Citation: HUANG Xian-Dan, LI Li, WEI Qiu-Ying, ZHANG Wen-Zhi, LU Lu. Preparation of Three-Dimensionally Ordered Macroporous Composite Bi₂O₃/TiO₂ and Its Photocatalytic Degradation of Crystal Violet under Multiple Modes[J]. Acta Physico-Chimica Sinica, ;2013, 29(12): 2615-2623. doi: 10.3866/PKU.WHXB201310221 shu

Preparation of Three-Dimensionally Ordered Macroporous Composite Bi₂O₃/TiO₂ and Its Photocatalytic Degradation of Crystal Violet under Multiple Modes

HUANG Xian-Dan ¹ ,
LI Li ^1,2, ,
WEI Qiu-Ying ¹ ,
ZHANG Wen-Zhi ¹ ,
LU Lu ¹

1.
1 College of Materials Science and Engineering, Qiqihar University, Qiqihar 161006, Heilongjiang Province, P. R. China;
2 Key Laboratory of Composite Modified Material of Colleges in Heilongjang Provence, Qiqihar 161006, Heilongjiang Province, P. R. China

Received Date: 16 July 2013
Available Online: 22 October 2013
Fund Project: 国家自然科学基金(21376126) (21376126) 黑龙江省自然科学基金(B201106) (B201106) 黑龙江省教育厅科学技术研究项目(12511592) (12511592) 黑龙江省政府博士后资助经费(LBH-Z11108) (LBH-Z11108)黑龙江省普通高校绿色化工技术重点实验室开放课题(2013 年)资助 (2013 年)

Polystyrene latex (PS) spheres and EO₂₀PO₇₀O₂₀ (P123) were used as dual template agents, with TiO₂ as the matrix, to prepare a three-dimensionally ordered macroporous (3DOM) composite Bi₂O₃/TiO₂, using a sol-gel method and post-processing calcination. The phase structures, chemical composition, morphology, and surface physicochemical properties were characterized using X-ray diffraction (XRD), Fourier-transform infrared (FT-IR), ultraviolet-visible diffuse reflectance (UV-Vis DRS) and X-ray photoelectron spectroscopies (XPS), inductively coupled plasma atomic emission spectroscopy (ICP-AES), scanning electron microscopy (SEM), and N₂ adsorption-desorption measurements. The results show that the composite is well crystallized and has a highly ordered porous structure with mesoporous walls; it is a 3DOM material. The light absorption of 3DOM-Bi₂O₃/TiO₂ is red-shifted by about 60 nm to the visible region compared with TiO₂. In the photocatalytic degradation of crystal violet using various methods, namely ultraviolet, visible-light, and microwave-assisted irradiation, the activity of 3DOM-Bi₂O₃/TiO₂ is significantly higher than those of P25, Bi₂O₃, and Bi₂O₃/TiO₂. The 3DOM-Bi₂O₃/TiO₂ composite also shows od photocatalytic activity in the degradations of various dyes under ultraviolet irradiation. The 3DOM-Bi₂O₃/TiO₂ activity is well retained after three cycles.
- Polystyrene,
- Three-dimensionally ordered macroporous,
- Bi₂O₃/TiO₂,
- Photocatalysis,
- Crystal violet
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Preparation of Three-Dimensionally Ordered Macroporous Composite Bi₂O₃/TiO₂ and Its Photocatalytic Degradation of Crystal Violet under Multiple Modes