Citation: LIU De-Zhi, HOU Xi-Xin, ZHU Xiu-Ling, WANG Rui, JING Jian, CUI Yue. Preparation and Physicochemical Property of Self-Crosslinked Poly(phthalazinone ether ketone) Anion-Exchange Membranes[J]. Acta Physico-Chimica Sinica, ;2013, 29(12): 2573-2578. doi: 10.3866/PKU.WHXB201310214 shu

Preparation and Physicochemical Property of Self-Crosslinked Poly(phthalazinone ether ketone) Anion-Exchange Membranes

1.
School of Chemical Engineering, Faculty of Environmental and Biological Science and Technology, Dalian University of Technology, Dalian 116024, Liaoning Province, P. R. China

Received Date: 22 August 2013
Available Online: 21 October 2013

Self-crosslinked poly(phthalazinone ether ketone) anion-exchange membranes (AEMs) were successfully fabricated from chloromethylated poly(phthalazinone ether ketone) (CMPPEK) by amination, membrane casting, and OH-exchange reaction steps. Triethylamine (TEA) was used as an ammonium agent, and diethylenetriamine (DETA) and diethylamine (DEA) were used as self-crosslinking agents in the quaternary reaction of CMPPEK, resulting in DETA-QPPEK-OH and DEA-QPPEK-OH AEMs, respectively. The chemical structures of DETA-QPPEK-OH and DEA-QPPEK-OH were characterized using Fourier transform infrared (FTIR) spectroscopy. The physicochemical properties of these AEMs were investigated including ion-exchange capacity (IEC), swelling ratios, water uptake, and ionic conductivities at 30 ℃. The results showed that the swelling ratio of the DETA-crosslinked AEM was lower than that of the DEAcrosslinked AEM. This could be attributed to multi-crosslinking of multi-amino groups in the DETA structure. The temperature dependences of the ionic conductivities of the AEMs were measured from 30 to 80 ℃. The ionic conductivities of the DEA-crosslinked and DETA-crosslinked AEMs were 0.060 and 0.028 S·cm^-1 at 80 ℃, respectively. The thermal stabilities of the resulting DETA-QPPEK-OH and DEAQPPEK-OH membranes were investigated using thermogravimetric analysis (TGA), under a nitrogen atmosphere. The obtained membranes have high dimensional stabilities and are very promising for potential applications in anion-exchange membrane fuel cells (AEMFCs).
- Anion exchange membrane,
- Alkaline fuel cell,
- Poly(phthalazinone ether ketone),
- Diethylenetriamine,
- Self-crosslinking,
- Conductivity
References
1. [1]
  
  (1) Yi, B. L. Fuel Cell——A High Efficient and Environmental Friendly Power Generation; Chemical Industry Press: Beijing,2000; p 32. [衣宝廉. 燃料电池——高效环境友好的发电方式. 北京: 化学工业出版社, 2000: 32.]
2. [2]
  (2) Zhou, Y. H. Chin. J. Power Sources 1996, 20, 161. [周运鸿. 电源技术, 1996, 20, 161.]
3. [3]
  (3) Schultz, M. G.; Diehl, T.; Brasseur, G. P.; Zittel,W. Science2003, 302, 624. doi: 10.1126/science.1089527
4. [4]
  (4) Inzelt, G.; Pineri, M.; Schultze, J.W.; Vorofyntsev, M. A.Electrochim. Acta 2000, 45, 2403. doi: 10.1016/S0013-4686(00)00329-7
5. [5]
  (5) Varcoe, J. R.; Slade, R. C. T.; Yee, E. L. H. Chem. Commun.2006, 1428.
6. [6]
  (6) Lu, S.; Pan, J.; Huang, A.; Zhuang, L. Proc. Natl. Acad. Sci. U. S. A. 2008, 105, 20611. doi: 10.1073/pnas.0810041106
7. [7]
  (7) Ye, Y.; Elabd, Y. A. Macromolecule 2011, 44, 8494. doi: 10.1021/ma201864u
8. [8]
  (8) Zhu, X.; Liang, Y.; Pan, H.; Jian, X.; Zhang, Y. J. Membr. Sci.2008, 312, 59. doi: 10.1016/j.memsci.2007.12.058
9. [9]
  (9) Liu, Z. Cross-linked Alkaline Exchange Membrane for FuelCell. Master's Thesis, Dalian University of Technology, Dalian,2011. [刘陟. 交联型燃料电池用阴离子交换膜的制备研究[D]. 大连: 大连理工大学, 2011.]
10. [10]
  (10) Chen, Y. L.; Meng, Y. Z.; Hay, A. S. Macromolecules 2005, 38,3564. doi: 10.1021/ma047591o
11. [11]
  (11) Zhu, X.; Liang, Y.; Pan, H.; Jian, X.; Zhang, Y. J. Membr. Sci.2008, 312, 59. doi: 10.1016/j.memsci.2007.12.058
12. [12]
  (12) Pan, H.; Zhu, X.; Chen, J.; Jian, X. J. Membr. Sci. 2009, 326,453. doi: 10.1016/j.memsci.2008.10.047
13. [13]
  (13) Gao, Y.; Robertson, G. P.; Guiver, M. D.; Jian, X. G. J. Polym. Sci. Part A: Polym. Chem. 2003, 41, 497.
14. [14]
  (14) Zhang, S.; Yin, C.; Xing, D.; Yang, D.; Jian, X. J. Membr. Sci.2010, 363, 243. doi: 10.1016/j.memsci.2010.07.046
15. [15]
  (15) Zhang, H.; Zhou, Z. J. Applied Polym. Sci. 2008, 110, 1756. doi: 10.1002/app.v110:3
16. [16]
  (16) Fang, J.; Shen, P. K. J. Membr. Sci. 2006, 285, 317.
17. [17]
  (17) Pan, J.; Chen, C.; Zhuang, L.; Lu, J. Accounts Chem. Res. 2012,45, 473. doi: 10.1021/ar200201x
18. [18]
  (18) Pan, J.; Li, Y.; Zhuang, L.; Lu, J. Chem. Commun. 2010, 46,8597. doi: 10.1039/c0cc03618h
19. [19]
  (19) Zhao, Y.; Yu, H.; Yang, D.; Li, J.; Shao, Z.; Yi, B. J. Power Sources 2013, 221, 247.
20. [20]
  (20) Sun, H.; Zhang, G.; Liu, Z.; Zhang, N.; Zhang, L.; Ma,W.;Zhao, C.; Qi, D.; Li, G.; Na, H. Int. J. Hydrog. Energy 2012, 37,9873. doi: 10.1016/j.ijhydene.2012.03.115
21. [21]
  (21) Gu, S.; Cai, R.; Yan, Y. Chem. Commun. 2011, 47, 2856. doi: 10.1039/c0cc04335d
22. [22]
  (22) Yan, C.; Zhang, S.; Yang, D.; Jian, X. J. Appl. Polym. Sci. 2008,107, 1809.
1. [1]
  
  (1) Yi, B. L. Fuel Cell——A High Efficient and Environmental Friendly Power Generation; Chemical Industry Press: Beijing,2000; p 32. [衣宝廉. 燃料电池——高效环境友好的发电方式. 北京: 化学工业出版社, 2000: 32.]
2. [2]
  (2) Zhou, Y. H. Chin. J. Power Sources 1996, 20, 161. [周运鸿. 电源技术, 1996, 20, 161.]
3. [3]
  (3) Schultz, M. G.; Diehl, T.; Brasseur, G. P.; Zittel,W. Science2003, 302, 624. doi: 10.1126/science.1089527
4. [4]
  (4) Inzelt, G.; Pineri, M.; Schultze, J.W.; Vorofyntsev, M. A.Electrochim. Acta 2000, 45, 2403. doi: 10.1016/S0013-4686(00)00329-7
5. [5]
  (5) Varcoe, J. R.; Slade, R. C. T.; Yee, E. L. H. Chem. Commun.2006, 1428.
6. [6]
  (6) Lu, S.; Pan, J.; Huang, A.; Zhuang, L. Proc. Natl. Acad. Sci. U. S. A. 2008, 105, 20611. doi: 10.1073/pnas.0810041106
7. [7]
  (7) Ye, Y.; Elabd, Y. A. Macromolecule 2011, 44, 8494. doi: 10.1021/ma201864u
8. [8]
  (8) Zhu, X.; Liang, Y.; Pan, H.; Jian, X.; Zhang, Y. J. Membr. Sci.2008, 312, 59. doi: 10.1016/j.memsci.2007.12.058
9. [9]
  (9) Liu, Z. Cross-linked Alkaline Exchange Membrane for FuelCell. Master's Thesis, Dalian University of Technology, Dalian,2011. [刘陟. 交联型燃料电池用阴离子交换膜的制备研究[D]. 大连: 大连理工大学, 2011.]
10. [10]
  (10) Chen, Y. L.; Meng, Y. Z.; Hay, A. S. Macromolecules 2005, 38,3564. doi: 10.1021/ma047591o
11. [11]
  (11) Zhu, X.; Liang, Y.; Pan, H.; Jian, X.; Zhang, Y. J. Membr. Sci.2008, 312, 59. doi: 10.1016/j.memsci.2007.12.058
12. [12]
  (12) Pan, H.; Zhu, X.; Chen, J.; Jian, X. J. Membr. Sci. 2009, 326,453. doi: 10.1016/j.memsci.2008.10.047
13. [13]
  (13) Gao, Y.; Robertson, G. P.; Guiver, M. D.; Jian, X. G. J. Polym. Sci. Part A: Polym. Chem. 2003, 41, 497.
14. [14]
  (14) Zhang, S.; Yin, C.; Xing, D.; Yang, D.; Jian, X. J. Membr. Sci.2010, 363, 243. doi: 10.1016/j.memsci.2010.07.046
15. [15]
  (15) Zhang, H.; Zhou, Z. J. Applied Polym. Sci. 2008, 110, 1756. doi: 10.1002/app.v110:3
16. [16]
  (16) Fang, J.; Shen, P. K. J. Membr. Sci. 2006, 285, 317.
17. [17]
  (17) Pan, J.; Chen, C.; Zhuang, L.; Lu, J. Accounts Chem. Res. 2012,45, 473. doi: 10.1021/ar200201x
18. [18]
  (18) Pan, J.; Li, Y.; Zhuang, L.; Lu, J. Chem. Commun. 2010, 46,8597. doi: 10.1039/c0cc03618h
19. [19]
  (19) Zhao, Y.; Yu, H.; Yang, D.; Li, J.; Shao, Z.; Yi, B. J. Power Sources 2013, 221, 247.
20. [20]
  (20) Sun, H.; Zhang, G.; Liu, Z.; Zhang, N.; Zhang, L.; Ma,W.;Zhao, C.; Qi, D.; Li, G.; Na, H. Int. J. Hydrog. Energy 2012, 37,9873. doi: 10.1016/j.ijhydene.2012.03.115
21. [21]
  (21) Gu, S.; Cai, R.; Yan, Y. Chem. Commun. 2011, 47, 2856. doi: 10.1039/c0cc04335d
22. [22]
  (22) Yan, C.; Zhang, S.; Yang, D.; Jian, X. J. Appl. Polym. Sci. 2008,107, 1809.
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Physicochemical Property of Self-Crosslinked Poly(phthalazinone ether ketone) Anion-Exchange Membranes

References

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

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通讯作者: 陈斌, bchen63@163.com