Citation: CHEN Qiang, NULI Yan-Na, YANG Jun, WANG Jiu-Lin, GUO Yu-Guo. PTMA/Graphene as a Novel Cathode Material for Rechargeable Magnesium Batteries[J]. Acta Physico-Chimica Sinica, ;2013, 29(11): 2295-2299. doi: 10.3866/PKU.WHXB201309241 shu

PTMA/Graphene as a Novel Cathode Material for Rechargeable Magnesium Batteries

CHEN Qiang ^1,2 ,
NULI Yan-Na ^1,2, ,
³ ,
YANG Jun ^1,2 ,
WANG Jiu-Lin ^1,2 ,
GUO Yu-Guo ^3,

1.
1 School of Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240, P. R. China;
2 Hirano Institute for Materials Innovation, Shanghai Jiao Tong University, Shanghai 200240, P. R. China;
3 Key Laboratory of Molecular Nanostructures and Nanotechnology, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China

Received Date: 26 June 2013
Available Online: 24 September 2013
Fund Project: 国家自然科学基金(21273147) (21273147)上海市科委(11JC1405700)资助项目 (11JC1405700)

We report the synthesis of a poly(2,2,6,6-tetramethylpiperidinyloxy-4-yl methacrylate) (PTMA)/graphene nanocomposite in which graphene is used as a support for improving electronic conductivity. The structure and morphology of the nanocomposite were characterized by Fourier transform infrared (FTIR) spectroscopy, scanning electron microscopy (SEM), and transmission electron microscopy (TEM). These results reveal that a graphene surface is decorated by nanoparticles of PTMAwith an average size of 10 nm. The electrochemical performance of the PTMA/graphene composite as a cathode material in rechargeable magnesium batteries was investigated using cyclic voltammetry and galvanostatic charge/discharge techniques. In a "first generation" electrolyte Mg(AlCl₂BuEt)₂/tetrahydrofuran (THF) (0.25 mol·L^-1), the material exhibits an initial discharge capacity of 81.2 mAh·g^-1 at 22.8 mA·g^-1. Further studies will focus on improving the capacity using electrolytes with a wider electrochemical window.
- Energy storage and conversion,
- Rechargeable magnesium battery,
- Nanocomposite,
- Organic cathode material,
- Graphene
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