Citation: SUN Jing-Fang, GE Cheng-Yan, YAO Xiao-Jiang, CAO Yuan, ZHANG Lei, TANG Chang-Jin, DONG Lin. Preparation of NiO/CeO₂ Catalysts by Solid State Impregnation and Their Application in CO Oxidation[J]. Acta Physico-Chimica Sinica, ;2013, 29(11): 2451-2458. doi: 10.3866/PKU.WHXB201309041 shu

Preparation of NiO/CeO₂ Catalysts by Solid State Impregnation and Their Application in CO Oxidation

1.
1 Key Laboratory of Mesoscopic Chemistry of Ministry of Education, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, P. R. China;
2 Jiangsu Key Laboratory of Vehicle Emissions Control, Center of Modern Analysis, Nanjing University, Nanjing 210093, P. R. China

Received Date: 13 May 2013
Available Online: 4 September 2013
Fund Project: 国家自然科学基金项目(21273110) (21273110)江苏省科技工业支撑计划(BE2011167) (BE2011167)厦门大学固体表面物理化学国家重点实验室开放课题(201207)资助 (201207)

NiO/CeO₂ catalysts with different NiO loadings were prepared by a novel solid state impregnation method. The physical and chemical properties of these catalysts were compared with those of catalysts prepared by traditional wet impregnation method. The catalysts were tested for low temperature catalytic CO oxidation and characterized by X-ray diffraction (XRD), N₂ physical adsorption, transmission electron microscopy (TEM), H₂ temperature-programmed reduction (H₂-TPR), Raman spectrum, and X-ray photoelectron spectroscopy (XPS). CO oxidation results showed that nickel-ceria catalysts were od candidates for low temperature CO oxidation, with complete oxidation achieved at temperatures below 200 ℃. The activity of the catalysts increased with nickel loading, and those prepared using the solid state impregnation method displayed higher activities than those prepared by wet impregnation method at the same nickel loading. TEM, XPS, and H₂-TPRresults showed that solid state impregnation increased the dispersion of the nickel species on the surface of catalysts and strengthened the interactions between nickel and cerium, which benefited the reduction of nickel species. Raman results showed that the 0001 concentration of oxygen vacancies in the catalysts could be increased using the solid state impregnation method, likely because of more doped nickel ions in the ceria lattice, which promote the activation of oxygen molecules to facilitate the CO oxidation.
- NiO/CeO₂,
- CO oxidation,
- Solid state impregnation,
- Wet impregnation,
- Interfacial interaction
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Preparation of NiO/CeO2 Catalysts by Solid State Impregnation and Their Application in CO Oxidation

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Preparation of NiO/CeO₂ Catalysts by Solid State Impregnation and Their Application in CO Oxidation