Citation: MA Guo-Fu, MU Jing-Jing, ZHANG Zhi-Guo, SUN Kan-Jun, PENG Hui, LEI Zi-Qiang. Preparation of Polypyrrole/Sodium Alginate Nanospheres and Their Application for High-Performance Supercapacitors[J]. Acta Physico-Chimica Sinica, ;2013, 29(11): 2385-2391. doi: 10.3866/PKU.WHXB201309051 shu

Preparation of Polypyrrole/Sodium Alginate Nanospheres and Their Application for High-Performance Supercapacitors

1.
1 Key Laboratory of Eco-Environment-Related Polymer Materials of Ministry of Education, Key Laboratory of Polymer Materials of Gansu Province, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, P. R. China;
2 College of Chemistry and Environmental Science, Lanzhou City University, Lanzhou 730070, P. R. China

Received Date: 27 May 2013
Available Online: 5 September 2013
Fund Project: 国家自然科学基金(21164009,21174114) (21164009,21174114)(IRT1177)资助项目 (IRT1177)

Polypyrrole/sodium alginate (PPy/SA) nanospheres are successfully synthesized by oxidative polymerization of pyrrole using sodium alginate as structural templating agent. The morphology and structure of the PPy/SAnanospheres were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), and Fourier transform infrared (FTIR) spectroscopy. Their electrochemical properties are investigated by cyclic voltammetry (CV) and galvanostatic charge-discharge tests. The PPy/SAnanospheres exhibit a high specific capacitance of 347 F·g^-1 at a charge-discharge current density of 1 A·g^-1 in 1 mol·L^-1 KCl electrolyte. Unlike pure PPy, there was little attenuation in the capacitance of the PPy/SAnanospheres over 500 continuous charging-discharging cycles demonstrating od electrochemical stability. This result indicates that PPy/SAnanospheres are a promising candidate for high-performance supercapacitors.
- Polypyrrole,
- Sodium alginate,
- Nanosphere,
- Supercapacitor,
- Electrode material
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