Citation: SONG Han, WANG Na-Na, LI Yue, RUAN Wen-Juan. Synthesis, Characterization and Properties of Terminal Alkynylate Modified Salen-Type Complexes[J]. Acta Physico-Chimica Sinica, ;2013, 29(11): 2300-2307. doi: 10.3866/PKU.WHXB201310091 shu

Synthesis, Characterization and Properties of Terminal Alkynylate Modified Salen-Type Complexes

1.
Department of Chemistry, Nankai University, Tianjin 300071, P. R. China

Received Date: 15 July 2013
Available Online: 9 October 2013
Fund Project: 国家自然科学基金(20671053)资助项目 (20671053)

We synthesized two terminal alkynyl modified Salen ligands, H₂Lⁿ, and their metal complexes, MLⁿ (n=1, 2, M=Ni, Cu, Mn). The ligands and complexes were characterized by ¹H nuclear magnetic resonance (¹H NMR) spectroscopy, electrospray ionization mass spectrometry (ESI-MS), elemental analysis, Fourier transform infrared (FT-IR) spectroscopy, and ultraviolet visible (UV-Vis) spectroscopy. The redox properties of the compounds were investigated with cyclic voltammetry (CV). Imine redox peaks appeared in the CV curves of all the ligands except H₂L¹. The Ni and Cu complexes underwent two single electron redox processes in the scanning range. Mn complexes gave a pair of quasi-reversible voltammetric peaks, which corresponded to the redox process between Mn(III)/Mn(II). Molar conductivity measurements of the complexes showed that they were all weak electrolytes with certain conductivity.
- Salen-type complex,
- Terminal alkynyl,
- Synthesis and characterization,
- Spectrum property,
- Cyclic voltammetry
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