Citation: WAN Dong, WANG Guang-Hua, LI Wen-Bing, CHEN Kun, SHU Guang. Synthesis of Fe-Al Pillared Bentonite and Heterogeneous Fenton Degradation of Orange Ⅱ[J]. Acta Physico-Chimica Sinica, ;2013, 29(11): 2429-2436. doi: 10.3866/PKU.WHXB201310084 shu

Synthesis of Fe-Al Pillared Bentonite and Heterogeneous Fenton Degradation of Orange Ⅱ

1.
College of Chemical Engineering and Technology, Wuhan University of Science and Technology, Wuhan 430081, P. R. China

Received Date: 11 July 2013
Available Online: 8 October 2013
Fund Project: 高等学校博士学科点专项科研基金(20114219110002) (20114219110002) 煤转化与新型炭材料湖北省重点实验室开放基金(武汉科技大学) (WKDM201107) (武汉科技大学) (WKDM201107)湖北省教育厅重点项目(D20131107)资助 (D20131107)

A series of Fe-Al pillared bentonites with different Fe contents were synthesized through a simple ion exchange method. The samples were used as catalysts for the heterogeneous Fenton degradation of Orange II. The microstructure of the catalysts was characterized by X-ray diffraction (XRD), specific surface area measurements (S_BET), Fourier transform infrared (FTIR) spectroscopy, Raman spectroscopy, and scanning electron microscopy (SEM). The obtained results showed that the pillaring process increased the basal spacing (d₍₀₀₁₎) from 1.24 nm for the Na-bentonite (Bent) to 1.77 nm for the Al-Bent and ~1.72 nm for the Fe-Al pillared bentonites. The S_BET values of the samples were increased after pillaring. It was obvious from the XRD and Raman results that intercalation was not achieved and that hematite was formed in the 20Fe-Al-Bent sample. The influence of Fe content on the degradation of Orange II was investigated. The catalytic activity of pillared bentonites increased with Fe content and hardly increased when the molar ratio of Fe/(Al + Fe) in the pillaring solution exceeded 10% . The decolorization efficiency and chemical oxygen demand (COD_Cr) removal of Orange II reached 100% and 87.73%, respectively, after 4 h oxidation reaction using the 10Fe-Al-Bent sample. It is also proved that the whole decomposition of Orange II by 10Fe-Al-Bent was dominated by heterogeneous Fenton reaction. The catalysts were chemically stable and reusable, with low release of iron.
- Fe-Al pillared bentonite,
- Heterogeneous catalysis,
- Orange II,
- Fenton reaction,
- Degradation
1. [1]
  
  (1) Feng, J. Y.; Hu, X. J.; Yue, P. L. Environ. Sci. Technol. 2004, 38,269. doi: 10.1021/es034515c
2. [2]
  (2) Feng, J. Y.; Hu, X. J.; Yue, P. L. Water Res. 2005, 39, 89. doi: 10.1016/j.watres.2004.08.037
3. [3]
  (3) Chen, J. X.; Zhu, L. Z. Chemosphere 2006, 65, 1249. doi: 10.1016/j.chemosphere.2006.04.016
4. [4]
  (4) Chen, J. X.; Zhu, L. Z. J. Photochem. Photobiol. A 2007, 188,56. doi: 10.1016/j.jphotochem.2006.11.018
5. [5]
  (5) Ramirez, J. H.; Costa, C. A.; Madeira, L. M.; Mata, G.; Vicente,M. A.; Rojas-Cervantes, M. L.; López-Peinado, A. J.; Martín-Aranda, R. M. Appl. Catal. B-Environ. 2007, 71, 44. doi: 10.1016/j.apcatb.2006.08.012
6. [6]
  (6) Liang, X. L.; Zhong, Y. H.; Zhu, S. Y.; Zhu, J. X.; Yuan, P.; He,H. P.; Zhang, J. J. Hazard. Mater. 2010, 181, 112. doi: 10.1016/j.jhazmat.2010.04.101
7. [7]
  (7) Moon, B. H.; Park, Y. B.; Park, K. H. Desalination 2011, 268,249. doi: 10.1016/j.desal.2010.10.036
8. [8]
  (8) Xi, Y. F.; Megharaj, M.; Naidu, R. Appl. Clay Sci. 2011, 53,716. doi: 10.1016/j.clay.2011.06.010
9. [9]
  (9) Chen, L.; Deng, C. Y.;Wu, F.; Deng, N. S. Desalination 2011,281, 306. doi: 10.1016/j.desal.2011.08.006
10. [10]
  (10) Hou, M. F.; Ma, C. X.; Zhang,W. D.; Tang, X. Y.; Fan, Y. N.;Wan, H. F. J. Hazard. Mater. 2011, 186, 1118. doi: 10.1016/j.jhazmat.2010.11.110
11. [11]
  (11) Guélou, E.; Barrault, J.; Fournier, J.; Tatibouët, J. M. Appl. Catal. B-Environ. 2003, 44, 1. doi: 10.1016/S0926-3373(03)00003-1
12. [12]
  (12) Crowther, N.; Larachi, F. Appl. Catal. B-Environ. 2003, 46,293. doi: 10.1016/S0926-3373(03)00224-8
13. [13]
  (13) Zhao, D. Y.; Yang, Y. S.; Guo, X. X.; Chen, H. R.; Xin, Q. Acta Phys. -Chim. Sin. 1993, 9, 336. [赵东源, 杨亚书, 郭燮贤, 陈恒荣, 辛勤. 物理化学学报, 1993, 9, 336.] doi: 10.3866/PKU.WHXB19930311
14. [14]
  (14) Timofeeva, M. N.; Khankhasaeva, S. T.; Badmaeva, S. V.;Chuvilin, A. L.; Burgina, E. B.; Ayupov, A. B.; Panchenko, V.N.; Kulikova, A. V. Appl. Catal. B-Environ. 2005, 59, 243. doi: 10.1016/j.apcatb.2005.01.013
15. [15]
  (15) Sanabria, N.; Álvarez, A.; Molina, R.; Moreno, S. Catal. Today2008, 133-135, 530.
16. [16]
  (16) Luo, M. L.; Bowden, D.; Brimblecombe, P. Appl. Catal. BEnviron.2009, 85, 201. doi: 10.1016/j.apcatb.2008.07.013
17. [17]
  (17) Olaya, A.; Moreno, S.; Molina, R. Appl. Catal. A-Gen. 2009,370, 7. doi: 10.1016/j.apcata.2009.08.018
18. [18]
  (18) Catrinescu, C.; Arsene, D.; Teodosiu, C. Appl. Catal. B-Environ.2011, 101, 451. doi: 10.1016/j.apcatb.2010.10.015
19. [19]
  (19) Catrinescu, C.; Arsene, D.; Apopei, P.; Teodosiu, C. Appl. Clay Sci. 2012, 58, 96. doi: 10.1016/j.clay.2012.01.019
20. [20]
  (20) Bankovi , P.; Milutinovi -Nikoli , A.; Mojovi , Z.; Jovi -Jovi i, N.; uni , M.; Dondur, V.; Jovanovi , D. Appl. Clay Sci.2012, 58, 73. doi: 10.1016/j.clay.2012.01.015
21. [21]
  (21) Timofeeva, M. N.; Khankhasaeva, S. T.; Chesalov, Y. A.;Tsybuly, S. V.; Panchenko, V. N.; Dashinamzhilova, E. T. Appl. Catal. B-Environ. 2009, 88, 127. doi: 10.1016/j.apcatb.2008.09.013
22. [22]
  (22) Chen, F.; Ma,W. H.; He, J. J.; Zhao, J. C. J. Phys. Chem. A2002, 106, 9485. doi: 10.1021/jp0144350
23. [23]
  (23) Kang, Y.W.; Cho, M. J.; Hwang, K. Y. Water Res. 1999, 33,1247. doi: 10.1016/S0043-1354(98)00315-7
24. [24]
  (24) Neam u, M.; Zaharia, C.; Catrinescu, C.; Yediler, A.;Macoveanu, M.; Kettrup, A. Appl. Catal. B-Environ. 2004, 48,287. doi: 10.1016/j.apcatb.2003.11.005
25. [25]
  (25) Carriazo, J. G.; Guelou, E.; Barrault, J.; Tatibouёt, J. M.;Moreno, S. Appl. Clay Sci. 2003, 22, 303. doi: 10.1016/S0169-1317(03)00124-8
26. [26]
  (26) Ksontini, N.; Najjar,W.; Ghorbel, A. J. Phys. Chem. Solids2008, 69, 1112. doi: 10.1016/j.jpcs.2007.10.069
27. [27]
  (27) Zhao, D. Y.; Yang, Y. S.; Guo, X. X.;Wang, G. J. Acta Phys. -Chim. Sin. 1993, 9, 193. [赵东源, 杨亚书, 郭燮贤,王国甲. 物理化学学报, 1993, 9, 193.] doi: 10.3866/PKU.WHXB19930210
28. [28]
  (28) Yuan, P.; He, H. P.; Bergaya, F.;Wu, D. Q.; Zhou, Q.; Zhu, J. X.Microporous Mesoporous Mat. 2006, 88. 8.
29. [29]
  (29) Wu, P.; Komatsu, T.; Yashima, T. Microporous Mesoporous Mat.1998, 20, 139. doi: 10.1016/S1387-1811(97)00005-X
30. [30]
  (30) Frost, R. L.; Rintoul, L. Appl. Clay Sci. 1996, 11, 171. doi: 10.1016/S0169-1317(96)00017-8
31. [31]
  (31) Alia, J. M.; Edwards, H. G. M.; Garcia-Navarro, F. J.; Parras-Armenteros, J.; Sanchez-Jimenez, C. J. Talanta 1999, 50,291. doi: 10.1016/S0039-9140(99)00031-4
32. [32]
  (32) Le di, M. A.;Waal, D. Spectrochim. Acta A 2007, 66, 135. doi: 10.1016/j.saa.2006.02.059
33. [33]
  (33) Faria, D. L. A.; Silva, S. V.; Oliveira, M. T. J. Raman Spectrosc.1997, 28, 873.
34. [34]
  (34) Dong, Y. C.; Du, F.; Han, Z. B. Acta Phys. -Chim. Sin. 2008, 24,2114. [董永春, 杜芳, 韩振邦. 物理化学学报, 2008, 24,2114.] doi: 10.3866/PKU.WHXB20081130
35. [35]
  (35) Mu, Y.; Yu, H. Q.; Zheng, J. C.; Zhang, S. J. J. Photochem. Photobiol. A 2004, 163, 311. doi: 10.1016/j.jphotochem.2003.08.002
36. [36]
  (36) Wang, X. X.; Xu, H. L.; Shen,W.; Ruhlmann, L.; Qin, F.;Sorgues, S.; Colbeau-Justin, C. Acta Phys. -Chim. Sin. 2013, 29,1837. [王晓夏, 徐华龙, 沈伟, RUHLMANN Laurent,秦枫, SORGUES Sébastien, COLBEAU-JUSTIN Christophe.物理化学学报, 2013, 29, 1837.] doi: 10.3866/PKU.WHXB201307024
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