Citation: JIAO Yi, QIN Li-Xiao, LI Xiong-Jian, WANG Jia, WANG Jian-Li, ZHU Quan, LI Xiang-Yuan, CHEN Yao-Qiang. Influence of Adding Zr_0.5Ti_0.5O₂ on the Performance of Supercritical Cracking Catalyst for RP-3[J]. Acta Physico-Chimica Sinica, ;2013, 29(10): 2255-2262. doi: 10.3866/PKU.WHXB201308271 shu

Influence of Adding Zr_0.5Ti_0.5O₂ on the Performance of Supercritical Cracking Catalyst for RP-3

1.
1 Key Laboratory of Green Chemistry and Technology of the Ministry of Education, College of Chemistry, Sichuan University, Chengdu 610064, P. R. China;
2 College of Chemical Engineering, Sichuan University, Chengdu 610064, P. R. China

Received Date: 18 June 2013
Available Online: 27 August 2013
Fund Project: 国家自然科学基金(91016002) (91016002)四川大学优秀青年学者科研基金(2013SCU04A05) (2013SCU04A05)国家高技术研究发展计划项目(863)(2006AA01A119) (863)(2006AA01A119)高超声速冲压发动机技术重点实验室开放基金(20120103013)资助 (20120103013)

Zr_0.5Ti_0.5O₂ was prepared by co-precipitation and tested for its catalytic performance under supercritical conditions when mixed with a CeO₂-Al₂O₃ (CA) base catalyst. The catalysts were characterized with an automatic adsorption instrument (BET method), X-ray diffraction (XRD), transmission electron microscopy (TEM), and temperature programmed desorption (TPD). It was found that Zr_0.5Ti_0.5O₂ significantly lowered the temperature of the cracking reaction, and increased the thermal cracking gas rate by a factor of 2.8 times as large as that at 600 ℃ for the CAbase catalyst. The gas rate was increased by a factor of 4.0 times when it was doped into the CAbase catalyst, and the heat sink increased by 0.55 MJ·kg^-1 over that of thermal cracking at 650 ℃. BET results show that the Zr_0.5Ti_0.5O₂-doped CAbase catalyst has a double-pore structure that enhances ethylene selectivity. NH3-TPD result indicates that the acidity of the catalyst increased by 4.0 times, indicating improved surface acidity conducive to alkene generation.
- Endothermic fuel,
- ZrO₂-TiO₂ composite oxide,
- Supercritical,
- Catalytic cracking,
- Heat sink
1. [1]
  
  (1) Edwards, T. J. Propul. Power 2003, 19, 1089. doi: 10.2514/2.6946
2. [2]
  (2) Kay, I. W.; Peschke, W. T. J. Propul. Power 1992, 18 (2), 507.
3. [3]
  (3) Lander, H. R.; Nixon, A. C. ACS Div. Pet. Chem. 1987, 32, 504.
4. [4]
  (4) Lander, H.; Nixon, A. C. J. Aircraft. 1971, 8, 200. doi: 10.2514/3.44255
5. [5]
  (5) Wickham, D. T.; Atria, J. V.; Engel, J. R.; Hitch, B. D.; Karpuk,M. E.; Striebich, R. ACS Div. Pet. Chem. 1998, 43, 428.
6. [6]
  (6) Buchanan, J. S. Catal.Today 2000, 55, 207. doi: 10.1016/S0920-5861(99)00248-5
7. [7]
  (7) Edwards, T. ACS Div. Pet. Chem. 2000, 45, 436.
8. [8]
  (8) Wickham, D. T.; Engel, J. R.; Hitch, B. D. J. Propul. Power2001, 17, 1253. doi: 10.2514/2.5872
9. [9]
  (9) Wickham, D. T. Methods for Suppression of Filamentous CokeFormation. US Patent 6 482 311 B1, 2002, 2003-03-07
10. [10]
  (10) F?rcasiu, D.; Le, K. H. Catal. Commun 2001, 2, 5.
11. [11]
  (11) Zhao, G. L.; Teng, J. W.; Xie, Z. Stud. Surf. Sci. Catal. 2007,1307.
12. [12]
  (12) Dimitris, K. L.; David, T. A. Ind. Eng. Chem. Res. 1992, 31,45. doi: 10.1021/ie00001a007
13. [13]
  (13) Tsai, T. C.; Kung, H. Y.; Yu, S. T. Appl. Catal. A 1989, 50, 1.doi: 10.1016/S0166-9834(00)80820-9
14. [14]
  (14) Benjaram, M. R.; Biswajit, C.; Panagiotis, G. S. Appl. Catal. A: Gen. 2001, 211, 19. doi: 10.1016/S0926-860X(00)00834-6
15. [15]
  (15) Benjaram, M. R.; Ataullah, K. Catal. Rev. 2005, 47, 257. doi: 10.1081/CR-200057488
16. [16]
  (16) Ma, Z. Y.; Xu, R.; Yang, C. Acta Phys. -Chim. Sin. 2004, 20,1221. [马中义,徐润,杨成.物理化学学报, 2004, 20,1221.] doi: 10.3866/PKU.WHXB20041011
17. [17]
  (17) Naoki, T.; Akihiko, S.; Ichiro, H. Appl. Catal. B-Environ. 2007,72, 187. doi: 10.1016/j.apcatb.2006.10.014
18. [18]
  (18) Han, C. H.; Liu, B. H.; Zhang, H. L. Acta Phys. -Chim. Sin.2006, 22, 993. [韩承辉,刘炳华, 张惠良.物理化学学报,2006, 22, 993.] doi: 10.1016/S1872-1508(06)60044-2
19. [19]
  (19) Das, D.; Mishra, H. K.; Parida, K. M. J. Mol. Catal. A: Chem.2002, 189, 271. doi: 10.1016/S1381-1169(02)00363-1
20. [20]
  (20) Colón, G.; Hidal , M. C.; Navo, J. A. Appl. Catal. A: Gen.2002, 23, 185.
21. [21]
  (21) Oi-Uchisawa, J.; Wang, S. D.; Nanba, T. Appl. Catal. B-Environ.2003, 203, 207.
22. [22]
  (22) Matsumoto, S.; Ikeda, Y.; Suzuki, H. Appl. Catal. B-Environ.2000, 25, 115. doi: 10.1016/S0926-3373(99)00124-1
23. [23]
  (23) Laniecki, I. M.; MaLecka, G. M.; Domka, F. Appl. Catal. A: Gen. 2000, 196, 293. doi: 10.1016/S0926-860X(99)00480-9
24. [24]
  (24) Mao, D. S.; Lu, G. Z.; Chen, Q. L. Chin. J. Catal. 2004, 25,501. [毛东森, 卢冠忠,陈庆龄. 催化学报, 2004, 25, 501.]
25. [25]
  (25) Yu, Y.; Lin, T.; Zhang, L. J.; Guo, J. X.; ng, M. C.; Chen, Y.Q. J. Inorg. Meter. 2003, 23, 71. [喻瑶,林涛,张丽娟,郭家秀, 龚茂初, 陈耀强. 无机材料学报, 2003, 23, 71.]
26. [26]
  (26) Fu, X. C.; Shen, W. X.; Yao, T. Y.; Hou, W. H. Physical Chemistry; Higher Education Press: Beijing, 2006; pp 191-197.[傅献彩, 沈文霞, 姚天扬, 侯文华.物理化学.北京:高等教育出版社, 2006: 191-197.]
27. [27]
  (27) Jiao, Y.; Li, J.; Wang, J. B.;Wang, J. L.; Zhu, Q.; Chen, Y. Q.; Li,X. Y. Acta Phys. -Chim. Sin. 2011, 27, 1061. [焦毅,李军,王静波,王健礼,朱权,陈耀强, 李象远.物理化学学报,2011, 27, 1061.] doi: 10.3866/PKU.WHXB20110437
28. [28]
  (28) Wang, Z. W.; Zhang, X. W.; Mi, Z. T.; Hao, W. H. Petrochem. Technol. 2005, 6, 518. [王占卫, 张香文,米镇涛, 郝伟华.石油化工, 2005, 6, 518.]
29. [29]
  (29) F?rcasiu, D.; Vargas, W.; Lee, K. H. Catal. Commun 2003, 4, 63.
30. [30]
  (30) Babitz, S. M.; Williams, J. T.; Miller, R. Q. Appl. Catal. A: Gen.1999, 179, 71. doi: 10.1016/S0926-860X(98)00301-9
31. [31]
  (31) Nie, R. F.; Wang, J. H.; Fei, J. H.; Hou, Z. Y.; Zheng, X. M.Chin. J. Catal. 2011, 32, 379. [聂仁峰,王军华,费金华, 侯昭胤, 郑小明. 催化学报, 2011, 32, 379.]
32. [32]
  (32) Sobel, D. R.; Spadaccini, L. J. J. Eng. Gas. Turb. Power 1997,119, 344. doi: 10.1115/1.2815581
33. [33]
  (33) Zhang, L. J.; Dong, W. P.; Guo, J. X.; Yuan, S. H.; Zhang, L.; ng, M. C.; Chen, Y. Q. Acta Phys. -Chim. Sin. 2007, 23,1738. [张丽娟, 董文萍, 郭家秀, 袁书华,张磊,龚茂初,陈耀强. 物理化学学报, 2007, 23, 1738.] doi: 10.3866/PKU.WHXB20071116
34. [34]
  (34) Leofanti, G.; Padovan, M.; Tozzola, G.; Venturelli, B. Catal. Today 1998, 41, 207. doi: 10.1016/S0920-5861(98)00050-9
35. [35]
  (35) Deraz, N. M. Ceram. Trans. 2012, 38, 747.
36. [36]
  (36) Lin, T.; Li, W.; ng, M. C.; Yu, Y.; Du, B.; Chen, Y. Q. Acta Phys. -Chim. Sin. 2007, 23, 1851. [林涛,李伟,龚茂初,喻瑶,杜波,陈耀强. 物理化学学报, 2007, 23, 1851.] doi: 10.1016/S1872-1508(07)60089-8
37. [37]
  (37) Lin, T.; Zhang, Q. L.; Li, W.; ng, M. C.; Xing, Y. X.; Chen, Y.Q. Acta Phys. -Chim. Sin. 2008, 24, 1127. [林涛,张秋林,李伟,龚茂初,幸怡汛, 陈耀强.物理化学学报, 2008, 24,1127.] doi: 10.1016/S1872-1508(08)60046-7
38. [38]
  (38) Mao, D. S.; Lu, G. Z.; Chen, Q. L.; Xie, Z. K.; Zhang, Y. X.Chin. J. Catal. 2002, 23, 9. [毛东森, 卢冠忠,陈庆龄, 谢在库, 张玉贤.催化学报, 2002, 23, 9.]
39. [39]
  (39) Mao, D. S.; Lu, G. Z.; Chen, Q. L.; Xie, Z. K.; Zhang, Y. X.Catal. Lett. 2001, 77, 119. doi: 10.1023/A:1012787028360
40. [40]
  (40) Wang, J. L.; Wang, K. C.; Cao, H. Y.; Chen, Y. D.; Liu, Z. M.;Zhu, Y.; ng, M. C.; Chen, Y. Q. Acta Phys. -Chim. Sin. 2009,25, 689. [王健礼,王康才, 曹红岩,陈永东,刘志敏,朱艺,龚茂初, 陈耀强.物理化学学报, 2009, 25, 689.] doi: 10.3866/PKU.WHXB200904211
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Influence of Adding Zr0.5Ti0.5O2 on the Performance of Supercritical Cracking Catalyst for RP-3

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Influence of Adding Zr_0.5Ti_0.5O₂ on the Performance of Supercritical Cracking Catalyst for RP-3