Citation: ZHAO Ning-Ning, HE Cui-Cui, LIU Jian-Bing, MA Hai-Xia, AN Ting, ZHAO Feng-Qi, HU Rong-Zu. Preparation and Characterization of Superthermite Al/Fe₂O₃ and Its Effect on Thermal Decomposition of Cyclotrimethylene Trinitramine[J]. Acta Physico-Chimica Sinica, ;2013, 29(12): 2498-2504. doi: 10.3866/PKU.WHXB201310212 shu

Preparation and Characterization of Superthermite Al/Fe₂O₃ and Its Effect on Thermal Decomposition of Cyclotrimethylene Trinitramine

1.
1 School of Chemical Engineering, Northwest University, Xi'an 710069, P. R. China;
2 Science and Technology on Combustion and Explosion Laboratory, Xi'an Modern Chemistry Research Institute, Xi'an 710065, P. R. China

Received Date: 12 June 2013
Available Online: 21 October 2013
Fund Project: 国家自然科学基金(21073141, 21373161) (21073141, 21373161) 教育部新世纪优秀人才支持计划基金(12-1047) (12-1047) 高等学校博士学科点专项科研基金(20126101110009) (20126101110009)燃烧与爆炸技术重点实验室基金(9140C3501041001)资助项目 (9140C3501041001)

Hollow Fe₂O₃ nanorods were prepared using a hydrothermal method, and were then combined with Al nanoparticles to form superthermite Al/Fe₂O₃ by ultrasonic mixing. Fe₂O₃ and Al/Fe₂O₃ were characterized using X-ray powder diffraction (XRD), Fourier-transform infrared (FTIR) spectroscopy, and scanning electron microscopy-energy dispersive spectroscopy (SEM-EDS). The effects of Al/Fe₂O₃, Al, and nano-Fe₂O₃ powders on the thermal decomposition of cyclotrimethylene trinitramine (RDX) were investigated using differential scanning calorimetry (DSC). The results show that the superthermite Al/Fe₂O₃ affects the thermal decomposition of RDX and greatly enhances its secondary gas-phase reaction. The shapes of the main RDX decomposition peaks changed with increasing superthermite content. The main influences of superthermite Al/Fe₂O₃, Al nanopowders, and Fe₂O₃ nanorods on the thermal decomposition of RDX are that the secondary decomposition peaks become distinct and the peak temperature decreases.
- Nano-Fe₂O₃,
- Superthermite Al/Fe₂O₃,
- Cyclotrimethylene trinitramine,
- Hydrothermal method,
- Ultrasonically dispersed method,
- Thermal decomposition
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1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Characterization of Superthermite Al/Fe2O3 and Its Effect on Thermal Decomposition of Cyclotrimethylene Trinitramine

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通讯作者: 陈斌, bchen63@163.com

Preparation and Characterization of Superthermite Al/Fe₂O₃ and Its Effect on Thermal Decomposition of Cyclotrimethylene Trinitramine