [32]
  (32) Kang, S. H.; Kim, J. Y.; Kim, Y. K. J. Phys. Chem. C 2007, 111 (26), 9614. doi: 10.1021/jp071504n
33. [33]
  (33) Vaidya, R.; Simonson, R J.; Dimos, D. Langmuir 1996, 12(11)2830. doi: 10.1021/la951072k
34. [34]
  (34) Srinivasan, M.; White, T. Environ. Sci. Technol. 2007, 41 (12),4405. doi: 10.1021/es070160b
35. [35]
  (35) Sun,W.; Zhou, S. X.; You, B.;Wu, L. M. Chem. Mater. 2012,24 (19), 3800. doi: 10.1021/cm302464g
36. [36]
  (36) Harish, K. N.; Naik, B.; Prashanth Kumar, P. N.; Viswanath, R.ACS Sustainable Chem. Eng. 2013, 1 (9), 1143. doi: 10.1021/sc400060z
37. [37]
  (37) Chen, Z. X.; Li, D. Z.; Zhang,W. J.; Shao, Y.; Chen, T.W.; Sun,M.; Fu, X. Z. J. Phys. Chem. C 2009, 113 (11), 4433. doi: 10.1021/jp8092513
38. [38]
  (38) Yang, X. F.; Cui, H.Y.; Li, Y.; Qin, J. L.; Zhang, R. X.; Tang, H.ACS Catal. 2013, 3 (3), 363. doi: 10.1021/cs3008126
39. [39]
  (39) Li, L.; Ji, Y.; Lu, D.; Zhao, Y. H. Chem. Online 2010, 6 (73),645. [李莉, 计远, 陆丹, 赵月红. 化学通报, 2010, 6 (73), 645.]
40. [40]
  (40) Chen, H. Z.; Yang, S. G.; Y, K.; J, Y. M.; Sun, C. J. Phys. Chem. A 2011, 115 (14), 3034. doi: 10.1021/jp109948n
41. [41]
  (41) Fan, H. M.; Li, H. Y.; Liu, B. K.; Lu, Y. C.; Xie, T. F.;Wang, D.J. Appl. Mater. Interfaces 2012, 4 (9), 4853. doi: 10.1021/am301199v
42. [42]
  (42) Sarkar, D.; Ghosh, C. K.; Mukherjee, S.; Chattopadhyay, K. K.Appl. Mater. Interfaces 2013, 5 (2), 331. doi: 10.1021/am302136y
43. [43]
  (43) Georgekutty, R.; Seery, M. K.; Pillai, S. C. J. Phys. Chem. C2008, 112 (35), 13563. doi: 10.1021/jp802729a
44. [44]
  (44) Kim, S.; Park, H.; Choi,W. J. Phys. Chem. B 2004, 108 (20),6402.
45. [45]
  (45) Chen, C. C.;Wang, Q.; Lei, P. X.; Song,W. J.; Ma,W. H.; Zhao,J. C. Environ. Sci. Technol. 2006, 40 (12), 3965. doi: 10.1021/jp049789g
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Preparation of Three-Dimensionally Ordered Macroporous Composite Bi₂O₃/TiO₂ and Its Photocatalytic Degradation of Crystal Violet under Multiple Modes