Citation: BAO Zhuo-Ran, CUI Yan-Xi, SUN Peng, SUN Qi, SHI Lei. Vapor-Phase Synthesis of 3-Methylindole from Glycerol and Aniline over Cu/SiO₂-Al₂O₃ Catalyst Modified by Co or Ni[J]. Acta Physico-Chimica Sinica, ;2013, 29(11): 2444-2450. doi: 10.3866/PKU.WHXB201309091 shu

Vapor-Phase Synthesis of 3-Methylindole from Glycerol and Aniline over Cu/SiO₂-Al₂O₃ Catalyst Modified by Co or Ni

1.
Institute of Chemistry for Functionalized Materials, Faculty of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian 116029, Liaoning Province, P. R. China

Received Date: 14 June 2013
Available Online: 9 September 2013
Fund Project: 国家自然科学基金(21173110)资助项目 (21173110)

This paper investigated the vapor-phase synthesis of 3-methylindole from glycerol and aniline over the catalyst of Cu/SiO₂-Al₂O₃ modified by Co or Ni. The catalysts were characterized by N₂ adsorption, H₂ temperature-programmed reduction (H₂-TPR), inductively coupled plasma (ICP) emission spectroscopy, X-ray diffraction (XRD), transmission electron microscopy (TEM), temperature-programmed desorption of ammonia (NH₃-TPD), and thermogravimetric (TG) analysis. The results indicated that adding Co or Ni to Cu/SiO₂-Al₂O₃ improved the performance of the catalyst and Co exhibited higher efficiency than Ni. The yields of 3-methylindole over Cu-Co/SiO₂-Al₂O₃ and Cu-Ni/SiO₂-Al₂O₃ reached 47% and 45%, respectively at the third hour of reaction and the yields remained 44% and 42% after the catalysts were regenerated six times. The characterizations revealed that the addition of Co or Ni to Cu/SiO₂-Al₂O₃ improved the interaction between copper and the support, which promoted the dispersion of Cu particles on the surface of the support, and also prevented the loss of the copper component during the reaction. Furthermore, Co or Ni promoter decreased the amount of the middle-strong acid sites on the catalyst surface, which gave rise to a high selectivity for 3-methylindole, and inhibited the formation of the coke. In addition, Co promoter increased the amount of the weak acid sites on the catalyst, which was favorable for the production of 3-methylindole. Acatalytic mechanism in which copper and weak acid sites acted together to promote the formation of 3-methylindole was proposed.
- Cu/SiO₂-Al₂O₃,
- Cobalt,
- Nickel,
- 3-Methylindole,
- Glycerol,
- Aniline
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沈阳化工大学材料科学与工程学院沈阳 110142

Vapor-Phase Synthesis of 3-Methylindole from Glycerol and Aniline over Cu/SiO2-Al2O3 Catalyst Modified by Co or Ni

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通讯作者: 陈斌, bchen63@163.com

Vapor-Phase Synthesis of 3-Methylindole from Glycerol and Aniline over Cu/SiO₂-Al₂O₃ Catalyst Modified by Co or Ni