Citation:
JIAO Yi, QIN Li-Xiao, LI Xiong-Jian, WANG Jia, WANG Jian-Li, ZHU Quan, LI Xiang-Yuan, CHEN Yao-Qiang. Influence of Adding Zr0.5Ti0.5O2 on the Performance of Supercritical Cracking Catalyst for RP-3[J]. Acta Physico-Chimica Sinica,
;2013, 29(10): 2255-2262.
doi:
10.3866/PKU.WHXB201308271
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Zr0.5Ti0.5O2 was prepared by co-precipitation and tested for its catalytic performance under supercritical conditions when mixed with a CeO2-Al2O3 (CA) base catalyst. The catalysts were characterized with an automatic adsorption instrument (BET method), X-ray diffraction (XRD), transmission electron microscopy (TEM), and temperature programmed desorption (TPD). It was found that Zr0.5Ti0.5O2 significantly lowered the temperature of the cracking reaction, and increased the thermal cracking gas rate by a factor of 2.8 times as large as that at 600 ℃ for the CAbase catalyst. The gas rate was increased by a factor of 4.0 times when it was doped into the CAbase catalyst, and the heat sink increased by 0.55 MJ·kg-1 over that of thermal cracking at 650 ℃. BET results show that the Zr0.5Ti0.5O2-doped CAbase catalyst has a double-pore structure that enhances ethylene selectivity. NH3-TPD result indicates that the acidity of the catalyst increased by 4.0 times, indicating improved surface acidity conducive to alkene generation.
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[1]
(1) Edwards, T. J. Propul. Power 2003, 19, 1089. doi: 10.2514/2.6946
-
[2]
(2) Kay, I. W.; Peschke, W. T. J. Propul. Power 1992, 18 (2), 507.
-
[3]
(3) Lander, H. R.; Nixon, A. C. ACS Div. Pet. Chem. 1987, 32, 504.
-
[4]
(4) Lander, H.; Nixon, A. C. J. Aircraft. 1971, 8, 200. doi: 10.2514/3.44255
-
[5]
(5) Wickham, D. T.; Atria, J. V.; Engel, J. R.; Hitch, B. D.; Karpuk,M. E.; Striebich, R. ACS Div. Pet. Chem. 1998, 43, 428.
-
[6]
(6) Buchanan, J. S. Catal.Today 2000, 55, 207. doi: 10.1016/S0920-5861(99)00248-5
-
[7]
(7) Edwards, T. ACS Div. Pet. Chem. 2000, 45, 436.
-
[8]
(8) Wickham, D. T.; Engel, J. R.; Hitch, B. D. J. Propul. Power2001, 17, 1253. doi: 10.2514/2.5872
-
[9]
(9) Wickham, D. T. Methods for Suppression of Filamentous CokeFormation. US Patent 6 482 311 B1, 2002, 2003-03-07
-
[10]
(10) F?rcasiu, D.; Le, K. H. Catal. Commun 2001, 2, 5.
-
[11]
(11) Zhao, G. L.; Teng, J. W.; Xie, Z. Stud. Surf. Sci. Catal. 2007,1307.
-
[12]
(12) Dimitris, K. L.; David, T. A. Ind. Eng. Chem. Res. 1992, 31,45. doi: 10.1021/ie00001a007
-
[13]
(13) Tsai, T. C.; Kung, H. Y.; Yu, S. T. Appl. Catal. A 1989, 50, 1.doi: 10.1016/S0166-9834(00)80820-9
-
[14]
(14) Benjaram, M. R.; Biswajit, C.; Panagiotis, G. S. Appl. Catal. A: Gen. 2001, 211, 19. doi: 10.1016/S0926-860X(00)00834-6
-
[15]
(15) Benjaram, M. R.; Ataullah, K. Catal. Rev. 2005, 47, 257. doi: 10.1081/CR-200057488
-
[16]
(16) Ma, Z. Y.; Xu, R.; Yang, C. Acta Phys. -Chim. Sin. 2004, 20,1221. [马中义,徐润,杨成.物理化学学报, 2004, 20,1221.] doi: 10.3866/PKU.WHXB20041011
-
[17]
(17) Naoki, T.; Akihiko, S.; Ichiro, H. Appl. Catal. B-Environ. 2007,72, 187. doi: 10.1016/j.apcatb.2006.10.014
-
[18]
(18) Han, C. H.; Liu, B. H.; Zhang, H. L. Acta Phys. -Chim. Sin.2006, 22, 993. [韩承辉,刘炳华, 张惠良.物理化学学报,2006, 22, 993.] doi: 10.1016/S1872-1508(06)60044-2
-
[19]
(19) Das, D.; Mishra, H. K.; Parida, K. M. J. Mol. Catal. A: Chem.2002, 189, 271. doi: 10.1016/S1381-1169(02)00363-1
-
[20]
(20) Colón, G.; Hidal , M. C.; Navo, J. A. Appl. Catal. A: Gen.2002, 23, 185.
-
[21]
(21) Oi-Uchisawa, J.; Wang, S. D.; Nanba, T. Appl. Catal. B-Environ.2003, 203, 207.
-
[22]
(22) Matsumoto, S.; Ikeda, Y.; Suzuki, H. Appl. Catal. B-Environ.2000, 25, 115. doi: 10.1016/S0926-3373(99)00124-1
-
[23]
(23) Laniecki, I. M.; MaLecka, G. M.; Domka, F. Appl. Catal. A: Gen. 2000, 196, 293. doi: 10.1016/S0926-860X(99)00480-9
-
[24]
(24) Mao, D. S.; Lu, G. Z.; Chen, Q. L. Chin. J. Catal. 2004, 25,501. [毛东森, 卢冠忠,陈庆龄. 催化学报, 2004, 25, 501.]
-
[25]
(25) Yu, Y.; Lin, T.; Zhang, L. J.; Guo, J. X.; ng, M. C.; Chen, Y.Q. J. Inorg. Meter. 2003, 23, 71. [喻瑶,林涛,张丽娟,郭家秀, 龚茂初, 陈耀强. 无机材料学报, 2003, 23, 71.]
-
[26]
(26) Fu, X. C.; Shen, W. X.; Yao, T. Y.; Hou, W. H. Physical Chemistry; Higher Education Press: Beijing, 2006; pp 191-197.[傅献彩, 沈文霞, 姚天扬, 侯文华.物理化学.北京:高等教育出版社, 2006: 191-197.]
-
[27]
(27) Jiao, Y.; Li, J.; Wang, J. B.;Wang, J. L.; Zhu, Q.; Chen, Y. Q.; Li,X. Y. Acta Phys. -Chim. Sin. 2011, 27, 1061. [焦毅,李军,王静波,王健礼,朱权,陈耀强, 李象远.物理化学学报,2011, 27, 1061.] doi: 10.3866/PKU.WHXB20110437
-
[28]
(28) Wang, Z. W.; Zhang, X. W.; Mi, Z. T.; Hao, W. H. Petrochem. Technol. 2005, 6, 518. [王占卫, 张香文,米镇涛, 郝伟华.石油化工, 2005, 6, 518.]
-
[29]
(29) F?rcasiu, D.; Vargas, W.; Lee, K. H. Catal. Commun 2003, 4, 63.
-
[30]
(30) Babitz, S. M.; Williams, J. T.; Miller, R. Q. Appl. Catal. A: Gen.1999, 179, 71. doi: 10.1016/S0926-860X(98)00301-9
-
[31]
(31) Nie, R. F.; Wang, J. H.; Fei, J. H.; Hou, Z. Y.; Zheng, X. M.Chin. J. Catal. 2011, 32, 379. [聂仁峰,王军华,费金华, 侯昭胤, 郑小明. 催化学报, 2011, 32, 379.]
-
[32]
(32) Sobel, D. R.; Spadaccini, L. J. J. Eng. Gas. Turb. Power 1997,119, 344. doi: 10.1115/1.2815581
-
[33]
(33) Zhang, L. J.; Dong, W. P.; Guo, J. X.; Yuan, S. H.; Zhang, L.; ng, M. C.; Chen, Y. Q. Acta Phys. -Chim. Sin. 2007, 23,1738. [张丽娟, 董文萍, 郭家秀, 袁书华,张磊,龚茂初,陈耀强. 物理化学学报, 2007, 23, 1738.] doi: 10.3866/PKU.WHXB20071116
-
[34]
(34) Leofanti, G.; Padovan, M.; Tozzola, G.; Venturelli, B. Catal. Today 1998, 41, 207. doi: 10.1016/S0920-5861(98)00050-9
-
[35]
(35) Deraz, N. M. Ceram. Trans. 2012, 38, 747.
-
[36]
(36) Lin, T.; Li, W.; ng, M. C.; Yu, Y.; Du, B.; Chen, Y. Q. Acta Phys. -Chim. Sin. 2007, 23, 1851. [林涛,李伟,龚茂初,喻瑶,杜波,陈耀强. 物理化学学报, 2007, 23, 1851.] doi: 10.1016/S1872-1508(07)60089-8
-
[37]
(37) Lin, T.; Zhang, Q. L.; Li, W.; ng, M. C.; Xing, Y. X.; Chen, Y.Q. Acta Phys. -Chim. Sin. 2008, 24, 1127. [林涛,张秋林,李伟,龚茂初,幸怡汛, 陈耀强.物理化学学报, 2008, 24,1127.] doi: 10.1016/S1872-1508(08)60046-7
-
[38]
(38) Mao, D. S.; Lu, G. Z.; Chen, Q. L.; Xie, Z. K.; Zhang, Y. X.Chin. J. Catal. 2002, 23, 9. [毛东森, 卢冠忠,陈庆龄, 谢在库, 张玉贤.催化学报, 2002, 23, 9.]
-
[39]
(39) Mao, D. S.; Lu, G. Z.; Chen, Q. L.; Xie, Z. K.; Zhang, Y. X.Catal. Lett. 2001, 77, 119. doi: 10.1023/A:1012787028360
-
[40]
(40) Wang, J. L.; Wang, K. C.; Cao, H. Y.; Chen, Y. D.; Liu, Z. M.;Zhu, Y.; ng, M. C.; Chen, Y. Q. Acta Phys. -Chim. Sin. 2009,25, 689. [王健礼,王康才, 曹红岩,陈永东,刘志敏,朱艺,龚茂初, 陈耀强.物理化学学报, 2009, 25, 689.] doi: 10.3866/PKU.WHXB200904211
-
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