Citation: LI Wen-Zhe, WANG Li-Duo, GAO Rui, DONG Hao-Peng, NIU Guang-Da, GUO Xu-Dong, QIU Yong. Transforming Organic Ligands into a ZnS Protective Layer through the S^2- Intermediate State in ex situ CdSe Quantum Dot Devices[J]. Acta Physico-Chimica Sinica, ;2013, 29(11): 2345-2353. doi: 10.3866/PKU.WHXB201309242 shu

Transforming Organic Ligands into a ZnS Protective Layer through the S^2- Intermediate State in ex situ CdSe Quantum Dot Devices

1.
Key Laboratory of Organic Optoelectronics & Molecular Engineering of Ministry of Education, Department of Chemistry, Tsinghua University, Beijing 100084, P. R. China

Received Date: 8 July 2013
Available Online: 24 September 2013
Fund Project: 国家自然科学基金(51273104) (51273104)国家重点基础研究发展规划项目(973)(2009CB930602)资助 (973)(2009CB930602)

In this paper, the tri-n-octylphosphine oxide (TOPO) ligand on CdSe quantum dots (QDs) are changed to ZnS coating layer through S^2- intermediate state. After ligand exchange, the Fourier transform infrared (FTIR) spectra indicate that the long chain organic ligands are replaced by S^2- ions. After ionic reaction, the generation of ZnS is confirmed by X-ray photoelectron spectroscopy (XPS) measurements. In addition the UV-Vis absorption peaks did not move and transmission electron microscopy (TEM) results show that the diameters of the quantum dots decrease. Electrochemical impedance spectroscopy (EIS) results show that the interface resistance between the TiO₂/QDs/electrolyte is reduced under illumination conditions, meaning that forward electron transport was enhanced. In addition, the intensity-modulated photovoltage spectroscopy (IMVS) and intensity-modulated photocurrent spectroscopy (IMPS) results reveal an increase in the electronic lifetime and diffusion rate increased. Finally, the conversion efficiency increases by 1.78 times from 0.98% (TOPO ligand) to 1.75% (ZnS coating).
- Quantum dot sensitized solar cell,
- Inorganic ligand,
- ZnS coating,
- Ligand exchange,
- Ionic reaction,
- CdSe quantum dot
1. [1]
  
  (1) O′Regan, B.; Grätzel, M. Nature 1991, 353, 737. doi: 10.1038/353737a0
2. [2]
  (2) Yella, A.; Lee, H.W.; Tsao, H. N.; Yi, C.; Chandiran, A. K.;Nazeeruddin, M. K.; Diau, E.W. G.;Yeh, C. Y.; Zakeeruddin, S.M.; Grätzel, M. Science 2011, 334, 629. doi: 10.1126/science.1209688
3. [3]
  (3) Vlachopoulos, N.; Liska, P.; Augustynski, J.; Grätzel, M. J. Am.Chem. Soc. 1988, 110, 1216. doi: 10.1021/ja00212a033
4. [4]
  (4) Watson, D. F. J. Phys. Chem. Lett. 2010, 1, 2299. doi: 10.1021/jz100571u
5. [5]
  (5) Sukhovatkin, V.; Hinds, S.; Brzozowski, L.; Sargent, E. H.Science 2009, 324, 1542. doi: 10.1126/science.1173812
6. [6]
  (6) Gao, R.; Tian, J.; Liang, Z.; Zhang, Q.;Wang, L.; Cao, G.Nanoscale 2013, 5, 1894. doi: 10.1039/c2nr33599a
7. [7]
  (7) Larson, D. R.; Zipfel,W. R.;Williams, R. M.; Clark, S.W.;Bruchez, M. P.;Wise, F.W.;Webb,W.W. Science 2003, 300,1434. doi: 10.1126/science.1083780
8. [8]
  (8) Kim, H.; Jeong, H.; An, T. K.; Park, C. E.; Yong, K. ACS Appl.Mater. Inter. 2012, 5, 268.
9. [9]
  (9) Gao, R.;Wang, L.; Ma, B.; Zhan, C.; Qiu, Y. Langmuir 2009,26, 2460.
10. [10]
  (10) Gao, R.;Wang, L.; Geng, Y.; Ma, B.; Zhu, Y.; Dong, H.; Qiu, Y.Phys. Chem. Chem. Phys. 2011, 13, 10635. doi: 10.1039/c0cp02820g
11. [11]
  (11) Gao, R.;Wang, L.; Geng, Y.; Ma, B.; Zhu, Y.; Dong, H.; Qiu, Y.J. Phys. Chem. C 2011, 115,17986. doi: 10.1021/jp204466h
12. [12]
  (12) Gao, R.; Niu, G.;Wang, L.; Geng, Y.; Ma, B.; Zhu, Y.; Dong,H.; Qiu, Y. Phys. Chem. Chem. Phys. 2012, 14, 5973. doi: 10.1039/c2cp24137d
13. [13]
  (13) Gao, R.; Ma, B. B.;Wang, L. D.; Shi, Y. T.; Dong, H. P.; Qiu, Y.Acta Phys. -Chim. Sin. 2011, 27, 413. [高瑞, 马蓓蓓, 王立铎, 史彦涛, 董豪鹏, 邱勇. 物理化学学报, 2011, 27, 413.]doi: 10.3866/PKU.WHXB20110234
14. [14]
  (14) Dong, H.;Wang, L.; Gao, R.; Ma, B.; Qiu, Y. J. Mater. Chem.2011, 21, 19389. doi: 10.1039/c1jm14191k
15. [15]
  (15) Shen, Q.; Kobayashi, J.; Diguna, L. J.; Toyoda, T. J. Appl. Phys.2008, 103, 084304.
16. [16]
  (16) Shalom, M.; Dor, S.; Ruühle, S.; Grinis, L.; Zaban, A. J. Phys.Chem. C 2009, 113, 3895.
17. [17]
  (17) Choi, H.; Nicolaescu, R.; Paek, S.; Ko, J.; Kamat, P. V. ACSNano 2011, 5, 9238. doi: 10.1021/nn2035022
18. [18]
  (18) Braga, A.; Giménez, S.; Concina, I.; Vomiero, A.; Mora-Seró, I.N. J. Phys. Chem. Lett. 2011, 2, 454. doi: 10.1021/jz2000112
19. [19]
  (19) Ning, Z.; Tian, H.; Qin, H.; Zhang, Q.; Ågren, H.; Sun, L.; Fu,Y. J. Phys. Chem. C 2010, 114, 15184. doi: 10.1021/jp102978g
20. [20]
  (20) Sambur, J. B.; Parkinson, B. A. J. Am. Chem. Soc. 2010, 132,2130. doi: 10.1021/ja9098577
21. [21]
  (21) Zhang, H.; Cheng, K.; Hou, Y. M.; Fang, Z.; Pan, Z. X.;Wu,W.J.; Hua, J. L.; Zhong, X. H. Chem. Commun. 2012, 48, 11235.doi: 10.1039/c2cc36526j
22. [22]
  (22) Deka, S.; Quarta, A.; Luo, M. G.; Falqui, A.; Boninelli, S.;Giannini, C.; Morello, G.; De Giorgi, M.; Lanzani, G.; Spinella,C.; Cin lani, R.; Pellegrino, T.; Manna, L. J. Am. Chem. Soc.2009, 131, 2948. doi: 10.1021/ja808369e
23. [23]
  (23) Xing, G.; Chakrabortty, S.; Ngiam, S.W.; Chan, Y.; Sum, T. C.J. Phys. Chem. C 2011, 115, 17711. doi: 10.1021/jp205238q
24. [24]
  (24) Xia, X.; Liu, Z.; Du, G.; Li, Y.; Ma, M. J. Phys. Chem. C 2010,114, 13414. doi: 10.1021/jp100442v
25. [25]
  (25) Justo, Y.; ris, B.; Kamal, J. S.; Geiregat, P.; Bals, S.; Hens, Z.J. Am. Chem. Soc.2012, 134, 5484. doi: 10.1021/ja300337d
26. [26]
  (26) Pan, Z.; Zhang, H.; Cheng, K.; Hou, Y.; Hua, J.; Zhong, X. ACSNano 2012, 6, 3982. doi: 10.1021/nn300278z
27. [27]
  (27) Murray, C. B.; Norris, D. J.; Bawendi, M. G. J. Am. Chem. Soc.1993, 115, 8706. doi: 10.1021/ja00072a025
28. [28]
  (28) Lee, H. J.; Yum, J. H.; Leventis, H. C.; Zakeeruddin, S. M.;Haque, S. A.; Chen, P.; Seok, S. I.; Graätzel, M.; Nazeeruddin,M. K. J. Phys. Chem. C 2008, 112, 11600. doi: 10.1021/jp802572b
29. [29]
  (29) Dibbell, R. S.; Youker, D. G.;Watson, D. F. J. Phys. Chem. C2009, 113, 18643. doi: 10.1021/jp9079469
30. [30]
  (30) Lokteva, I.; Radychev, N.;Witt, F.; Borchert, H.; Parisi, J. R.;Kolny-Olesiak, J. J. Phys. Chem. C 2010, 114, 12784. doi: 10.1021/jp103300v
31. [31]
  (31) Zillner, E.; Fengler, S.; Niyamakom, P.; Rauscher, F.; Köhler,K.; Dittrich, T. J. Phys. Chem. C 2012, 116, 16747. doi: 10.1021/jp303766d
32. [32]
  (32) Kovalenko, M. V.; Scheele, M.; Talapin, D. V. Science 2009,324, 1417. doi: 10.1126/science.1170524
33. [33]
  (33) Nag, A.; Kovalenko, M. V.; Lee, J. S.; Liu,W.; Spokoyny, B.;Talapin, D. V. J. Am. Chem. Soc. 2011, 133, 10612. doi: 10.1021/ja2029415
34. [34]
  (34) Kovalenko, M. V.; Bodnarchuk, M. I.; Zaumseil, J.; Lee, J. S.;Talapin, D. V. J. Am. Chem. Soc. 2010, 132, 10085. doi: 10.1021/ja1024832
35. [35]
  (35) Kovalenko, M. V.; Bodnarchuk, M. I.; Talapin, D. V. J. Am.Chem. Soc. 2010, 132, 15124. doi: 10.1021/ja106841f
36. [36]
  (36) Abel, K. A.; Qiao, H.; Young, J. F.; van Veggel, F. C. J. M.J. Phys. Chem. Lett. 2010, 1, 2334. doi: 10.1021/jz1007565
37. [37]
  (37) Dworak, L.; Matylitsky, V. V.; Breus, V. V.; Braun, M.; Basché,T.;Wachtveitl, J. J. Phys. Chem. C 2011, 115, 3949. doi: 10.1021/jp111574w
38. [38]
  (38) Jing, P.; Yuan, X.; Ji,W.; Ikezawa, M.;Wang, Y. A.; Liu, X.;Zhang, L.; Zhao, J.; Masumoto, Y. J. Phys. Chem. C 2010, 114,19256. doi: 10.1021/jp107524b
39. [39]
  (39) Kim, S.; Fisher, B.; Eisler, H. J.; Bawendi, M. J. Am. Chem.Soc. 2003, 125, 11466. doi: 10.1021/ja0361749
40. [40]
  (40) Mora-Seró, I. N.; Giménez, S.; Fabregat-Santia , F.; Gómez,R.; Shen, Q.; Toyoda, T.; Bisquert, J. Accounts Chem. Res.2009, 42, 1848. doi: 10.1021/ar900134d
41. [41]
  (41) Samanta, A.; Deng, Z.; Liu, Y. Langmuir 2012, 28, 8205. doi: 10.1021/la300515a
42. [42]
  (42) Wang, H.; Luan, C.; Xu, X.; Kershaw, S. V.; Rogach, A. L.J. Phys. Chem. C 2011, 116, 484.
43. [43]
  (43) Zhong, X.; Feng, Y.; Zhang, Y. J. Phys. Chem. C 2006, 111, 526.
44. [44]
  (44) Vogel, R.; Hoyer, P.;Weller, H. J. Phys. Chem. 1994, 98, 3183.doi: 10.1021/j100063a022
45. [45]
  (45) Niu, G.;Wang, L.; Gao, R.; Ma, B.; Dong, H.; Qiu, Y. J. Mater.Chem. 2012, 22, 16914. doi: 10.1039/c2jm32459h
46. [46]
  (46) Tachan, Z.; Shalom, M.; Hod, I.; Ruühle, S.; Tirosh, S.; Zaban,A. J. Phys. Chem. C 2011, 115, 6162. doi: 10.1021/jp112010m
47. [47]
  (47) Zhang, L.;Wang, Y.; Xu, Z.; Li, H. J. Phys. Chem. B 2009, 113,5978. doi: 10.1021/jp900139z
48. [48]
  (48) Li, H.; Brescia, R.; Krahne, R.; Bertoni, G.; Alcocer, M. J. P.;D′Andrea, C.; Scotognella, F.; Tassone, F.; Zanella, M.; DeGiorgi, M.; Manna, L. ACS Nano 2012, 6, 1637. doi: 10.1021/nn204601n
49. [49]
  (49) Li, H.; Zanella, M.; Genovese, A.; Povia, M.; Falqui, A.;Giannini, C.; Manna, L. Nano Letters 2011, 11, 4964. doi: 10.1021/nl202927a
50. [50]
  (50) Tang, J.; Kemp, K.W.; Hoogland, S.; Jeong, K. S.; Liu, H.;Levina, L.; Furukawa, M.;Wang, X.; Debnath, R.; Cha, D.;Chou, K.W.; Fischer, A.; Amassian, A.; Asbury, J. B.; Sargent,E. H. Nat. Mater. 2011, 10, 765. doi: 10.1038/nmat3118
51. [51]
  (51) Buckley, A. N.;Wouterlood, H. J.;Woods, R. Hydrometallurgy1989, 22, 39. doi: 10.1016/0304-386X(89)90040-6
52. [52]
  (52) Wang, D. H.;Wang, L.; Xu, A.W. Nanoscale 2012, 4, 2046.doi: 10.1039/c2nr11972b
53. [53]
  (53) Gimenez, S.; Mora-Sero, I.; Macor, L.; Guijarro, N.; Lana-Villarreal, T.; mez, R.; Diguna, L. J.; Shen, Q.; Toyoda, T.;Bisquert, J. Nanotechnology 2009, 20, 295204. doi: 10.1088/0957-4484/20/29/295204
54. [54]
  (54) Grätzel, M. Inorg. Chem. 2005, 44, 6841. doi: 10.1021/ic0508371
55. [55]
  (55) Kern, R.; Sastrawan, R.; Ferber, J.; Stangl, R.; Luther, J.Electrochimica Acta 2002, 47, 4213. doi: 10.1016/S0013-4686(02)00444-9
56. [56]
  (56) Stergiopoulos, T.; Karakostas, S.; Falaras, P. J. Photochem.Photobiol. A: Chem. 2004, 163, 331. doi: 10.1016/j.jphotochem.2004.01.002
57. [57]
  (57) Vittadini, A.; Selloni, A.; Rotzinger, F. P.; Grätzel, M. Phys. Rev.Lett. 1998, 81, 2954. doi: 10.1103/PhysRevLett.81.2954
58. [58]
  (58) Schlichthörl, G.; Huang, S. Y.; Sprague, J.; Frank, A. J. J. Phys.Chem. B 1997, 101, 8141. doi: 10.1021/jp9714126
59. [59]
  (59) Krüger, J.; Plass, R.; Grätzel, M.; Cameron, P. J.; Peter, L. M.J. Phys. Chem. B 2003, 107, 7536. doi: 10.1021/jp0348777
60. [60]
  (60) Dloczik, L.; Ileperuma, O.; Lauermann, I.; Peter, L. M.;Ponomarev, E. A.; Redmond, G.; Shaw, N. J.; Uhlendorf, I.J. Phys. Chem. B 1997, 101, 10281. doi: 10.1021/jp972466i
1. [1]
  Miaomiao He , Zhiqing Ge , Qiang Zhou , Jiaqing He , Hong Gong , Lingling Li , Pingping Zhu , Wei Shao . Exploring the Fascinating Realm of Quantum Dots. University Chemistry, 2024, 39(6): 231-237. doi: 10.3866/PKU.DXHX202310040
2. [2]
  Zeyuan WANG , Songzhi ZHENG , Hao LI , Jingbo WENG , Wei WANG , Yang WANG , Weihai SUN . Effect of I₂ interface modification engineering on the performance of all-inorganic CsPbBr₃ perovskite solar cells. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1290-1300. doi: 10.11862/CJIC.20240021
3. [3]
  Jianjun Liu , Xue Yang , Chi Zhang , Xueyu Zhao , Zhiwei Zhang , Yongmei Chen , Qinghong Xu , Shao Jin . Preparation and Fluorescence Characterization of CdTe Semiconductor Quantum Dots. University Chemistry, 2024, 39(7): 307-315. doi: 10.3866/PKU.DXHX202311031
4. [4]
  Zeyu XU , Anlei DANG , Bihua DENG , Xiaoxin ZUO , Yu LU , Ping YANG , Wenzhu YIN . Evaluation of the efficacy of graphene oxide quantum dots as an ovalbumin delivery platform and adjuvant for immune enhancement. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1065-1078. doi: 10.11862/CJIC.20240099
5. [5]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
6. [6]
  Yipeng Zhou , Chenxin Ran , Zhongbin Wu . Metacognitive Enhancement in Diversifying Ideological and Political Education within Graduate Course: A Case Study on “Solar Cell Performance Enhancement Technology”. University Chemistry, 2024, 39(6): 151-159. doi: 10.3866/PKU.DXHX202312096
7. [7]
  Yixuan Gao , Lingxing Zan , Wenlin Zhang , Qingbo Wei . Comprehensive Innovation Experiment: Preparation and Characterization of Carbon-based Perovskite Solar Cells. University Chemistry, 2024, 39(4): 178-183. doi: 10.3866/PKU.DXHX202311091
8. [8]
  Qilu DU , Li ZHAO , Peng NIE , Bo XU . Synthesis and characterization of osmium-germyl complexes stabilized by triphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1088-1094. doi: 10.11862/CJIC.20240006
9. [9]
  Jizhou Liu , Chenbin Ai , Chenrui Hu , Bei Cheng , Jianjun Zhang . 六氯锡酸铵促进钙钛矿太阳能电池界面电子转移及其飞秒瞬态吸收光谱研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2402006-. doi: 10.3866/PKU.WHXB202402006
10. [10]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
11. [11]
  Youlin SI , Shuquan SUN , Junsong YANG , Zijun BIE , Yan CHEN , Li LUO . Synthesis and adsorption properties of Zn(Ⅱ) metal-organic framework based on 3, 3', 5, 5'-tetraimidazolyl biphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1755-1762. doi: 10.11862/CJIC.20240061
12. [12]
  Qilong Fang , Yiqi Li , Jiangyihui Sheng , Quan Yuan , Jie Tan . Magical Pesticide Residue Detection Test Strips: Aptamer-based Lateral Flow Test Strips for Organophosphorus Pesticide Detection. University Chemistry, 2024, 39(5): 80-89. doi: 10.3866/PKU.DXHX202310004
13. [13]
  Wenjun Zheng . Application in Inorganic Synthesis of Ionic Liquids. University Chemistry, 2024, 39(8): 163-168. doi: 10.3866/PKU.DXHX202401020
14. [14]
  Simin Fang , Hong Wu , Wei Liu , Wei Wei , Hongyan Feng , Wan Li . Construction and Application of Teaching Resources for Inorganic and Analytical Chemistry Experimental Course in the Context of Digital Empowerment. University Chemistry, 2024, 39(10): 156-163. doi: 10.3866/PKU.DXHX202402053
15. [15]
  Xinxin JING , Weiduo WANG , Hesu MO , Peng TAN , Zhigang CHEN , Zhengying WU , Linbing SUN . Research progress on photothermal materials and their application in solar desalination. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1033-1064. doi: 10.11862/CJIC.20230371
16. [16]
  Yuanyin Cui , Jinfeng Zhang , Hailiang Chu , Lixian Sun , Kai Dai . Rational Design of Bismuth Based Photocatalysts for Solar Energy Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2405016-. doi: 10.3866/PKU.WHXB202405016
17. [17]
  Siyi ZHONG , Xiaowen LIN , Jiaxin LIU , Ruyi WANG , Tao LIANG , Zhengfeng DENG , Ao ZHONG , Cuiping HAN . Targeting imaging and detection of ovarian cancer cells based on fluorescent magnetic carbon dots. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1483-1490. doi: 10.11862/CJIC.20240093
18. [18]
  Weina Wang , Fengyi Liu , Wenliang Wang . “Extracting Commonality, Delving into Typicals, Deriving Individuality”: Constructing a Knowledge Graph of Crystal Structures. University Chemistry, 2024, 39(3): 36-42. doi: 10.3866/PKU.DXHX202308029
19. [19]
  Liangyu Gong , Jie Wang , Fengyu Du , Lubin Xu , Chuanli Ma , Shihai Yan , Zhuwei Song , Fuheng Liu , Xiuzhong Wang . Construction and Practice of “One-Point, Two-Lines and Three-Sides” Innovative Experimental Platform. University Chemistry, 2024, 39(4): 26-32. doi: 10.3866/PKU.DXHX202308023
20. [20]
  Hongyan Feng , Weiwei Li . Reflections on the Safety of Chemical Science Popularization Activities. University Chemistry, 2024, 39(9): 379-384. doi: 10.12461/PKU.DXHX202404087

Get Citation

PDF

XML

Metrics

PDF Downloads(440)
Abstract views(858)
HTML views(3)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Transforming Organic Ligands into a ZnS Protective Layer through the S2- Intermediate State in ex situ CdSe Quantum Dot Devices

Metrics

通讯作者: 陈斌, bchen63@163.com

Transforming Organic Ligands into a ZnS Protective Layer through the S^2- Intermediate State in ex situ CdSe Quantum Dot Devices