Citation:
LI Qi, HOU Yu-Hui, DONG Ling-Yu, HUANG Ming-Xiang, WENG Wei-Zheng, XIA Wen-Sheng, WAN Hui-Lin. Catalytic Behaviors and Stability of Aerogel Silica-Supported Ni Catalysts for the Partial Oxidation of Methane into Synthesis Gas[J]. Acta Physico-Chimica Sinica,
;2013, 29(10): 2245-2254.
doi:
10.3866/PKU.WHXB201308201
-
Two types of aerogel silica, denoted as SiO2-A(or B)G are synthesized with either solvent substitution (A) or solvent substitution-surface modification (B) under atmospheric conditions. Aerogel silicasupported Ni catalysts are then prepared via impregnated (IM) and polyvinylpyrrolidone (PVP)-added IM methods, and their performances for the partial oxidation of methane (POM) are investigated. The similar initial catalytic performances (activity and selectivity) are observed over the different Ni/SiO2 catalysts. With respect to POMstability, Ni/SiO2-BG is significantly worse than Ni/SiO2-AG, while catalysts with PVP addition (during preparation) exhibit a significant improvement. In this case, Ni/SiO2-BG-PVPis comparable to Ni/SiO2-AG-PVP. We characterize the catalysts with X-ray diffraction (XRD), temperature-programmed hydrogen reduction (H2-TPR), transmission electron microscopy (TEM), and Brunauer-Emmett-Teller (BET) analysis. We find that there are hydroxyls on the SiO2-AG surface that favor their interaction with hydrophilic metal species, while on the SiO2-BGsurface there are organic groups that do not interact with hydrophilic metal species. In addition, with the help of PVP, metal species can access the deep pores of hydrophilic/hydrophobic silica gels. Then, the contraction of the silica framework and the growth of metal particles are inhibited during calcinations, enhancing interactions between Ni and the silica gels. These (benefits fromsurface hydroxyls and PVP) result in significant improvements in the catalysts with respect to POMstability.
-
-
-
[1]
(1) Zhang, Y. W.; Liu, J.; Ding, W. Z.; Lu, X. G. Fuel 2011, 90,324. doi: 10.1016/j.fuel.2010.08.027
-
[2]
(2) Mudu, F.; Arstad, B.; Bakken, E.; Fjellvåg, H.; Olsbye, U.Journal of Catalysis 2010, 275, 25. doi: 10.1016/j.jcat.2010.07.004
-
[3]
(3) Christian, E. B.; Lødeng, R.; Holmen, A. Applied Catalysis A: General 2008, 346, 1. doi: 10.1016/j.apcata.2008.05.018
-
[4]
(4) Nematollahi, B.; Rezaei, M.; Khajenoori, M. International Journal of Hydrogen Energy 2011, 36, 2969. doi: 10.1016/j.ijhydene.2010.12.007
-
[5]
(5) Yang, S. W.; Kondo, J. N.; Hayashi, K.; Hirano, M.; Domen, K.;Hosono, H. Applied Catalysis A: General 2004, 277, 239. doi: 10.1016/j.apcata.2004.09.030
-
[6]
(6) Weng, W. Z.; Pei, X. Q.; Li, J. M.; Luo, C. R.; Liu, Y.; Lin, H.Q.; Huang, C. J.; Wan, H. L. Catalysis Today 2006, 117, 53. doi: 10.1016/j.cattod.2006.05.011
-
[7]
(7) Li, J. M.; Huang, F. Y.; Weng, W. Z.; Pei, X. Q.; Luo, C. R.; Lin,H. Q.; Huang, C. J.;Wan, H. L. Catalysis Today 2008, 131, 179.doi: 10.1016/j.cattod.2007.10.040
-
[8]
(8) He, S. F.;Wu, H. M.; Yu, W. J.; Mo, L. Y.; Lou, H.; Zheng, X.M. International Journal of Hydrogen Energy 2009, 34, 839.doi: 10.1016/j.ijhydene.2008.10.072
-
[9]
(9) Özdemir, H.; Faruk Öksüzömer, M. A.; Ali Gürkaynak, M.International Journal of Hydrogen Energy 2010, 35, 12147. doi: 10.1016/j.ijhydene.2010.08.091
-
[10]
(10) Jing, Q.; Lou, H.; Fei, J.; Hou, Z.; Zheng, X. International Journal of Hydrogen Energy 2004, 29, 1245. doi: 10.1016/j.ijhydene.2004.01.012
-
[11]
(11) Takenaka, S.; Umebayashi, H.; Tanabe, E.; Matsune, H.;Kishida, M. Journal of Catalysis 2007, 245, 392. doi: 10.1016/j.jcat.2006.11.005
-
[12]
(12) He, S. F.; Wu, H. M.; Yu, W. J.; Mo, L. Y.; Lou, H.; Zheng, X.M. Catalysis Today 2009, 148, 130. doi: 10.1016/j.cattod.2009.03.009
-
[13]
(13) Li, L.; He, S. C.; Song, Y. Y.; Zhao, J.; Ji, W. J.; Au, C. T.Journal of Catalysis 2012, 288, 54. doi: 10.1016/j.jcat.2012.01.004
-
[14]
(14) Choudhary, V. R.; Mamman, A. S. Applied Energy 2000, 66,161. doi: 10.1016/S0306-2619(99)00039-2
-
[15]
(15) Requies, J.; Cabrero, M. A.; Barrio, V. L.; Güemez, M. B.;Cambra, J. F.; Arias, P. L.; Pérez-Alonso, F. J.; Ojeda, M.; Peña,M. A.; Fierro, J. L. G. Applied Catalysis A: General 2005, 289,214. doi: 10.1016/j.apcata.2005.05.002
-
[16]
(16) Li, B. T.; Xu, X. J.; Zhang, S. Y. International Journal of Hydrogen Energy 2013, 38, 890.
-
[17]
(17) Chen, L.; Zhu, Q. S.;Wu, R. F. International Journal of Hydrogen Energy 2011, 36, 2128. doi: 10.1016/j.ijhydene.2010.11.042
-
[18]
(18) Xia, W. S.; Hou, Y. H.; Chang, G.; Weng, W. Z.; Han, G. B.;Wan, H. L. International Journal of Hydrogen Energy 2012, 37,8343. doi: 10.1016/j.ijhydene.2012.02.141
-
[19]
(19) Guan, L. X.; Zhang, L. W.; Qu, Y. X. Fine Chemical 2010, 27,738. [关鲁雄, 张利伟, 区叶秀. 精细化工2010, 27, 738.]
-
[20]
(20) Zhu, H. F. Supports of Catalyst; Chemical Industy Press:Beijing, 1980; p 473. [朱洪法. 催化剂载体. 北京:化学工业出版社, 1980: 473.]
-
[21]
(21) Jiang, J. T.; Wei, X. J.; Xu, C. Y.; Zhou, Z. X.; Zhen, L. Journal of Magnetism and Magnetic Materials 2013, 334, 111. doi: 10.1016/j.jmmm.2012.12.036
-
[22]
(22) Dissanayake, D.; Rosynek, M. P.; Lunsford, J. H. Journal of Physical Chemistry 1993, 97, 3644. doi: 10.1021/j100117a002
-
[23]
(23) Song, Y. Q.; Liu, H. M.; Liu, S. Q.; He, D. H. Energy& Fuels2009, 23, 1925. doi: 10.1021/ef800954a
-
[24]
(24) Li, B.; Weng, W. Z.; Zhang, Q.; Wang, Z. W.; Wan, H. L.ChemCatChem 2011, 3, 1277. doi: 10.1002/cctc.v3.8
-
[25]
(25) Lin, J. B.; Chen, H. J.; Yao, L. C. Applied Surface Science 2010,256, 5978. doi: 10.1016/j.apsusc.2010.03.105
-
[26]
(26) Hegde, N. D.; Hirashima, H.; Venkateswara Rao, A. Journal of Porous Materials 2007, 14, 165. doi: 10.1007/s10934-006-9021-2
-
[27]
(27) Ermakova, M. A.; Ermakov, D. Y. Catalysis Today 2002, 77,225. doi: 10.1016/S0920-5861(02)00248-1
-
[28]
(28) Gao, C. G.; Zhao, Y. X.; Liu, D. S. Catalysis Letters 2007, 118,50. doi: 10.1007/s10562-007-9135-4
-
[29]
(29) Rao, A. V.; Kulkarni, M. M.; Pajonk, G. M.; Amalnerkar, D. P.;Seth, T. Journal of Sol-Gel Science and Technology 2003, 27,103. doi: 10.1023/A:1023765030983
-
[1]
-
-
-
[1]
Jingyu Cai , Xiaoyu Miao , Yulai Zhao , Longqiang Xiao . Exploratory Teaching Experiment Design of FeOOH-RGO Aerogel for Photocatalytic Benzene to Phenol. University Chemistry, 2024, 39(4): 169-177. doi: 10.3866/PKU.DXHX202311028
-
[2]
Feng Zheng , Ruxun Yuan , Xiaogang Wang . “Research-Oriented” Comprehensive Experimental Design in Polymer Chemistry: the Case of Polyimide Aerogels. University Chemistry, 2024, 39(10): 210-218. doi: 10.12461/PKU.DXHX202404027
-
[3]
Jiaxi Xu , Yuan Ma . Influence of Hyperconjugation on the Stability and Stable Conformation of Ethane, Hydrazine, and Hydrogen Peroxide. University Chemistry, 2024, 39(11): 374-377. doi: 10.3866/PKU.DXHX202402049
-
[4]
Ying Xu , Chengying Shen , Hailong Yuan , Wei Wu . Mapping multiple phases in curcumin binary solid dispersions by fluorescence contrasting. Chinese Chemical Letters, 2024, 35(9): 109324-. doi: 10.1016/j.cclet.2023.109324
-
[5]
Hailian Tang , Siyuan Chen , Qiaoyun Liu , Guoyi Bai , Botao Qiao , Fei Liu . Stabilized Rh/hydroxyapatite Catalyst for Furfuryl Alcohol Hydrogenation: Application of Oxidative Strong Metal-Support Interactions in Reducing Conditions. Acta Physico-Chimica Sinica, 2025, 41(4): 100036-. doi: 10.3866/PKU.WHXB202408004
-
[6]
Shitao Fu , Jianming Zhang , Cancan Cao , Zhihui Wang , Chaoran Qin , Jian Zhang , Hui Xiong . Study on the Stability of Purple Cabbage Pigment. University Chemistry, 2024, 39(4): 367-372. doi: 10.3866/PKU.DXHX202401059
-
[7]
Xiaoning TANG , Junnan LIU , Xingfu YANG , Jie LEI , Qiuyang LUO , Shu XIA , An XUE . Effect of sodium alginate-sodium carboxymethylcellulose gel layer on the stability of Zn anodes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1452-1460. doi: 10.11862/CJIC.20240191
-
[8]
Bo YANG , Gongxuan LÜ , Jiantai MA . Corrosion inhibition of nickel-cobalt-phosphide in water by coating TiO2 layer. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 365-384. doi: 10.11862/CJIC.20240063
-
[9]
Xuewei BA , Cheng CHENG , Huaikang ZHANG , Deqing ZHANG , Shuhua LI . Preparation and luminescent performance of Sr1-xZrSi2O7∶xDy3+ phosphor with high thermal stability. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 357-364. doi: 10.11862/CJIC.20240096
-
[10]
Shilong Li , Ming Zhao , Yefei Xu , Zhanyi Liu , Mian Li , Qing Huang , Xiang Wu . Performance optimization of aqueous Zn/MnO2 batteries through the synergistic effect of PVP intercalation and GO coating. Chinese Chemical Letters, 2025, 36(3): 110701-. doi: 10.1016/j.cclet.2024.110701
-
[11]
Xuyang Wang , Jiapei Zhang , Lirui Zhao , Xiaowen Xu , Guizheng Zou , Bin Zhang . Theoretical Study on the Structure and Stability of Copper-Ammonia Coordination Ions. University Chemistry, 2024, 39(3): 384-389. doi: 10.3866/PKU.DXHX202309065
-
[12]
Jingke LIU , Jia CHEN , Yingchao HAN . Nano hydroxyapatite stable suspension system: Preparation and cobalt adsorption performance. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1763-1774. doi: 10.11862/CJIC.20240060
-
[13]
Yifeng TAN , Ping CAO , Kai MA , Jingtong LI , Yuheng WANG . Synthesis of pentaerythritol tetra(2-ethylthylhexoate) catalyzed by h-MoO3/SiO2. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2155-2162. doi: 10.11862/CJIC.20240147
-
[14]
Guang-Xu Duan , Queting Chen , Rui-Rui Shao , Hui-Huang Sun , Tong Yuan , Dong-Hao Zhang . Encapsulating lipase on the surface of magnetic ZIF-8 nanosphers with mesoporous SiO2 nano-membrane for enhancing catalytic performance. Chinese Chemical Letters, 2025, 36(2): 109751-. doi: 10.1016/j.cclet.2024.109751
-
[15]
Jing SU , Bingrong LI , Yiyan BAI , Wenjuan JI , Haiying YANG , Zhefeng Fan . Highly sensitive electrochemical dopamine sensor based on a highly stable In-based metal-organic framework with amino-enriched pores. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1337-1346. doi: 10.11862/CJIC.20230414
-
[16]
Renqing Lü , Shutao Wang , Fang Wang , Guoping Shen . Computational Chemistry Aided Organic Chemistry Teaching: A Case of Comparison of Basicity and Stability of Diazine Isomers. University Chemistry, 2025, 40(3): 76-82. doi: 10.12461/PKU.DXHX202404119
-
[17]
Baitong Wei , Jinxin Guo , Xigong Liu , Rongxiu Zhu , Lei Liu . Theoretical Study on the Structure, Stability of Hydrocarbon Free Radicals and Selectivity of Alkane Chlorination Reaction. University Chemistry, 2025, 40(3): 402-407. doi: 10.12461/PKU.DXHX202406003
-
[18]
Xinpin Pan , Yongjian Cui , Zhe Wang , Bowen Li , Hailong Wang , Jian Hao , Feng Li , Jing Li . Robust chemo-mechanical stability of additives-free SiO2 anode realized by honeycomb nanolattice for high performance Li-ion batteries. Chinese Chemical Letters, 2024, 35(10): 109567-. doi: 10.1016/j.cclet.2024.109567
-
[19]
Yuan GAO , Yiming LIU , Chunhui WANG , Zhe HAN , Chaoyue FAN , Jie QIU . A hexanuclear cerium oxo cluster stabilized by furoate: Synthesis, structure, and remarkable ability to scavenge hydroxyl radicals. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 491-498. doi: 10.11862/CJIC.20240271
-
[20]
Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . 层状双金属氢氧化物的层间阴离子对衍生的Ni-Al2O3催化剂光热催化CO2甲烷化反应的影响. Acta Physico-Chimica Sinica, 2025, 41(1): 2309002-. doi: 10.3866/PKU.WHXB202309002
-
[1]
Metrics
- PDF Downloads(505)
- Abstract views(802)
- HTML views(14)