Citation: WANG Ya-Nan, YANG Yu-Xia, LI Yong-Wen, LAI Jun-Hua, SUN Kun-Peng. Preparation of Fe₃O₄ Modified Pt-Ru/C Nanocatalysts and Their Catalytic Properties for the Selective Hydrogenation of ortho-Chloronitrobenzene under Solvent-Free Conditions[J]. Acta Physico-Chimica Sinica, ;2013, 29(10): 2239-2244. doi: 10.3866/PKU.WHXB201308151 shu

Preparation of Fe₃O₄ Modified Pt-Ru/C Nanocatalysts and Their Catalytic Properties for the Selective Hydrogenation of ortho-Chloronitrobenzene under Solvent-Free Conditions

1.
1 Centre for Green Chemistry and Catalysis, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, P. R. China;
2 University of Chinese Academy of Sciences, Beijing 100049, P. R. China;
3 Cold and Arid Regions Environmental and Engineering Research Institute, Chinese Academy of Sciences, Lanzhou 730000, P. R. China

Received Date: 10 April 2013
Available Online: 15 August 2013

Aseries of Fe₃O₄-modified Pt-Ru/C nanocomposite catalysts were prepared by impregnation and hydrazine hydrate reduction of Pt and Ru precursors. Various Pt/Ru mass ratios of the catalysts were examined in terms of catalytic activity. They were characterized by transmission electron microscopic measurements (TEM), energy dispersive X-ray spectroscopy (EDX), X-ray photoelectron spectroscopy (XPS), and X-ray diffraction (XRD). The average diameters of the catalysts with different mass ratios of Pt/Ru were in a range of 2.2-2.5 nmwith narrowsize distributions. The valence states of the nanoparticles indicate strong interactions between the Pt and the carbon support or with Fe₃O₄. The XRDpatterns of the 8Pt-1Ru/Fe₃O₄/C, 6Pt-1Ru/Fe₃O₄/ C, 4Pt-1Ru/Fe₃O₄/C, and 2Pt-1Ru/Fe₃O₄/Ccatalysts have similar profiles, which are attributed to the cubic phase of pure Fe₃O₄ (i.e., no Pt or Ru present). These catalysts selectively hydrogenate ortho-chloronitrobenzene (o-CNB) to the corresponding ortho-chloroaniline (o-CAN) under solvent-free conditions that not only allowed high substrate concentrations promoting the hydrogenation reaction, but also enabled easy product separation and purification. They exhibited excellent catalytic activity (turnover frequency (TOF) range: 0.98-2.09 mol·mol^-1·s^-1) and up to 100% o-CAN selectivity, which was composition-dependent. The o-CAN yield selectivity monotonically increased with the proportion of Ru; however, the catalytic activity decreased. The high catalytic activity and selectivity of Pt-Ru/Fe₃O₄/Cnanoparticles are attributed to electron transfer between the two metals and Fe₃O₄.
- Selective hydrogenation,
- Solvent-free,
- Chloronitrobenzene,
- Chloroaniline,
- Ferroferric oxide,
- Platinum,
- Ruthenium
1. [1]
  
  (1) Wang, X. D.; Liang, M. H.; Zhang, J. L.; Wang, Y. Curr. Organ. Chem. 2007, 11, 299. doi: 10.2174/138527207779940856
2. [2]
  (2) Sikhwivhilu, L. M.; Coville, N. J.; Pulimaddi, B. M.;Venkatreddy, J.; Vishwanathan, V. Catal. Commun. 2007, 8,1999. doi: 10.1016/j.catcom.2007.03.023
3. [3]
  (3) Liang, C. H.; Han, J. G.; Shen, K. H.; Wang, L. G.; Zhang, D.F.; Freeman, H. S. Chem. Eng. J. 2010, 165, 709. doi: 10.1016/j.cej.2010.10.022
4. [4]
  (4) Xiao, C. X.; Wang, H. Z.; Mu, X. D.; Kou, Y. J. Catal. 2007,250, 25. doi: 10.1016/j.jcat.2007.05.009
5. [5]
  (5) Yao, N.; Chen, J. X.; Zhang, J. X.; Zhang, J. Y. Catal. Commun.2008, 9, 1510. doi: 10.1016/j.catcom.2007.12.022
6. [6]
  (6) Chen, Y. Z.; Chen, Y. C. Appl. Catal. A 1994, 115, 45. doi: 10.1016/0926-860X(94)80377-3
7. [7]
  (7) Zhao, B. Z.; Chen, Y. W. J. Non-Cryst. Solids 2010, 356, 839.doi: 10.1016/j.jnoncrysol.2010.01.009
8. [8]
  (8) Kosak, J. R. Ann. NY Acad. Sci. 1970, 172, 175. doi: 10.1111/nyas.1970.172.issue-9
9. [9]
  (9) Jiang, L. C.; Gu, H. Z.; Xu, X. Z.; Yan, X. H. J. Mol. Catal. A2009, 310, 144. doi: 10.1016/j.molcata.2009.06.009
10. [10]
  (10) Xie, Y. L.; Xiao, N.; Ling, Z.; Liu, Y.; Yu, C.; Qiu, J. S. Chin. J. Catal. 2012, 33, 1883. [解雅玲, 肖南,凌铮,柳月,于畅,邱介山. 催化学报, 2012, 33, 1883.] doi: 10.1016/S1872-2067(11)60451-8
11. [11]
  (11) Yan, X. H.; Sun, J. Q.; Xu, Y. H.; Yang, J. F. Chin. J. Catal.2006, 27, 119. [严新焕,孙军庆, 徐颖华, 杨建峰. 催化学报,2006, 27, 119.] doi: 10.1016/S1872-2067(06)60010-7
12. [12]
  (12) Xu, X. Z.; Yang, J. F.; Li, X. N.; Yan, X. H. Acta Phys. -Chim. Sin. 2008, 24 (1), 121. [许兴中, 杨建锋,李小年, 严新焕.物理化学学报, 2008, 24 (1), 121.] doi: 10.3866/PKU.WHXB20080121
13. [13]
  (13) Coq, B.; Tijani, A.; Dutartre, R.; Figuéras, F. J. Mol. Catal.1993, 79, 253. doi: 10.1016/0304-5102(93)85106-4
14. [14]
  (14) Tijani, A.; Coq, B.; Figuéras, F. Appl. Catal. 1991, 76, 255. doi: 10.1016/0166-9834(91)80051-W
15. [15]
  (15) Dovell, F. S.; Greenfield, H. J. Am. Chem. Soc. 1965, 87,2767. doi: 10.1021/ja01090a050
16. [16]
  (16) Zuo, B. J.; Wang, Y.; Wang, Q. L.; Zhang, J. L.; Wu, N. Z.;Peng, L. D.; Gui, L. L.; Wang, X. D.; Wang, R. M.; Yu, D. P.J. Catal. 2004, 222, 493. doi: 10.1016/j.jcat.2003.12.007
17. [17]
  (17) Pietrowski, M.; Wojciechowska, M. Catal. Today 2009, 142,211. doi: 10.1016/j.cattod.2008.09.040
18. [18]
  (18) Winans, C. F. J. Am. Chem. Soc. 1939, 61, 3564. doi: 10.1021/ja01267a101
19. [19]
  (19) Dunworth, W. P.; Nord, F. F. J. Am. Chem. Soc. 1952, 74,1459. doi: 10.1021/ja01126a029
20. [20]
  (20) Liu, M. H.; Zhang, J.; Liu, J. Q.; Yu, W. W. J. Catal. 2011, 278,1. doi: 10.1016/j.jcat.2010.11.009
21. [21]
  (21) Raltzly, B.; Phillips, A. P. J. Am. Chem. Soc. 1946, 68, 261. doi: 10.1021/ja01206a034
22. [22]
  (22) Mao, J. Z.; Yan, X. H.; Gu, H. Z.; Jiang, L. C. Chin. J. Catal.2009, 30, 182. [毛建忠, 严新焕,顾辉子, 江玲超.催化学报, 2009, 30, 182.]
23. [23]
  (23) Wang, F.; Liu, J. H.; Yin, Y. Q.; Xu, X. L. Acta Phys. -Chim. Sin.2009, 25 (8), 1678. [王芳, 刘俊华,殷元骐, 徐贤伦.物理化学学报, 2009, 25 (8), 1678.] doi: 10.3866/PKU.WHXB20090814
24. [24]
  (24) Liu, M.; Yu, W.; Liu, H. J. Mol. Catal. A 1999, 138, 295. doi: 10.1016/S1381-1169(98)00159-9
25. [25]
  (25) Pietrowski, M.; Zieliński, M.; Wojciechowska, M.ChemCatChem 2011, 3, 835. doi: 10.1002/cctc.v3.5
26. [26]
  (26) Sun, Z. Y.; Zhang, H. Y.; An, G. M.; Yang, G. Y.; Liu, Z. M.J. Mater. Chem. 2010, 20, 1947.
27. [27]
  (27) Lian, C.; Liu, H. Q.; Xiao, C.; Yang, W.; Zhang, K.; Liu, Y.;Wang, Y. Chem. Commun. 2012, 48, 3124. doi: 10.1039/c2cc16620h
28. [28]
  (28) Liu, M. H.; Mo, X. X.; Liu, Y. Y.; Xiao, H. L.; Zhang, Y.; Jing,J. Y.; Colvin, V. L.; William, W. Y. Appl. Catal. A 2012, 439,192.
29. [29]
  (29) Cheney, B. A.; Lauterbach, J. A.; Chen, J. G. Appl. Catal. A2011, 394, 41. doi: 10.1016/j.apcata.2010.12.021
30. [30]
  (30) Zhao, T. T.; Lin, R.; Zhang, L.; Cao, C. H.; Ma, J. X. Acta Phys. -Chim. Sin. 2013, 29 (8), 1745. [赵天天,林瑞,张路,曹春晖,马建新. 物理化学学报, 2013, 29 (8),1745.] doi: 10.3866/PKU.WHXB201305101
31. [31]
  (31) Igarashi, H.; Fujino, T.; Zhu, Y.; Uchida, H.; Watanabe, M.Phys. Chem. Chem. Phys. 2001, 3, 306. doi: 10.1039/b007768m
32. [32]
  (32) Sun, Z. Y.; Wang, X.; Liu, Z. M.; Zhang, H. Y.; Yu, P.; Mao, L.Q. Langmuir 2010, 26, 12383. doi: 10.1021/la101060s
33. [33]
  (33) Holmgren, A.; Duprez, D.; Andersson, B. J. Catal. 1999, 182,441. doi: 10.1006/jcat.1998.2334
34. [34]
  (34) Sen, S.; Sen, F.; Gökagac, G. Phys. Chem. Chem. Phys. 2011,13, 6784. doi: 10.1039/c1cp20064j
35. [35]
  (35) Yang, X. L.; Zhang, W. Q.; Xia, C. G.; Xiong, X. M.; Mu, X. Y.;Hu, B. Catal. Commun. 2010, 11, 867. doi: 10.1016/j.catcom.2010.03.008
36. [36]
  (36) Allen, G. C.; Curtis, M. T.; Hooper, A. J.; Tucker, P. M. J. Chem. Soc. Dalton 2004, 1525.
1. [1]
  Shihui Shi , Haoyu Li , Shaojie Han , Yifan Yao , Siqi Liu . Regioselectively Synthesis of Halogenated Arenes via Self-Assembly and Synergistic Catalysis Strategy. University Chemistry, 2024, 39(5): 336-344. doi: 10.3866/PKU.DXHX202312002
2. [2]
  Peiran ZHAO , Yuqian LIU , Cheng HE , Chunying DUAN . A functionalized Eu³⁺ metal-organic framework for selective fluorescent detection of pyrene. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 713-724. doi: 10.11862/CJIC.20230355
3. [3]
  Jiaqi AN , Yunle LIU , Jianxuan SHANG , Yan GUO , Ce LIU , Fanlong ZENG , Anyang LI , Wenyuan WANG . Reactivity of extremely bulky silylaminogermylene chloride and bonding analysis of a cubic tetragermylene. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1511-1518. doi: 10.11862/CJIC.20240072
4. [4]
  Junjie Zhang , Yue Wang , Qiuhan Wu , Ruquan Shen , Han Liu , Xinhua Duan . Preparation and Selective Separation of Lightweight Magnetic Molecularly Imprinted Polymers for Trace Tetracycline Detection in Milk. University Chemistry, 2024, 39(5): 251-257. doi: 10.3866/PKU.DXHX202311084
5. [5]
  Geyang Song , Dong Xue , Gang Li . Recent Advances in Transition Metal-Catalyzed Synthesis of Anilines from Aryl Halides. University Chemistry, 2024, 39(2): 321-329. doi: 10.3866/PKU.DXHX202308030
6. [6]
  Yanhui Zhong , Ran Wang , Zian Lin . Analysis of Halogenated Quinone Compounds in Environmental Water by Dispersive Solid-Phase Extraction with Liquid Chromatography-Triple Quadrupole Mass Spectrometry. University Chemistry, 2024, 39(11): 296-303. doi: 10.12461/PKU.DXHX202402017
7. [7]
  Chunmei GUO , Weihan YIN , Jingyi SHI , Jianhang ZHAO , Ying CHEN , Quli FAN . Facile construction and peroxidase-like activity of single-atom platinum nanozyme. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1633-1639. doi: 10.11862/CJIC.20240162
8. [8]
  Yinuo Wang , Siran Wang , Yilong Zhao , Dazhen Xu . Selective Synthesis of Diarylmethyl Anilines and Triarylmethanes via Multicomponent Reactions: Introduce a Comprehensive Experiment of Organic Chemistry. University Chemistry, 2024, 39(8): 324-330. doi: 10.3866/PKU.DXHX202401063
9. [9]
  Yongpo Zhang , Xinfeng Li , Yafei Song , Mengyao Sun , Congcong Yin , Chunyan Gao , Jinzhong Zhao . Synthesis of Chlorine-Bridged Binuclear Cu(I) Complexes Based on Conjugation-Driven Cu(II) Oxidized Secondary Amines. University Chemistry, 2024, 39(5): 44-51. doi: 10.3866/PKU.DXHX202309092
10. [10]
  Yunhao Zhang , Yinuo Wang , Siran Wang , Dazhen Xu . Progress in Selective Construction of Functional Aromatics from Nitrogenous Cycloalkanes. University Chemistry, 2024, 39(11): 136-145. doi: 10.3866/PKU.DXHX202401083
11. [11]
  Xilin Zhao , Xingyu Tu , Zongxuan Li , Rui Dong , Bo Jiang , Zhiwei Miao . Research Progress in Enantioselective Synthesis of Axial Chiral Compounds. University Chemistry, 2024, 39(11): 158-173. doi: 10.12461/PKU.DXHX202403106
12. [12]
  Jiakun BAI , Ting XU , Lu ZHANG , Jiang PENG , Yuqiang LI , Junhui JIA . A red-emitting fluorescent probe with a large Stokes shift for selective detection of hypochlorous acid. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1095-1104. doi: 10.11862/CJIC.20240002
13. [13]
  Jie ZHAO , Sen LIU , Qikang YIN , Xiaoqing LU , Zhaojie WANG . Theoretical calculation of selective adsorption and separation of CO₂ by alkali metal modified naphthalene/naphthalenediyne. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 515-522. doi: 10.11862/CJIC.20230385
14. [14]
  Renxiao Liang , Zhe Zhong , Zhangling Jin , Lijuan Shi , Yixia Jia . A Palladium/Chiral Phosphoric Acid Relay Catalysis for the One-Pot Three-Step Synthesis of Chiral Tetrahydroquinoline. University Chemistry, 2024, 39(5): 209-217. doi: 10.3866/PKU.DXHX202311024
15. [15]
  Yiling Wu , Peiyao Jin , Shenyue Tian , Ji Zhang . The Star of Sugar Substitutes: An Interview of Erythritol. University Chemistry, 2024, 39(9): 22-27. doi: 10.12461/PKU.DXHX202404034
16. [16]
  Jizhou Liu , Chenbin Ai , Chenrui Hu , Bei Cheng , Jianjun Zhang . 六氯锡酸铵促进钙钛矿太阳能电池界面电子转移及其飞秒瞬态吸收光谱研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2402006-. doi: 10.3866/PKU.WHXB202402006
17. [17]
  Xiuyun Wang , Jiashuo Cheng , Yiming Wang , Haoyu Wu , Yan Su , Yuzhuo Gao , Xiaoyu Liu , Mingyu Zhao , Chunyan Wang , Miao Cui , Wenfeng Jiang . Improvement of Sodium Ferric Ethylenediaminetetraacetate (NaFeEDTA) Iron Supplement Preparation Experiment. University Chemistry, 2024, 39(2): 340-346. doi: 10.3866/PKU.DXHX202308067
18. [18]
  Yang Chen , Peng Chen , Yuyang Song , Yuxue Jin , Song Wu . Application of Chemical Transformation Driven Impurity Separation in Experiments Teaching: A Novel Method for Purification of α-Fluorinated Mandelic Acid. University Chemistry, 2024, 39(6): 253-263. doi: 10.3866/PKU.DXHX202310077
19. [19]
  Daojuan Cheng , Fang Fang . Exploration and Implementation of Science-Education Integration in Organic Chemistry Teaching for Pharmacy Majors: A Case Study on Nucleophilic Substitution Reactions of Alkyl Halides. University Chemistry, 2024, 39(11): 72-78. doi: 10.12461/PKU.DXHX202403105
20. [20]
  Jinfeng Chu , Yicheng Wang , Ji Qi , Yulin Liu , Yan Li , Lan Jin , Lei He , Yufei Song . Comprehensive Chemical Experiment Design: Convenient Preparation and Characterization of an Oxygen-Bridged Trinuclear Iron(III) Complex. University Chemistry, 2024, 39(7): 299-306. doi: 10.3866/PKU.DXHX202310105

Get Citation

PDF

XML

Metrics

PDF Downloads(5582)
Abstract views(1754)
HTML views(71)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation of Fe3O4 Modified Pt-Ru/C Nanocatalysts and Their Catalytic Properties for the Selective Hydrogenation of ortho-Chloronitrobenzene under Solvent-Free Conditions

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation of Fe₃O₄ Modified Pt-Ru/C Nanocatalysts and Their Catalytic Properties for the Selective Hydrogenation of ortho-Chloronitrobenzene under Solvent-Free Conditions