Citation: SUN Jing-Fang, GE Cheng-Yan, YAO Xiao-Jiang, CAO Yuan, ZHANG Lei, TANG Chang-Jin, DONG Lin. Preparation of NiO/CeO₂ Catalysts by Solid State Impregnation and Their Application in CO Oxidation[J]. Acta Physico-Chimica Sinica, ;2013, 29(11): 2451-2458. doi: 10.3866/PKU.WHXB201309041 shu

Preparation of NiO/CeO₂ Catalysts by Solid State Impregnation and Their Application in CO Oxidation

1.
1 Key Laboratory of Mesoscopic Chemistry of Ministry of Education, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, P. R. China;
2 Jiangsu Key Laboratory of Vehicle Emissions Control, Center of Modern Analysis, Nanjing University, Nanjing 210093, P. R. China

Received Date: 13 May 2013
Available Online: 4 September 2013
Fund Project: 国家自然科学基金项目(21273110) (21273110)江苏省科技工业支撑计划(BE2011167) (BE2011167)厦门大学固体表面物理化学国家重点实验室开放课题(201207)资助 (201207)

NiO/CeO₂ catalysts with different NiO loadings were prepared by a novel solid state impregnation method. The physical and chemical properties of these catalysts were compared with those of catalysts prepared by traditional wet impregnation method. The catalysts were tested for low temperature catalytic CO oxidation and characterized by X-ray diffraction (XRD), N₂ physical adsorption, transmission electron microscopy (TEM), H₂ temperature-programmed reduction (H₂-TPR), Raman spectrum, and X-ray photoelectron spectroscopy (XPS). CO oxidation results showed that nickel-ceria catalysts were od candidates for low temperature CO oxidation, with complete oxidation achieved at temperatures below 200 ℃. The activity of the catalysts increased with nickel loading, and those prepared using the solid state impregnation method displayed higher activities than those prepared by wet impregnation method at the same nickel loading. TEM, XPS, and H₂-TPRresults showed that solid state impregnation increased the dispersion of the nickel species on the surface of catalysts and strengthened the interactions between nickel and cerium, which benefited the reduction of nickel species. Raman results showed that the 0001 concentration of oxygen vacancies in the catalysts could be increased using the solid state impregnation method, likely because of more doped nickel ions in the ceria lattice, which promote the activation of oxygen molecules to facilitate the CO oxidation.
- NiO/CeO₂,
- CO oxidation,
- Solid state impregnation,
- Wet impregnation,
- Interfacial interaction
1. [1]
  
  (1) Zou, H. B.; Dong, X. F.; Lin,W. M. Chem. World 2005, 6, 367.[邹汉波, 董新法, 林维明. 化学世界, 2005, 6, 367.]
2. [2]
  (2) Grisel, R. J. H.; Nieuwenhuys, B. E. J. Catal. 2001, 199, 48.doi: 10.1006/jcat.2000.3121
3. [3]
  (3) Liu, Y.; Meng, M.; Yao, J. S.; Zha, Y. Q. Acta Phys. -Chim. Sin.2007, 23, 641. [刘咏, 孟明, 姚金松, 査宇清. 物理化学学报, 2007, 23, 641.] doi: 10.1016/S1872-1508(07)60041-2
4. [4]
  (4) Yu, J.;Wu, G. S.; Mao, D. S.; Lu, G. Z. Acta Phys. -Chim. Sin.2008, 24, 1751. [俞俊, 吴贵升, 毛东森, 卢冠忠. 物理化学学报, 2008, 24, 1751.] doi: 10.1016/S1872-1508(08)60071-6
5. [5]
  (5) Kaspar, J.; Fornasiero, P.; Graziani, M. Catal. Today 1999, 50 (2), 285. doi: 10.1016/S0920-5861(98)00510-0
6. [6]
  (6) Shan,W. J.; Luo, M. F.; Ying, P. L.; Shen,W. J.; Li, C. Appl. Catal. A: Gen. 2003, 246, 1. doi: 10.1016/S0926-860X(02)00659-2
7. [7]
  (7) Agula, B.; Deng, Q. F.; Jia, M. L.; Liu, Y. P.; Zhaorigetu, B.;Yuan, Z. Y. Reac. Kinet. Mech. Cat. 2011, 103, 101. doi: 10.1007/s11144-011-0296-1
8. [8]
  (8) Zhang, Y.W.;Wang, Z. H.; Zhou, J. H.; Liu, J. Z.; Cen, K. F.Int. J. Hydrog. Energy 2009, 34, 5637. doi: 10.1016/j.ijhydene.2009.05.061
9. [9]
  (9) Yisup, N.; Cao, Y.; Feng,W. L.; Dai,W. L.; Fan, K. N. Catal. Lett. 2005, 99, 207. doi: 10.1007/s10562-005-2121-9
10. [10]
  (10) Ertl, G.; Knozinger, H.; Schuth, F.;Weitkamp, J. Handbook of Heterogenous Catalysis;Wiley-VCH:Weinheim, Germany,2008.
11. [11]
  (11) Jobbagy, M.; Marino, F.; Schonbrod, B.; Baronetti, G.; Laborde,M. Chem. Mater. 2006, 18, 1945. doi: 10.1021/cm052437h
12. [12]
  (12) Schwarz, J. A.; Contescu, C.; Contescu, A. Chem. Rev. 1995, 95,477. doi: 10.1021/cr00035a002
13. [13]
  (13) Wang, Y. M.;Wu, Z. Y.;Wang, H. L.; Zhu, J. H. Adv. Funct. Meter. 2006, 16, 2374.
14. [14]
  (14) Li, X. B.; Quek, X. Y.; Michel Ligthart, D. A. J.; Guo, M. L.;Zhang, Y.; Li, C.; Yang, Q. H.; Hensen, E. J. M. Appl. Catal. B: Environ. 2012, 123, 424.
15. [15]
  (15) Medina-Mendoza, A. K.; Cortés-Jácome, M. A.; Toledo-Antonio, J. A.; Angeles-Chávez, C.; López-Salinas, E.;Cuauhtémoc-López, I.; Barrera, M. C.; Escobar, J.; Navarrete,J.; Hernández, I. Appl. Catal. B: Environ. 2011, 106, 14.
16. [16]
  (16) Lai, S.W.; Chung, D. D. J. Mater. Sci. 1994, 29, 3128. doi: 10.1007/BF00356655
17. [17]
  (17) Liu, J.W.; Zheng, Z. X.;Wang, J. M.;Wu, Y. C.; Tang,W. M.;Lu, J. J. Alloy. Compd. 2008, 465, 239. doi: 10.1016/j.jallcom.2007.10.055
18. [18]
  (18) de Jongh, P. E.;Wagemans, R.W. P.; Eggenhuisen, T. M.;Dauvillier, B. S.; Radstake, P. B.; Meeldijk, J. D.; Geus, J.W.;de Jong, K. P. Chem. Mater. 2007, 19, 6052. doi: 10.1021/cm702205v
19. [19]
  (19) Tang, C. J.; Zhang, H. L.; Sun, C. Z.; Li, J. C.; Qi, L.; Quan, Y.J.; Gao, F.; Dong, L. Catal. Commun. 2011, 12, 1075. doi: 10.1016/j.catcom.2011.03.031
20. [20]
  (20) Tang, C. J.; Sun, J. F.; Yao, X. J.; Cao, Y.; Liu, L. C.; Ge, C. Y.;Gao, F.; Dong, L. Appl. Catal. B: Environ. 2013, doi: 10.1016/j.apcatb.2013.05.060.
21. [21]
  (21) Mohamed, M. M.; Salama, T. M.; Othman, A. I.; El-Shobaky, G.A. Appl. Catal. A: Gen. 2005, 279, 23. doi: 10.1016/j.apcata.2004.09.040
22. [22]
  (22) Barrio, L.; Kubacka, A.; Zhou, G.; Estrella, M.; Martínez-Arias,A.; Hanson, J.C.; Fernández-García, M.; Rodriguez, J. A.J. Phys. Chem. C 2010, 114, 12689. doi: 10.1021/jp103958u
23. [23]
  (23) Guillén-Hurtado, N.; Atribak, I.; Bueno-Lopez, A.; García-García, A. J. Mol. Catal. A: Chem. 2010, 323, 52. doi: 10.1016/j.molcata.2010.03.010
24. [24]
  (24) Li, Y.; Zhang, B. C.; Tang, X. L.; Xu, Y. D.; Shen,W. J. Catal. Commun. 2006, 7, 380. doi: 10.1016/j.catcom.2005.12.002
25. [25]
  (25) Wang, Y.; Zhu, A. M.; Zhang, Y. Z.; Au, C. T.; Yang, X. F. Shi,C. Appl. Catal. B: Environ. 2008, 1, 141.
26. [26]
  (26) Wu, Z. L.; Li, M. J.; Howe, J. Langmuir 2010, 26 (21), 16595.doi: 10.1021/la101723w
27. [27]
  (27) Du, X. J.; Zhang, D. S.; Shi, L. Y.; Gao, R. H.; Zhang, J. P.J. Phys. Chem. C 2012, 116, 10009. doi: 10.1021/jp300543r
28. [28]
  (28) Lin, J.; Li, L.; Huang, Y. Q.; Zhang,W. S.;Wang, X. D.;Wang,A. Q.; Zhang, T. J. Phys. Chem. C 2011, 115, 16509. doi: 10.1021/jp204288h
29. [29]
  (29) Chen, C. S.; Lin, J. H.; You, J. H.; Yang, K. H. J. Phys. Chem. A2010, 114, 3773. doi: 10.1021/jp904434e
30. [30]
  (30) Alifanti, M.; Baps, B. Blangenois, N.; Naud, J.; Grange, P.;Delmon, B. Chem. Mater. 2003, 15, 395. doi: 10.1021/cm021274j
31. [31]
  (31) Yao, X. J.; Yu, Q.; Ji, Z. Y.; Lv, Y. Y.; Cao, Y.; Jin, C. T.; Gao, F.;Dong, L. Appl. Catal. B: Environ. 2013, 130-131, 293.
32. [32]
  (32) Liu, X.W.; Zhou, K.;Wang, L.;Wang, B.; Li, Y. J. J. Am. Chem. Soc. 2009, 131, 3140. doi: 10.1021/ja808433d
33. [33]
  (33) Luo, M. F.; Song, Y. P.; Lu, J. Q.;Wang, X. Y.; Pu, Z. Y. J. Phys. Chem. C 2007, 111, 12686. doi: 10.1021/jp0733217
1. [1]
  Xiutao Xu , Chunfeng Shao , Jinfeng Zhang , Zhongliao Wang , Kai Dai . Rational Design of S-Scheme CeO₂/Bi₂MoO₆ Microsphere Heterojunction for Efficient Photocatalytic CO₂ Reduction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309031-. doi: 10.3866/PKU.WHXB202309031
2. [2]
  Hailian Tang , Siyuan Chen , Qiaoyun Liu , Guoyi Bai , Botao Qiao , Fei Liu . Stabilized Rh/hydroxyapatite Catalyst for Furfuryl Alcohol Hydrogenation: Application of Oxidative Strong Metal-Support Interactions in Reducing Conditions. Acta Physico-Chimica Sinica, 2025, 41(4): 100036-. doi: 10.3866/PKU.WHXB202408004
3. [3]
  Hui Shi , Shuangyan Huan , Yuzhi Wang . Ideological and Political Design of Potassium Permanganate Oxidation-Reduction Titration Experiment. University Chemistry, 2024, 39(2): 175-180. doi: 10.3866/PKU.DXHX202308042
4. [4]
  Jiaxun Wu , Mingde Li , Li Dang . The R eaction of Metal Selenium Complexes with Olefins as a Tutorial Case Study for Analyzing Molecular Orbital Interaction Modes. University Chemistry, 2025, 40(3): 108-115. doi: 10.12461/PKU.DXHX202405098
5. [5]
  Huiying Xu , Minghui Liang , Zhi Zhou , Hui Gao , Wei Yi . Application of Quantum Chemistry Computation and Visual Analysis in Teaching of Weak Interactions. University Chemistry, 2025, 40(3): 199-205. doi: 10.12461/PKU.DXHX202407011
6. [6]
  Gang Lang , Jing Feng , Bo Feng , Junlan Hu , Zhiling Ran , Zhiting Zhou , Zhenju Jiang , Yunxiang He , Junling Guo . Supramolecular phenolic network-engineered C–CeO₂ nanofibers for simultaneous determination of isoniazid and hydrazine in biological fluids. Chinese Chemical Letters, 2024, 35(6): 109113-. doi: 10.1016/j.cclet.2023.109113
7. [7]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
8. [8]
  Zhi Zhu , Xiaohan Xing , Qi Qi , Wenjing Shen , Hongyue Wu , Dongyi Li , Binrong Li , Jialin Liang , Xu Tang , Jun Zhao , Hongping Li , Pengwei Huo . Fabrication of graphene modified CeO2/g-C3N4 heterostructures for photocatalytic degradation of organic pollutants. Chinese Journal of Structural Chemistry, 2023, 42(12): 100194-100194. doi: 10.1016/j.cjsc.2023.100194
9. [9]
  Simin Wei , Yaqing Yang , Junjie Li , Jialin Wang , Jinlu Tang , Ningning Wang , Zhaohui Li . The Mn/Yb/Er triple-doped CeO₂ nanozyme with enhanced oxidase-like activity for highly sensitive ratiometric detection of nitrite. Chinese Chemical Letters, 2024, 35(6): 109114-. doi: 10.1016/j.cclet.2023.109114
10. [10]
  Chenye An , Abiduweili Sikandaier , Xue Guo , Yukun Zhu , Hua Tang , Dongjiang Yang . 红磷纳米颗粒嵌入花状CeO₂分级S型异质结高效光催化产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2405019-. doi: 10.3866/PKU.WHXB202405019
11. [11]
  Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . 层状双金属氢氧化物的层间阴离子对衍生的Ni-Al₂O₃催化剂光热催化CO₂甲烷化反应的影响. Acta Physico-Chimica Sinica, 2025, 41(1): 2309002-. doi: 10.3866/PKU.WHXB202309002
12. [12]
  Zunxiang Zeng , Yuling Hu , Yufei Hu , Hua Xiao . Analysis of Plant Essential Oils by Supercritical CO₂Extraction with Gas Chromatography-Mass Spectrometry: An Instrumental Analysis Comprehensive Experiment Teaching Reform. University Chemistry, 2024, 39(3): 274-282. doi: 10.3866/PKU.DXHX202309069
13. [13]
  Zhenlin Zhou , Siyuan Chen , Yi Liu , Chengguo Hu , Faqiong Zhao . A New Program of Voltammetry Experiment Teaching Based on Laser-Scribed Graphene Electrode. University Chemistry, 2024, 39(2): 358-370. doi: 10.3866/PKU.DXHX202308049
14. [14]
  Feng Liang , Desheng Li , Yuting Jiang , Jiaxin Dong , Dongcheng Liu , Xingcan Shen . Method Exploration and Instrument Innovation for the Experiment of Colloid ζ Potential Measurement by Electrophoresis. University Chemistry, 2024, 39(5): 345-353. doi: 10.3866/PKU.DXHX202312009
15. [15]
  Wei Peng , Baoying Wen , Huamin Li , Yiru Wang , Jianfeng Li . Exploration and Practice on Raman Scattering Spectroscopy Experimental Teaching. University Chemistry, 2024, 39(8): 230-240. doi: 10.3866/PKU.DXHX202312062
16. [16]
  Yujia Luo , Yunpeng Qi , Huiping Xing , Yuhu Li . The Use of Viscosity Method for Predicting the Life Expectancy of Xuan Paper-based Heritage Objects. University Chemistry, 2024, 39(8): 290-294. doi: 10.3866/PKU.DXHX202401037
17. [17]
  Tiejun Su . The Construction and Application of the Calculation Formula for Endpoint Error in Precipitation Titration: A Case Study of the Mohr Method. University Chemistry, 2024, 39(11): 384-387. doi: 10.12461/PKU.DXHX202402039
18. [18]
  Chongjing Liu , Yujian Xia , Pengjun Zhang , Shiqiang Wei , Dengfeng Cao , Beibei Sheng , Yongheng Chu , Shuangming Chen , Li Song , Xiaosong Liu . Understanding Solid-Gas and Solid-Liquid Interfaces through Near Ambient Pressure X-Ray Photoelectron Spectroscopy. Acta Physico-Chimica Sinica, 2025, 41(2): 100013-. doi: 10.3866/PKU.WHXB202309036
19. [19]
  Yanhui Zhong , Ran Wang , Zian Lin . Analysis of Halogenated Quinone Compounds in Environmental Water by Dispersive Solid-Phase Extraction with Liquid Chromatography-Triple Quadrupole Mass Spectrometry. University Chemistry, 2024, 39(11): 296-303. doi: 10.12461/PKU.DXHX202402017
20. [20]
  Chunai Dai , Yongsheng Han , Luting Yan , Zhen Li , Yingze Cao . Ideological and Political Design of Solid-liquid Contact Angle Measurement Experiment. University Chemistry, 2024, 39(2): 28-33. doi: 10.3866/PKU.DXHX202306065

Get Citation

PDF

XML

Metrics

PDF Downloads(629)
Abstract views(664)
HTML views(3)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation of NiO/CeO2 Catalysts by Solid State Impregnation and Their Application in CO Oxidation

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation of NiO/CeO₂ Catalysts by Solid State Impregnation and Their Application in CO Oxidation